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Phase state and rheology of polyisobutylene mixtures with decyl surface modified silica nanoparticles

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An Erratum to this article was published on 23 January 2015

Abstract

The miscibility of linear polyisobutylene and silica nanoparticles with surfaces modified by decyl groups is studied. The phase state of these systems corresponds to the amorphous equilibrium and may be described by a binodal with the UCST. As the radius of the inorganic core of nanoparticles and the molecular mass of polyisobutylene increase, the insolubility region on the phase diagram becomes wider. The addition of nanoparticles to the polymer leads to decreases in the viscoelastic characteristics of homogeneous media and provides the non-Newtonian behavior of the composition in the two-phase region. Shear deformation causes shifts of the phase equilibrium lines in the direction depended on the sizes of the nanoparticles.

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Authors and Affiliations

  1. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Leninskii pr. 29, Moscow, 119991, Russia

    E. A. Karpukhina, S. O. Il’in, V. V. Makarova & V. G. Kulichikhin

  2. Enikolopov Institute of Synthetic Polymer Materials, Russian Academy of Sciences, Profsoyuznaya ul. 70, Moscow, 117393, Russia

    I. B. Meshkov

Authors
  1. E. A. Karpukhina
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  2. S. O. Il’in
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  3. V. V. Makarova
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  4. I. B. Meshkov
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  5. V. G. Kulichikhin
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Correspondence to S. O. Il’in.

Additional information

Original Russian Text © E.A. Karpukhina, S.O. Il’in, V.V. Makarova, I.B. Meshkov, V.G. Kulichikhin, 2014, published in Vysokomolekulyarnye Soedineniya. Ser. A, 2014, Vol. 56, No. 6, pp. 670–684.

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Karpukhina, E.A., Il’in, S.O., Makarova, V.V. et al. Phase state and rheology of polyisobutylene mixtures with decyl surface modified silica nanoparticles. Polym. Sci. Ser. A 56, 798–811 (2014). https://doi.org/10.1134/S0965545X14060066

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  • DOI: https://doi.org/10.1134/S0965545X14060066

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