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Effect of hexagonal boron nitride on poly(vinyl phosphonic acid) composite polymer electrolytes for fuel cells

  • Polymer Membranes
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Abstract

In this work, hexagonal boron nitride nanoparticles were used as inorganic fillers, which increase the mechanical and thermal stabilities as well as the proton conductivity of the proton conducting composite membranes prepared by blending of poly(vinyl phosphonic acid) and hexagonal boron nitride. Thermo gravimetric analysis showed that the polymer electrolyte membranes are thermally stable up to 200°C. Scanning electron microscopy analysis indicated the homogeneous distribution of boron nitride nanoparticles in the polymer matrix. The crystallinity of the membranes was characterized by using X-ray Diffraction. X-ray patterns support semi-crystalline nature of the composite materials.

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References

  1. A. Aslan and A. Bozkurt, Solid State Ionics 255, 89 (2014).

    Article  CAS  Google Scholar 

  2. A. Taguet, P. Cassagnau, and J. M. Lopez-Cuesta, Prog. Polym. Sci. 39, 1526 (2014).

    Article  CAS  Google Scholar 

  3. A. Aslan and A. Bozkurt, J. Power Sources 217, 158 (2012).

    Article  CAS  Google Scholar 

  4. H. Wu, W. Hou, J. Wang, L. Xiaoa, and Z. Jiang, J. Power Sources 195, 4104 (2010).

    Article  CAS  Google Scholar 

  5. S. Park and R. S. Ruoff, Nat. Nanotechnol. 4, 217 (2009).

    Article  CAS  Google Scholar 

  6. A. Aslan, K. Golcuk, and A. Bozkurt, J. Polym. Res. 19, 1 (2014).

    Google Scholar 

  7. A. Pakdel, Y. Bando, and D. Golberg, Chem. Soc. Rev. 3, 934 (2014).

    Article  Google Scholar 

  8. A. Pakdel, Y. Bando, and D. Golberg, ACS Nano 8, 10631 (2014).

    Article  CAS  Google Scholar 

  9. X. Hou, Z. Yu, Y. Li, and K. C. Chou, Mater. Res. Bull. 49, 39 (2014).

    Article  CAS  Google Scholar 

  10. A. Pakdel, C. Zhi, Y. Bando, and D. Golberg, Mater. Today 15, 256 (2012).

    Article  CAS  Google Scholar 

  11. C. Zhi, Y. Bando, C. Tang, H. Kuwahara, and D. Golberg, Adv. Mater. 21, 2889 (2009).

    Article  CAS  Google Scholar 

  12. S. Kemaloglu, G. Ozkoc, and A. Aytac, Thermochim. Acta 499, 40 (2010).

    Article  CAS  Google Scholar 

  13. J. Yu, X. Huang, C. Wu, X. Wu, G. Wang, and P. Jiang, Polymer 53, 471 (2012).

    Article  CAS  Google Scholar 

  14. Y. Wang, Z. X. Shi, and J. Yin, J. Mater. Chem. 21, 11371 (2011).

    Article  CAS  Google Scholar 

  15. R. S. Pease, Acta Crystallogr. 5, 356 (1952).

    Article  CAS  Google Scholar 

  16. S. Madakbas, E. Cakmakci, and M. V. Kahraman, Thermochim. Acta 552, 1 (2013).

    Article  CAS  Google Scholar 

  17. V. Salles, S. Bernard, R. Chiriac, and P. Miele, J. Eur. Ceram. Soc. 32, 1867 (2012).

    Article  CAS  Google Scholar 

  18. T. L. Li, S. Lien, and C. Hsu, J. Phys. Chem. B 114, 6825 (2010).

    Article  CAS  Google Scholar 

  19. J. H. Warner, M. H. Rummeli, A. Bachmatiuk, and B. Buchner, ACS Nano 4, 1299 (2010).

    Article  CAS  Google Scholar 

  20. T. Sainsbury, A. Satti, P. May, Z. Wang, I. McGovern, Y. K. Gunko, and J. Coleman, J. Am. Chem. Soc. 134, 18758 (2012).

