Abstract
Process parameters of the polymerization of a mixture of exo,exo- and endo,endo-dimethyl esters of norbornene-2,3-dicarboxylic acid in the bulk of the monomer under the action of a ruthenium catalyst of the Hoveyda–Grubbs type are developed. The effect of the concentration of the catalyst on the physical and mechanical properties of poly(norbornene-2,3-dicarboxylic acid dimethyl ester) is studied.
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REFERENCES
Savin, S.P., The use of up-to-date polymeric composite materials in the design of airframes for MS-21 airplanes, Izv. Samar. Nauchn. Tsentra Ross. Akad. Nauk, 2012, vol. 14, no. 4 (2), pp. 686–693.
Yang, J.-X., Cui, J., Long, Y.-Y., Li, Y.-G., and Li, Y.-S., Synthesis of novel cyclic olefin polymers with excellent transparency and high glass-transition temperature via gradient copolymerization of bulky cyclic olefin and cis-cyclooctene, J. Polym. Sci., Part A: Polym. Chem., 2014, vol. 52, no. 22, pp. 3240–3249. https://doi.org/ 10.1002/pola.27386
Hobbs, C.E., Lin, B., and Malinski, T., Norbornene derivatives from a metal-free, strain-promoted cycloaddition reaction: New building blocks for ring-opening metathesis polymerization reactions, J. Polym. Sci., Part A: Polym. Chem., 2015, vol. 53, no. 20, pp. 2357–2362. https://doi.org/10.1002/pola.27691
Mol, J.C., Industrial applications of olefin metathesis, J. Mol. Catal. A: Chem., 2004, vol. 213, no. 1, pp. 39–45. https://doi.org/10.1016/j.molcata.2003.10.049
Gurevich, P.A., Zemlyakov, D.I., Bozhenkova, G.S., and Ashirov, R.V., Effect of ethylene glycol-dinorbornene-5-carboxylate on the glass transition temperature of a polymer based on the dimethyl ethers of exo- and endo-norbornene-2,3-dicarboxylic acids, Vestn. Kazan. Tekhnol. Univ., 2013, vol. 16, no. 11, pp. 155–157.
Zamanova, M.K., Bozhenkova, G.S., Bondaletov, V.G., Samochernova, A.P., and Zemlyakov, D.I., Analytical control for the production of exo,exo- and endo,endo-dimethyl ethers of norbornene-2,3-dicarboxylic acid, Sorbtsionnye Khromatogr. Protsessy, 2016, vol. 16, no. 2, pp. 241–250.
Afanas’ev, V.V., Nizovtsev, A.V., Dolgina, T.M., and Bespalova, N.B., RF Patent 2374269, 2009.
Jang, E.S., John, J.M., and Schrock, R.R., Synthesis of cis,syndiotactic A-alt-B copolymers from two enantiomerically pure trans-2,3-disubstituted-5,6-norbornenes, ACS Cent. Sci., 2016, vol. 2, no. 9, pp. 631–636. https://doi.org/10.1021/acscentsci.6b00200
Gurevich, P.A., Bozhenkova, G.S., Zemlyakov, D.I., and Ashirov, R.V., Effect of a bifunctional comonomer on the physicomechanical properties of a polymer based on polydimethyl-norbornene-2,3-dicarboxylates, Vestn. Kazan. Tekhnol. Univ., 2015, vol. 18, no. 2, pp. 227–230.
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Translated by E. Boltukhina
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Bozhenkova, G.S., Smirnova, N.A., Bragina, O.O. et al. The Development of a Method for the Production of Structural Polymeric Materials on the Basis of Norbornene Derivatives. Theor Found Chem Eng 53, 875–879 (2019). https://doi.org/10.1134/S0040579518050068
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DOI: https://doi.org/10.1134/S0040579518050068