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Synthesis and characterization of new thermally stable poly(amide-imide)s based on bicyclo[2,2,2]oct-7-ene-2,3,5,6-tetracarboxylic diimide and aromatic diamines

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Abstract

N,N′-bis-(4-carboxyphenyl)bicyclo[2,2,2]oct-7-ene-2,3,5,6-tetracarboxylic diimide was prepared by reaction of bicyclo[2,2,2]oct-7-ene-2,3,5,6-tetra carboxylic dianhydride with p-aminobenzoic acid in a mixture of acetic acid and pyridine (3: 2). Polycondensation of N,N′-bis-(4-carboxyphenyl)bicyclo[2,2,2]oct-7-ene-2,3,5,6-tetracarboxylic diimide with six different aromatic diamines produced a series of new poly(amide-imide)s (PAIs) in high yields with inherent viscosities between 0.49–0.95 dl/g. All PAIs were characterized by means of elemental analysis, viscosity measurement, solubility test, FTIR spectroscopy and 1H-NMR spectroscopy. Dynamic TGA of PAIs shows 10% weight loss temperatures from 410 to 435°C under nitrogen.

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Authors and Affiliations

  1. Organic Polymer Chemistry Research Laboratory, Department of Chemistry, Faculty of Science, Arak University, Arak, 38156, Iran

    Khalil Faghihi & Mohsen Hajibeygi

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  1. Khalil Faghihi
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  2. Mohsen Hajibeygi
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Correspondence to Khalil Faghihi.

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Faghihi, K., Hajibeygi, M. Synthesis and characterization of new thermally stable poly(amide-imide)s based on bicyclo[2,2,2]oct-7-ene-2,3,5,6-tetracarboxylic diimide and aromatic diamines. Polym. Sci. Ser. B 53, 137–143 (2011). https://doi.org/10.1134/S156009041103002X

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  • DOI: https://doi.org/10.1134/S156009041103002X

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