    Article  CAS  Google Scholar 

  21. Y. Lin, T. V. Williams, and J. W. Connell, J. Phys. Chem. Lett. 1, 277 (2010).

    Article  Google Scholar 

  22. J. P. Hong, S. W. Yoon, T. Hwang, J. S. Oh, S. C. Hong, Y. Lee, and J. D. Nam, Thermochim. Acta 537, 70 (2012).

    Article  CAS  Google Scholar 

  23. D. Sinirlioglu, S. U. Celik, A. E. Muftuoglu, and A. Bozkurt, Polym. Eng. Sci. 55, 260 (2015).

    Article  CAS  Google Scholar 

  24. A. Jayakumar, S. S. Pethaiah, M. Ramos, J. Robertson, and A. A. Jumaily, Ionics 21, 1 (2015).

    Article  CAS  Google Scholar 

  25. D. Sinirlioglu and A. E. Muftuoglu, J. Polym. Res. 22, 232 (2015).

    Article  Google Scholar 

  26. S. U. Celik, A. Bozkurt, and S. S. Hosseini, Prog. Polym. Sci. 37, 1265 (2012).

    Article  CAS  Google Scholar 

  27. D. Sinirlioglu, A. E. Muftuoglu, K. Golcuk K, and A. Bozkurt, J. Polym. Sci., Part A: Polym.Chem. 52, 1885 (2014).

    Article  CAS  Google Scholar 

  28. D. Sinirlioglu, S. U. Celik, A. E. Muftuoglu, and A. Bozkurt, Macromol. Chem. Phys. 215, 269 (2014).

    Article  CAS  Google Scholar 

  29. D. Sasa, D. Sinirlioglu, A. E. Muftuoglu, F. Eren, S. U. Celik, and A. Bozkurt, J. Polym. Res. 20, 313 (2013).

  30. L. Geng, Y. He, D. Liu, and C. Lü, J. Appl. Polym. Sci. 123, 3164 (2012).

  31. X. Huang, H. Cao, Z. Shi, H. Xu, J. Fang, J. Yin, and Q. Pan, J. Mater. Sci.: Mater. Med. 21, 1829, (2010).

    CAS  Google Scholar 

  32. M. T. Huang and H. Ishida, Surf. Interface Anal. 37, 621 (2005).

    Article  CAS  Google Scholar 

  33. N. I. Kovtyukhova, Y. Wang, R. Lv, M. Terrones, V. H. Crespi, and T. E. Mallouk, J. Am. Chem. Soc. 135, 8372 (2013).

    Article  CAS  Google Scholar 

  34. K. H. Oh, D. Lee, M. J. Choo, K. H. Park, S. Jeon, S. H. Hong, J. K. Park, and J. W. Choi, ACS Appl. Mater. Interfaces 6, 7751 (2014).

    Article  CAS  Google Scholar 

  35. M. Akel, S. U. Celik, A. Bozkurt, and A. Ata, Polym. Compos. 37 (2), 422 (2016).

    Article  CAS  Google Scholar 

  36. M. S. Tutgun, D. Sinirlioglu, S. U. Celik, and A. Bozkurt, J. Polym. Res. 22, 47 (2015).

    Article  Google Scholar 

  37. K. Z. Ekinci, S. U. Celik, and A. Bozkurt, Int. J. Polym. Mater. 64, 683 (2015).

    Article  CAS  Google Scholar 

  38. B. Bingöl, W. H. Meyer, M. Wagner, and G. Wegner, Macromol. Rapid. Commun. 27, 1719 (2006).

    Article  Google Scholar 

  39. H. Steininger, M. Schuster, K. D. Kreuer, A. Kaltbeitzel, B. Bingöl, W. H. Meyer, S. Schauff, G. Brunklaus, J. Maier, and H. W. Spiess, Phys. Chem. Chem. Phys. 9, 1764 (2007).

    Article  CAS  Google Scholar 

  40. C. Y. Zhi, Y. Bando, C. C. Tang, H. Kuwahara, and D. Golberg, Adv. Mater. 21, 2889 (2009).

    Article  CAS  Google Scholar 

  41. P. Dibandjo, L. Bois, F. Chassagneux, D. Cornu, J. M. Letoffe, and B. Toury, Adv. Mater. 17, 571 (2005).

    Article  CAS  Google Scholar 

  42. S. U. Celik, U. Akbey, R. Graf, A. Bozkurt, and H. W. Spiess, Phys. Chem. Chem. Phys. 10, 6058 (2008).

    Article  CAS  Google Scholar 

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Correspondence to M. S. Tutgun.

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Tutgun, M.S., Sinirlioglu, D., Celik, S.U. et al. Effect of hexagonal boron nitride on poly(vinyl phosphonic acid) composite polymer electrolytes for fuel cells. Polym. Sci. Ser. A 58, 810–817 (2016). https://doi.org/10.1134/S0965545X16050205

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  • DOI: https://doi.org/10.1134/S0965545X16050205

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