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On Conditions of Formation of Hollow Particles by an Interpolylectrolyte Complex

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Abstract

Interpolyelectrolyte complexes formed by linear oppositely charged macromolecules with different affinities for a solvent are studied for the first time using the computer experiment method. It is shown that such complexes self-organize into structures, on the surface of which solvophilic groups are predominantly located. These can be dense spherical particles, hollow vesicle-like particles, and hollow particles with perforated shells. The detailed structure of the obtained morphologies is determined.

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ACKNOWLEDGMENTS

This work was performed using the equipment of the shared research facilities of HPC computing resources at Lomonosov Moscow State University [44].

Funding

The study was supported by the Russian Science Foundation (project 18-73-00335). V.V. Vasilevskaya thanks the Ministry of Science and Higher Education of the Russian Federation.

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Authors and Affiliations

  1. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 119991, Moscow, Russia

    A. A. Glagoleva & V. V. Vasilevskaya

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  1. A. A. Glagoleva
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  2. V. V. Vasilevskaya
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Correspondence to A. A. Glagoleva or V. V. Vasilevskaya.

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Glagoleva, A.A., Vasilevskaya, V.V. On Conditions of Formation of Hollow Particles by an Interpolylectrolyte Complex. Polym. Sci. Ser. A 61, 780–788 (2019). https://doi.org/10.1134/S0965545X19060038

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  • DOI: https://doi.org/10.1134/S0965545X19060038

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