Abstract
A new vic-dioxime, N-{4-[[(2-hydroxyphenyl)methylene]hydrazinecarbonyl]phenyl}aminoglyoxime (H3L), was prepared by the reaction of anti-chloroglyoxime with salicylaldehyde 4-aminobenzoylhydrazone. The reaction of H3L with Cu(II) salts and an appropriate simple ligand gave only homotrinuclear complexes [Cu3(HL)2X2], whereas the reaction of H3L with Ni(II) salts gave mono-and homotrinuclear complexes [Ni(H2L)2 and Ni3(HL)2X2]. Also, heterotrinuclear complexes of H3L were prepared by the reaction of Ni(H2L)2 with Cu(II) salt and an appropriate simple ligand, [NiCu2(HL)2X2], X = Cl−, NO −3 , SCN−, CN−, and N −3 . The new vic-dioxime and its complexes were identified by elemental analyses, IR, 1H NMR, UV-VIS, magnetic susceptibility, and mass spectral data. The elemental analyses and spectral data indicated that the hydrazone side of H3L acted as monobasic tridentate and the fourth position was occupied by simple ligands, such as Cl−, NO −3 , SCN−, CN−, and N −3 .
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Martin, E.M., Bereman, R.D., and Singh, P., Inorg. Chim Acta, 1991, vol. 30, no. 5, p. 957.
Kahn, O., Angew. Chem. Int. Ed. Engl., 1985, vol. 24, no. 10, p. 834.
Simmons, M.G., Merril, C.K., Wilson, L.J., et al., J. Chem. Soc., Dalton Trans., 1980, no. 10, p. 1827.
Prushan, M.J., Addison, A.W., and Butcher, R.J., Inorg. Chim. Acta, 2000, vol. 300–302, p. 992.
Smith, A.G., Tasker, P.A., and White, D.J., Coord. Chem. Rev., 2003, vol. 241, nos. 1–2, p. 61.
Valkert, W.A. and Hoffman, T.J., Chem. Rev., 1999, vol. 99, no. 9, p. 2269.
Cheng, M.Y., De, B., Almstead, N.G., et al., J. Med. Chem., 1999, vol. 22, no. 26, p. 5426.
Angeloff, A., Daran, J.C., Bernadou, J., and Meunier, B., Eur. J. Inorg. Chem., 2000, vol. 9, p. 1985.
Kitajima, N. and Morovka, Y., Chem. Rev., 1994, vol. 94, no. 3, p. 737.
Kukushkin, V.Y. and Pombeiro, A.J.L., Coord. Chem. Rev., 1999, vol. 181, p. 147.
Kukushkin, V.Y., Tudela, D., and Pombeiro, A.J.L., Coord. Chem. Rev., 1996, vol. 156, p. 333.
Voloshin, Y.Z., Kostromina, N.A., and Kramer, R., Chlatrochelates: Synthesis, Structure and Properties, Amsterdam: Elsevier, 2002, p. 419.
Foulds, G.A., Coord. Chem. Rev., 1997, vol. 162, p. 1.
Garnovskii, A.D. and Kharisov, B.I., Synthetic Coordination and Organometallic Chemistry, New York-Basel: Marcel Dekker, 2003, p. 520.
Chaudhuri, P., Coord. Chem. Rev., 2003, vol. 243, p. 143.
Fenton, D.E., Biocoordination Chemistry, Oxford: Oxford Univ. Press, 1997.
Kurse, S. and Motomizu, K.T., Anal. Chim. Acta, 1974, vol. 70, p. 65.
Rockenbauer, A., Gyor, M., Kwiecinski, M., and Tyrlik, S., Inorg. Chim. Acta, 1982, vol. 58, p. 237.
Nemeth, S. and Simondi, L., J. Mol. Catal., 1982, vol. 14, p. 87.
White, G.S. and Stephan, D.W., Inorg. Chem., 1985, vol. 24, p. 1499.
Koh, L.L., Kon, O.L., Loh, K.W., et al., J. Inorg. Biochem., 1998, vol. 72, p. 155.
Ven Reyk, D., Sarel, S., and Hunt, N., Biochem. Pharmacol., 2000, vol. 60, no 4, p. 581.
