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A 1D linear chain coordination polymer constructed by Co(II) with Atibdc and Bipy Ligands (H2Atibdc = 5-amino-2,4,6-triiodoisophthalic acid, Bipy = 4,4-bipyridyl)

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Abstract

A new coordination polymer, [Co(Atibdc)(Bipy)(H2O)3] · 2DMF · H2O (I) (H2Atibdc = 5-amino-2,4,6-triiodoisophthalic acid, Bipy = 4,4′-bipyridyl), has been synthesized and characterized by elemental analysis, IR, and X-ray single-crystal diffraction. The X-ray diffraction analysis reveals that I (C24H30CoI3N5O10) crystallizes in the monoclinic system, space group P21/n. The adjacent cobalt atoms adopt different coordination modes via nitrogen atoms from two different Bipy ligands to generate an infinite linear chain, which are further linked by hydrogen bonds and I…I weak interactions to form a two-dimensional layer.

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Authors and Affiliations

  1. College of Chemistry, Liaoning University, Shenyang, 110036, P.R. China

    Y. E. Du & Z. B. Han

  2. College of Chemistry, Beijing Normal University, Beijing, 100875, P.R. China

    L. Ai

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  1. Y. E. Du
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  2. L. Ai
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  3. Z. B. Han
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Correspondence to Z. B. Han.

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Du, Y.E., Ai, L. & Han, Z.B. A 1D linear chain coordination polymer constructed by Co(II) with Atibdc and Bipy Ligands (H2Atibdc = 5-amino-2,4,6-triiodoisophthalic acid, Bipy = 4,4-bipyridyl). Russ J Coord Chem 37, 122–126 (2011). https://doi.org/10.1134/S1070328411010039

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  • DOI: https://doi.org/10.1134/S1070328411010039

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