Abstract
The new organotin(IV) complexes have been synthesized by the reaction of l-lysine monohydrate with CS2 and R2SnCl2/R3SnCl. The organotin(IV) complexes and the ligand have been characterized by elemental analysis, FT-IR and NMR (1H and 13C) spectrometry. IR data indicated that complexation proceeded -COO and -CSS sites and the ligand acted as a bidentate one. 1H and 13C NMR data confirmed the tetrahedral structure of the products in solution. Biological activity of the complexes was tested.
Similar content being viewed by others
References
Gielen, M., Biesemans, M., De-Vos. D., and Willem, R., J. Inorg. Biochem., 2000, vol. 79, p. 139.
Yin, D.H., Wang, B.Q., and Xing, J.Q., Heteroatom Chem., 2004, vol. 15, p. 524.
Geilen, M., Meunier-Piret, J., Biesemans, M., Willem, R., and Khloufo, A.El., Appl. Organomet. Chem., 1992, vol. 6, p. 67.
Shahzadi, S., Bhatti, M. H., Shahid, K., Ali, S., Tariq, S. R., Mazhar, M., and Khan, K.M., Monatsh fur Chemie, 2002, vol. 133, p. 1089.
Gielen, M., Biesemans, M., and Willem, R., Appl. Organomet. Chem., 2005, vol. 19, p. 440.
Sadiq-ur-Rehman, Shahid, K., Ali, S., Bhatti, M.H., and Parvez, M., J. Organomet. Chem., 2005, vol. 690, p. 1396.
Haiduc, I., In Comprehensive Coordination Chemistry-II, Meyer, J.A. and Meyer, T J., Eds., vol. 1, p. 349, Elsevier, 2004.
Menezes, D.C., Main Group Met. Chem., 2008, vol. 31, p. 21.
Menezes, D.C., Appl. Organomet. Chem., 2008, vol. 22, p. 221.
Stiefel, E.I. Matsumoto, K., Transition Metal Sulfur Chemistry, ACS Symposium Series 653, American Chemical Society, Washington, DC, 1995.
Jabeen, M., Ali, S., Shahzadi, S., Shahid, M., Khan, Q.M., Sharma, S.K., and Qanungo, K., J. Iran. Chem. Soc., 2012, vol. 9, p. 307.
Shah, F.A., Ali, S., Shahzadi, S., Rizzoli, C., and Ahmad, A., J. Iran. Chem. Soc., 2012, vo.l. 9, p. 923.
Jabbar, S., Shahzadi, I., Rehman, R., Iqbal, H., Qurat-ul-Ain, Jamil, A., Kaosar, R., Ali, S., Shahzadi, S., Chaudhary, M.A., Khan, Q.M., Shahid, M., Sharma, S.K., and Qanungo, K., J. Coord. Chem., 2012, vol. 65(4), p. 572.
Anwer, J., Ali, S. Shahzadi, S., Shahid, M., Sharma, S.K., and Qanungo, K., J. Coord. Chem., 2013, vol. 66(7), p. 1142.
Armarego, W.L.F. and Chai, C.L.L., Purification of Laboratory Chemicals, New York: Elsevier, 2003.
CLSI (The Clinical Laboratory Standards Institute), Agar Dilution and Disc Diffusion Susceptibility Testing of Campylobacter spp. Clinical Microbio., 2007, vol. 45, p. 2758.
Huang, G., Moore, S., Jiaxin, J., and Dehui, D., J. Food Sci. Techn., 2001, vol. 11(1), p. 25.
Huynh, Q.K., Borgmeyer, J.R., Smith, C.E., Bell, L.D., and Shah, D.M., J. Bio. Chem., 2001, vol. 316, p. 723.
Shahzadi, S., Shahid, K., Ali, S., and Bakhtiar, M., Turk. J. Chem., 2008, vol. 32, p. 333.
Singh, H.L., Singh, J.B., and Sharma, K.P., Res. Chem. Intermed., 2012, vol. 38, p. 53.
Joshi, R., Kumar, P., Kumar, V., and Hashmi, A.A., J. Coord. Chem., 2008, vol. 61(8), p. 1283.
Jain, M. and Singh, R.V., Appl. Organomet. Chem., 2003, vol. 17, p. 616.
Kalinowski, H.O., Berger, S., and Braun, S., 13C NMR Spektroskopic Thieme, Stuttgart, Germany, 1984.
Rehman, W., Musa, K.B., Badshah, A., and Ali. S., Spectrochim. Acta, Part A, 2006, vol. 65, p. 689.
Ali, S., Ahmad, F., Mazhar, M., Munir, A., and Masood, M.T., Synth. React. Inorg. Met.-Org. Chem., 2001, vol. 32, p. 357.
Win, Y.F., Teoh, S.G., Lim, E.K., Nig, S.L., and Fun, H.K., J. Chem. Cryst., 2008, vol. 38, p. 345.
Lockhart, T.P. and Manders, W.F., Inorg. Chem., 1986, vol. 25, p. 892.
Nadvornik, M., Holecek, J., Handlir, K., and Lycka, A., J. Organomet. Chem., 1984, vol. 275, p. 43.
Jamil, K., Bakhtiar, M., Khan, A.R., Rubina, F., Rehana, R., Wajid, R., Qaisar, M., Khan, A. F., Khan, A.K., Danish, M., Awais, M., Bhatti, Z.A., Rizwan, M., Naveed, A., Hussain, M., and Pervez, A., Afri. J. Pure Appl. Chem., 2009, vol. 3(4), p. 066.
Author information
Authors and Affiliations
Corresponding author
Additional information
The text was submitted by the authors in English.
Rights and permissions
About this article
Cite this article
Bashir, M.S., Ali, S., Shahzadi, S. et al. Synthesis, characterization and biological activities of organotin(IV) complexes with l-lysine monohydrate. Russ J Gen Chem 85, 1532–1537 (2015). https://doi.org/10.1134/S1070363215060298
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S1070363215060298