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A New Metalloligand Powerful in Forming Helical Coordination Polymers

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Abstract

A new macrocyclic oxamido carboxylate metalloligand was designed and three heteronuclear coordination polymers of the metalloligand and metal nodes Cu2+, Zn2+ and Cd2+ were prepared. X-ray single crystal analyses (CIF files CCDC nos. 1025722–1025724 for I–III) revealed that multiple favourable features endowed the metalloligand with a strong power to force the metal nodes to generate 1D helical coordination polymers. Thermogravimetric analyses showed that the complexes with Cu2+ and Zn2+ nodes exhibited moderate thermal stability. The three complexes were also characterized by IR spectra and PXRD.

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Authors and Affiliations

  1. Department of Chemistry, School of Science, Tianjin University, and Collaborative Innovation Center of Chemical Science and Engineering, Tianjin, 300072, P.R. China

    S. Z. Zhang, B. Yuan, Y. L. Lan, X. Z. Li & L. N. Zhu

  2. Department of Chemical Engineering, Ren’ai College of Tianjin University, Tianjin, 301636, P.R. China

    P. P. Hao

Authors
  1. S. Z. Zhang
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  2. B. Yuan
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  3. Y. L. Lan
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  4. X. Z. Li
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  5. P. P. Hao
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  6. L. N. Zhu
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Correspondence to X. Z. Li.

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Zhang, S.Z., Yuan, B., Lan, Y.L. et al. A New Metalloligand Powerful in Forming Helical Coordination Polymers. Russ J Coord Chem 43, 700–707 (2017). https://doi.org/10.1134/S1070328417100116

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  • DOI: https://doi.org/10.1134/S1070328417100116

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