Abstract
A 1D zigzag coordination polymer {[Zn2(2,6-Pydc)2(Bpp)2] · 4H2O} n (I) [2,6-H2Pydc = 2,6-pyridinedicarboxylic acid, Bpp = 1,3-bis(4-pyridyl)propane] has been synthesized via the hydrothermal method. Single crystal structural analysis exhibits that a novel 2D complicated framework comprised of two kinds of infinite 1D zigzag chains was stabilized by chains through hydrogen bonding, and π-π stacking interaction, which aggregate together to give birth to the 3D network structure via the C-H…O interaction.
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Zhao, B., Cheng, P., Chen, X.Y., et al., J. Am. Chem. Soc., 2004, vol. 126, p. 3012.
Leininger, S., Olenyuk, B., and Stang, P.J., Chem. Rev., 2000, vol. 100, p. 853.
Wang, J.J., Gou, L., Hu, H.M., et al., Cryst. Growth. Des., 2007, vol. 7, no. 8, p. 1514.
Yin, P.X., Zhang, J., Li, Z.J., et al., Inorg. Chem. Commun., 2008, vol. 11, p. 134.
Chen, Q.Y., Li, Y., Zou, W.Q., et al., Inorg. Chem. Commun., 2008, vol. 11, p. 969.
Bai, Y.Y., Huang, Y., Yan, B., et al., Inorg. Chem. Commun., 2008, vol. 11, p. 1030.
Ding, J.G., Liu, X.G., Li, B.L., et al., Inorg. Chem. Commun., 2008, vol. 11, p. 1079.
Xiao, B., Hou, H.W., Fan, Y.T., and Tang, M.S., Inorg. Chem. Commun., 2007, vol. 10, p. 376.
Hou, H.W., Li, L. K., and Li, G., Inorg. Chem., 2003, vol. 42, p. 3501.
Lin, J.G., Wen, L.L., Zang, S.Q., et al., Inorg. Chem. Commun., 2007, vol. 10, p. 74.
Gao, E.J., Sun, Y.G., Gu, X.F., et al., Chin. J. Struct. Chem., 2008, vol. 24, no. 11, p. 1298.
Feng, Xia, Tang, Z.W., Fong, Y.L., and Lan, Y.Z., Chin. J. Struct. Chem., 2008, vol. 24, no. 10, p. 1713.
Chen, B.Y., Meng, X.R., Li, L.K., and Hou, H.W., Chin. J. Struct. Chem., 2003, vol. 19, no. 3, p. 295.
Ying, T., Jian, R.L., Qun, Yu., et al., CrystEngComm., 2008, vol. 10, p. 699.
Gao, E.J., Yu, Y., Wang, K.H., et al., Chin. J. Struct. Chem., 2006, vol. 25, no. 10, p. 1265.
Gao, E.J., Wang, K.H., Gu, X.F., et al., J. Inorg. Biochem., 2007, vol. 101, p. 1404.
Gao, E.J., Yin, H.X., Zhang, W.Z., et al., Russ. J. Coord. Chem., 2008, vol. 34, no. 7, p. 516.
Gao, E.J., Sun, Y.G., Wei, D.Z., and Wang, C.S., Chin. J. Struct. Chem., 2006, vol. 25, no. 5, p. 594.
Korybut-Daszkiewicz, B., Wieckowska, A., Bilewicz, R., et al., J. Am. Chem. Soc., 2001, vol. 123, p. 9356.
Gao, E.J., Sun, Y.G., Gu, X.F., and Chen, S.D., Chin. J. Struct. Chem., 2006, vol. 25, no. 12, p. 1431.
Li, F., Wang, Y.L., Li, G.S., et al., Inorg. Chem. Commun., 2007, vol. 10, p. 767.
Jiang-Gao Mao, Zhike Wang, and Clearfield, A., Inorg. Biochem., 2002, vol. 41, p. 6160.
Gu, X.F., Sun, Y.G., Gao, E.J., and Yan, X.M., Chin. J. Struct. Chem., 2008, vol. 27, no. 1, p. 112.
Sheldrick, G.M., SHELXS-97, Program for Crystal Structure Refinement, Göttingen (Germany): Univ. of Göttingen, 1997.
Sheldrick, G.M., SHELXS-97, Program for Crystal Structure Solution, Göttingen (Germany): Univ. of Göttingen, 1997.
Sun, Y.F., Cui, Y.P., Wu, R.T., et al., Chin. J. Struct. Chem., 2008, vol. 27, no. 1, p. 39.
Lin, J.G., Zang, S.Q., Tian, Z.F., et al., Cryst. Eng. Commun., 2007, vol. 9, p. 915.
Lei Han and Yan Zhou, Inorg. Chem. Commun., 2008, vol. 11, p. 385.
Gao, E.J., Huang, Y., Zhu, M.C., and Wang, L., Inorg. Chem. Commun., 2009, vol. 12, p. 872.
Zhang, J., Li, Z.J., Qin, Y.Y., et al., Chin. J. Struct. Chem., 2004, vol. 23, no. 12, pp. 1366.
Liu J.Q., Wang, Y.Y., Liu, P., et al., Inorg. Chem. Commun., 2007, vol. 10, p. 343.
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Gao, E.J., Guo, M.J., Zhang, Y.X. et al. Synthesis and crystal structure of a novel coordination polymer: {[Zn2(6-Pydc)2(Bpp)2] · 4H2O}n . Russ J Coord Chem 36, 923–928 (2010). https://doi.org/10.1134/S1070328410120109
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DOI: https://doi.org/10.1134/S1070328410120109