Abstract
In this work, hexagonal boron nitride nanoparticles were used as inorganic fillers, which increase the mechanical and thermal stabilities as well as the proton conductivity of the proton conducting composite membranes prepared by blending of poly(vinyl phosphonic acid) and hexagonal boron nitride. Thermo gravimetric analysis showed that the polymer electrolyte membranes are thermally stable up to 200°C. Scanning electron microscopy analysis indicated the homogeneous distribution of boron nitride nanoparticles in the polymer matrix. The crystallinity of the membranes was characterized by using X-ray Diffraction. X-ray patterns support semi-crystalline nature of the composite materials.
Similar content being viewed by others
References
A. Aslan and A. Bozkurt, Solid State Ionics 255, 89 (2014).
A. Taguet, P. Cassagnau, and J. M. Lopez-Cuesta, Prog. Polym. Sci. 39, 1526 (2014).
A. Aslan and A. Bozkurt, J. Power Sources 217, 158 (2012).
H. Wu, W. Hou, J. Wang, L. Xiaoa, and Z. Jiang, J. Power Sources 195, 4104 (2010).
S. Park and R. S. Ruoff, Nat. Nanotechnol. 4, 217 (2009).
A. Aslan, K. Golcuk, and A. Bozkurt, J. Polym. Res. 19, 1 (2014).
A. Pakdel, Y. Bando, and D. Golberg, Chem. Soc. Rev. 3, 934 (2014).
A. Pakdel, Y. Bando, and D. Golberg, ACS Nano 8, 10631 (2014).
X. Hou, Z. Yu, Y. Li, and K. C. Chou, Mater. Res. Bull. 49, 39 (2014).
A. Pakdel, C. Zhi, Y. Bando, and D. Golberg, Mater. Today 15, 256 (2012).
C. Zhi, Y. Bando, C. Tang, H. Kuwahara, and D. Golberg, Adv. Mater. 21, 2889 (2009).
S. Kemaloglu, G. Ozkoc, and A. Aytac, Thermochim. Acta 499, 40 (2010).
J. Yu, X. Huang, C. Wu, X. Wu, G. Wang, and P. Jiang, Polymer 53, 471 (2012).
Y. Wang, Z. X. Shi, and J. Yin, J. Mater. Chem. 21, 11371 (2011).
R. S. Pease, Acta Crystallogr. 5, 356 (1952).
S. Madakbas, E. Cakmakci, and M. V. Kahraman, Thermochim. Acta 552, 1 (2013).
V. Salles, S. Bernard, R. Chiriac, and P. Miele, J. Eur. Ceram. Soc. 32, 1867 (2012).
T. L. Li, S. Lien, and C. Hsu, J. Phys. Chem. B 114, 6825 (2010).
J. H. Warner, M. H. Rummeli, A. Bachmatiuk, and B. Buchner, ACS Nano 4, 1299 (2010).
T. Sainsbury, A. Satti, P. May, Z. Wang, I. McGovern, Y. K. Gunko, and J. Coleman, J. Am. Chem. Soc. 134, 18758 (2012).
Y. Lin, T. V. Williams, and J. W. Connell, J. Phys. Chem. Lett. 1, 277 (2010).
J. P. Hong, S. W. Yoon, T. Hwang, J. S. Oh, S. C. Hong, Y. Lee, and J. D. Nam, Thermochim. Acta 537, 70 (2012).
D. Sinirlioglu, S. U. Celik, A. E. Muftuoglu, and A. Bozkurt, Polym. Eng. Sci. 55, 260 (2015).
A. Jayakumar, S. S. Pethaiah, M. Ramos, J. Robertson, and A. A. Jumaily, Ionics 21, 1 (2015).
D. Sinirlioglu and A. E. Muftuoglu, J. Polym. Res. 22, 232 (2015).
S. U. Celik, A. Bozkurt, and S. S. Hosseini, Prog. Polym. Sci. 37, 1265 (2012).
D. Sinirlioglu, A. E. Muftuoglu, K. Golcuk K, and A. Bozkurt, J. Polym. Sci., Part A: Polym.Chem. 52, 1885 (2014).
D. Sinirlioglu, S. U. Celik, A. E. Muftuoglu, and A. Bozkurt, Macromol. Chem. Phys. 215, 269 (2014).
D. Sasa, D. Sinirlioglu, A. E. Muftuoglu, F. Eren, S. U. Celik, and A. Bozkurt, J. Polym. Res. 20, 313 (2013).
L. Geng, Y. He, D. Liu, and C. Lü, J. Appl. Polym. Sci. 123, 3164 (2012).
X. Huang, H. Cao, Z. Shi, H. Xu, J. Fang, J. Yin, and Q. Pan, J. Mater. Sci.: Mater. Med. 21, 1829, (2010).
M. T. Huang and H. Ishida, Surf. Interface Anal. 37, 621 (2005).
N. I. Kovtyukhova, Y. Wang, R. Lv, M. Terrones, V. H. Crespi, and T. E. Mallouk, J. Am. Chem. Soc. 135, 8372 (2013).
K. H. Oh, D. Lee, M. J. Choo, K. H. Park, S. Jeon, S. H. Hong, J. K. Park, and J. W. Choi, ACS Appl. Mater. Interfaces 6, 7751 (2014).
M. Akel, S. U. Celik, A. Bozkurt, and A. Ata, Polym. Compos. 37 (2), 422 (2016).
M. S. Tutgun, D. Sinirlioglu, S. U. Celik, and A. Bozkurt, J. Polym. Res. 22, 47 (2015).
K. Z. Ekinci, S. U. Celik, and A. Bozkurt, Int. J. Polym. Mater. 64, 683 (2015).
B. Bingöl, W. H. Meyer, M. Wagner, and G. Wegner, Macromol. Rapid. Commun. 27, 1719 (2006).
H. Steininger, M. Schuster, K. D. Kreuer, A. Kaltbeitzel, B. Bingöl, W. H. Meyer, S. Schauff, G. Brunklaus, J. Maier, and H. W. Spiess, Phys. Chem. Chem. Phys. 9, 1764 (2007).
C. Y. Zhi, Y. Bando, C. C. Tang, H. Kuwahara, and D. Golberg, Adv. Mater. 21, 2889 (2009).
P. Dibandjo, L. Bois, F. Chassagneux, D. Cornu, J. M. Letoffe, and B. Toury, Adv. Mater. 17, 571 (2005).
S. U. Celik, U. Akbey, R. Graf, A. Bozkurt, and H. W. Spiess, Phys. Chem. Chem. Phys. 10, 6058 (2008).
Author information
Authors and Affiliations
Corresponding author
Additional information
The article is published in the original.
Rights and permissions
About this article
Cite this article
Tutgun, M.S., Sinirlioglu, D., Celik, S.U. et al. Effect of hexagonal boron nitride on poly(vinyl phosphonic acid) composite polymer electrolytes for fuel cells. Polym. Sci. Ser. A 58, 810–817 (2016). https://doi.org/10.1134/S0965545X16050205
Received:
Revised:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S0965545X16050205