Chon, C., Koh, L.L., Leung, P.H., et al., Inorg. Chim. Acta, 1995, vol. 236, no. 1, p. 27.
Ainscough, E.W., Brodie, A.M., Dobbs, A.J., and Ranford, J.D., Inorg. Chim. Acta, 1998, vol. 267, no. 1, p. 27.
Brintzinger, H. and Titzmann, R., Chem. Ber., 1952, vol. 85, no. 4, p. 344.
Ainscough, E.W., Brodie, A.M., Denny, W.A., et al., J. Inorg. Biochem., 1999, vol. 77, p. 125.
Komurcu, S.G., Rollas, S., Ulgen, M., et al., Bull. Chim. Fermaccutico, 1995, vol. 134, no. 7, p. 375.
Saha, M.K., Sen, S., Gupta, T., and Mitra, S., Transition Met. Chem. (London), 1998, vol. 23, p. 635.
Voloshin, Y.Z., Varzatskii, O.A., Strizhakova, N.G., and Tkachenko, E.Y., Inorg. Chim. Acta, 2000, vol. 299, no. 1, p. 104.
Voloshin, Y.Z., Varzatskii, O.A., Stash, A.I., et al., Polyhedron, 2001, vol. 20, no. 21, p. 2721.
Bilgin, A., Serbest, K., and Gök, Y., Transition Met. Chem. (London), 2000, vol. 25, no. 1, p. 63.
Ramanujan, V.V. and Alexander, V., Inorg. Chem., 1987, vol. 26, no. 19, p. 3124.
Silverstein, R.M., Bassler, G.C., and Morrill, T.C., Spectrometric Identification of Organic Compounds, New York: Willey, 1991.
Alexander, V. and Ramanujam, V.V., Inorg. Chim. Acta, 1989, vol. 156, no. 1, p. 125.
Gup, R. and Beduk, A.D., Synth. React. Inorg. Met.-Org. Chem., 2002, vol. 32, no. 6, p. 1043.
Canpolat, E., Kaya, M., and Yazc, A., Russ. J. Coord. Chem., 2004, vol. 30, no. 2, p. 95.
Sreeja, P.B., Prathapochondra, K., Kishare, A., and Jasmin, C., Polyhedron, 2003, vol. 645, nos. 2–3, p. 221.
Gök, Y. and Kantekin, H., Chem. Ber., 1990, vol. 123, p. 1479.
Gök, Y., Karabocek, S., Karabocek, N., and Atalay, Y., New. J. Chem., 1995, vol. 19, p. 1275.
Singh, B., Narang, K.K., and Srivastava, R., Synth. React. Inorg. Met.-Org. Chem., 2002, vol. 32, no. 9, p. 1561.
Calinescu, M., Emandi, A., Serban, I., and Pop, V., Synth. React. Inorg. Met.-Org. Chem., 2003, vol. 33, no. 10, p. 1927.
Sreekanth, A., Maliyeckal, R., and Kurup, P., Polyhedron, 2003, vol. 22, nos. 25–26, p. 3321.
Gupta, R., Lal, T.P., and Mukherjee, R., Polyhedron, 2002, vol. 21, nos. 12–13, p. 1245.
Gul, A. and Bekaroglu, O., J. Chem. Soc., Dalton Trans., 1983, no. 12, p. 2537.
Lewer, A.B.P., Inorganic Electronic Spectroscopy, Amsterdam: Elsevier, 1984.
Kandaz, M., Yilmaz, I., Keskin, S., and Koca, A., Polyhedron, 2002, vol. 21, no. 8, p. 825.
Karaböcek, N. and Karaböcek, S., Transition Met. Chem. (London), 1999, vol. 24, p. 84.
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Gup, R. A new unsymmetrical vic-dioxime bearing salicylaldehyde 4-aminobenzoylhydrazone and its homo-and heterotrinuclear complexes with copper(II) and nickel(II) ions. Russ J Coord Chem 32, 99–108 (2006). https://doi.org/10.1134/S1070328406020047
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DOI: https://doi.org/10.1134/S1070328406020047