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Synthesis, Crystal Structure, and Luminescent Properties of Two ZnII/CdII Coordination Polymers Based on 1,4-Bis(pyridine-3-Ylmethoxy)benzene

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Abstract

Two polymeric frameworks, [Zn(Dpb)(Oba)] n (Ι) and [Cd(Dpb)(2,6-Pda)H2O] n · nH2O (II) (Dpb = 1,4-bis(pyridin-3-ylmethoxy)benzene, H2Oba = 4,4'-oxybis(benzoic acid), 2,6-H2Pda = 2,6-pyridyl-dicarboxylate), have been hydrothermally synthesized and structurally characterized by single crystal X-ray diffraction method (CIF files CCDC 1488269 (Ι), 1488270 (II)). Complex Ι is a 2D layer structure, which is constructed from 1D double chain. Complex II is a 1D chain. The luminescent properties of Ι, II have been investigated with fluorescent spectra in the solid state, I and II displayed a strong fluorescent emission at room temperature.

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Authors and Affiliations

  1. Shaanxi Key Laboratory of Catalysis, College of Chemical and Environment Science, Shaanxi University of Technology, Han Zhong, 723001, P.R. China

    J. Song, J. Liu, J. Shi, J. W. Ji, R. Wu, J. F. Lu & Q. Zhang

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  1. J. Song
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  2. J. Liu
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  3. J. Shi
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  4. J. W. Ji
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  5. R. Wu
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  6. J. F. Lu
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  7. Q. Zhang
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Correspondence to J. Song.

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Song, J., Liu, J., Shi, J. et al. Synthesis, Crystal Structure, and Luminescent Properties of Two ZnII/CdII Coordination Polymers Based on 1,4-Bis(pyridine-3-Ylmethoxy)benzene. Russ J Coord Chem 43, 685–692 (2017). https://doi.org/10.1134/S1070328417100098

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  • DOI: https://doi.org/10.1134/S1070328417100098

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