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Two heterometallic complexes with a new macrocyclic oxamido complex ligand

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Abstract

A new macrocyclic oxamido-nickle(II) complex Na2NiL was synthesized. L denotes the doubly deprotonated forms of (13Z, 19Z)-16-methyl-6,7-dioxo-5,6,7,8-tetrahydrotriben-zo[b,f,l][1,4,8,11]tetraazacyclotetradecine- 13,20-dicarboxylate. Based on the complex ligand Ni(L2–), two heterometallic complexes [Ca2(NiL)2(H2O)8] · 10H2O (I) and [Co(NiL)2(H2O)2][Co(H2O)6] · 2.8H2O (II) were prepared. X-ray single crystal analyses (CCDC nos. 914618 (I), 914616 (II)) revealed that [Ca2(NiL)2(H2O)8] in I is a molecular box and the trinuclear complex anion [Co(NiL)2(H2O)2]2–in II is centrosymmetric. Thermogravimetric analyses showed that I exhibited moderately good stability and Co(II) catalyzed the thermal decomposition of II.

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Authors and Affiliations

  1. Department of Chemistry, School of Science, Tianjin University, and Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Tianjin, 300072, P.R. China

    Y. H. Li, Z. G. Ma, B. Yuan, B. B. Ding, X. Z. Li & L. N. Zhu

  2. State Key Laboratory of Crystal Material (Shandong University), Jinan, 250100, P.R. China

    X. Z. Li

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  1. Y. H. Li
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  2. Z. G. Ma
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  3. B. Yuan
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  4. B. B. Ding
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  5. X. Z. Li
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  6. L. N. Zhu
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Correspondence to X. Z. Li.

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Li, Y.H., Ma, Z.G., Yuan, B. et al. Two heterometallic complexes with a new macrocyclic oxamido complex ligand. Russ J Coord Chem 42, 546–556 (2016). https://doi.org/10.1134/S1070328416080030

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  • DOI: https://doi.org/10.1134/S1070328416080030

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