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Syntheses, Crystal Structures, and Fluorescence Properties of 3d–4f Coordination Polymers LnNi (Ln = Er, Eu)

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Abstract

Two novel 3d–4f coordination polymers [Ln(NiL)(Nipt)(C2O4)0.5 · H2O] · H2O (Ln = Er (I), Eu (II) (H2L = 2,3-dioxo-5,6,14,15-dibenzo-1,4,8,12-tetraazacyclopentadeca-7,13-dien; H2Nip = 5-nit-roisophthalic acid) were obtained by using 5-nitroisophthalate and mononuclear macrocyclic oxamide complex NiL as co-ligand to react with Ln(NO3)3 ⋅ 6H2O (Ln = Er, Eu) under solvothermal condition, and characterized by single crystal X-ray diffraction (CIF files CCDC nos. 1587618 (I) and 1587619 (II)). Two complexes are isostructural structure and exhibit a two-dimensional network architecture formed by [Ln(III)Ni(II)] units via the oxamide, 5-nitroisophthalate and oxalate bridges, and adjacent 2D structures are linked together with C–H⋅⋅⋅O and O–H⋅⋅⋅O intermolecular hydrogen bonds to form a 3D superamolecular architectures. The fluorescence properties of I and II are also characterized.

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Authors and Affiliations

  1. Tianjin Key Laboratory of Structure and Performance for Functional Molecule, College of Chemistry, Tianjin Normal University, 300387, Tianjin, P.R. China

    G. Z. Deng, N. Xin, Y. Q. Sun, Y. Y. Xu & D. Z. Gao

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  1. G. Z. Deng
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  2. N. Xin
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  3. Y. Q. Sun
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  4. Y. Y. Xu
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  5. D. Z. Gao
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Correspondence to Y. Q. Sun.

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Deng, G.Z., Xin, N., Sun, Y.Q. et al. Syntheses, Crystal Structures, and Fluorescence Properties of 3d–4f Coordination Polymers LnNi (Ln = Er, Eu). Russ J Coord Chem 44, 565–571 (2018). https://doi.org/10.1134/S1070328418090014

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  • DOI: https://doi.org/10.1134/S1070328418090014

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