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Growth from Solutions, Structure, and Photoluminescence of Single-Crystal Plates of p-Terphenyl and Its Trimethylsilyl Derivative

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Abstract

Samples of single-crystal plates of p-terphenyl (3Р) and its derivative with terminal substituents–Si(CH3)3 (TMS-3P-TMS), up to 25–30 mm in size and 400 μm thick, have been obtained for the first time by the solvent–antisolvent growth method. The crystal structure at temperatures of 293 and 85 K is refined for 3Р and solved (for the first time) for TMS-3P-TMS using X-ray diffraction. The habit of crystals and their surface morphology are investigated by methods of optical and laser confocal microscopy. The influence of substituent terminal groups -Si(CH3)3 on the growth and structure of TMS-3P-TMS crystals is analyzed based on experimental data. The optical absorption and photoluminescence spectra of solutions and crystalline samples are investigated.

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Authors and Affiliations

  1. Shubnikov Institute of Crystallography, Federal Scientific Research Centre “Crystallography and Photonics,”, Russian Academy of Sciences, Moscow, 119333, Russia

    V. A. Postnikov, N. I. Sorokina, O. A. Alekseeva, A. A. Kulishov, M. S. Lyasnikova, V. V. Grebenev & A. E. Voloshin

  2. Moscow Technological University (MITHT), Moscow, 119571, Russia

    R. I. Sokolnikov

  3. Enikolopov Institute of Synthetic Polymer Materials, Russian Academy of Sciences, Moscow, 117393, Russia

    O. V. Borshchev, M. S. Skorotecky, N. M. Surin, E. A. Svidchenko & S. A. Ponomarenko

  4. Smart Engines Ltd., Moscow, 117321, Russia

    V. A. Postnikov

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  1. V. A. Postnikov
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  2. N. I. Sorokina
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  3. O. A. Alekseeva
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  4. A. A. Kulishov
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  6. M. S. Lyasnikova
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  7. V. V. Grebenev
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  8. O. V. Borshchev
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  9. M. S. Skorotecky
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  10. N. M. Surin
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  11. E. A. Svidchenko
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  12. S. A. Ponomarenko
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  13. A. E. Voloshin
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Correspondence to V. A. Postnikov.

Additional information

Original Russian Text © V.A. Postnikov, N.I. Sorokina, O.A. Alekseeva, A.A. Kulishov, R.I. Sokolnikov, M.S. Lyasnikova, V.V. Grebenev, O.V. Borshchev, M.S. Skorotecky, N.M. Surin, E.A. Svidchenko, S.A. Ponomarenko, A.E. Voloshin, 2018, published in Kristallografiya, 2018, Vol. 63, No. 5, pp. 801–814.

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Postnikov, V.A., Sorokina, N.I., Alekseeva, O.A. et al. Growth from Solutions, Structure, and Photoluminescence of Single-Crystal Plates of p-Terphenyl and Its Trimethylsilyl Derivative. Crystallogr. Rep. 63, 819–831 (2018). https://doi.org/10.1134/S1063774518050243

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  • DOI: https://doi.org/10.1134/S1063774518050243

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