Abstract
Magnetic Fe–Fe3O4/UiO-66 was prepared by hydrogen reduction method and used as the catalyst for catalytic transfer hydrogenation of furfural to furfuryl alcohol with alcohol as the hydrogen donor. The preparation parameters of Fe–Fe3O4/UiO-66 and the effects of reaction conditions on catalytic transfer hydrogenation of furfural were studied in detail. Fe3O4, elementary iron (Fe), and Fe–Fe3O4 mixture from the corresponding iron oxide (FexOy) active components can be formed by controlling the reducing temperature. Compared with UiO-66, when FexOy is a Fe–Fe3O4 mixture, the resulting Fe–Fe3O4/UiO-66 shows the highest activity in catalytic transfer hydrogenation of furfural. Furthermore, Fe–Fe3O4/UiO-66 is easy to separate by a magnetic field and exhibits excellent catalytic recycling performance.
Similar content being viewed by others
REFERENCES
Y. Yang, Z. Ren, S. Zhou, and M. Wei, ACS Catal. 11, 6440 (2021).
F. Zhuo, S. Yan, G. Wen, et al., Mol. Catal. 513, 111824 (2021).
C. P. Jiménez-Gómez, J. A. Cecilia, C. García-Sancho, et al., J. Environ. Chem. Eng. 9, 105468 (2021).
H. Zhang, Z. J. Quek, S. Jaenicke, and G. K. Chuah, J. Catal. 400, 50 (2021).
C. G. Santana and M. J. Krische, ACS Catal. 11, 5572 (2021).
R. Cohen, C. R. Graves, S. B. T. Nguyen, et al., J. Am. Chem. Soc. 126, 14796 (2004).
L. Hu, T. Li, J. Xu, et al., Chem. Eng. J. 352, 110 (2018).
J. Zhang and J. Chen, ACS Sustain. Chem. Eng. 5, 5982 (2017).
C. García-Sancho, C. P. Jiménez-Gómez, N. Viar-Antuñano, et al., Appl. Catal., A 609, 117905 (2021).
P. Hou, M. Ma, P. Zhang, et al., New J. Chem. 45, 2715 (2021).
P. N. Paulino, R. F. Perez, N. G. Figueiredo, and M. A. Fraga, Green Chem. 19, 3759 (2017).
J. Sittiwong, A. Prasertsab, S. Boonmark, et al., Mol. Catal. 504, 111471 (2021).
Z. Zhu, L. Yang, C. Ke, et al., Dalton Trans. 50, 2616 (2021).
A. Ciemięga, K. Maresz, and J. Mrowiec-Białoń, Appl. Catal., A 560, 111 (2018).
J. Song, B. Zhou, H. Zhou, et al., Angew. Chem., Int. Ed. 54, 9399 (2015).
H. P. Winoto, Z. A. Fikri, J. M. Ha, et al., Appl. Catal., B 241, 588 (2019).
J. Song, L. Wu, B. Zhou, et al., Green Chem. 17, 1626 (2015).
X. Tang, H. Chen, L. Hu, et al., Appl. Catal., B 147, 817 (2014).
Q. Shen, X. Li, R. Li, and Y. Wu, ACS Sustain. Chem. Eng. 8, 17608 (2020).
R. Fang, A. Dhakshinamoorthy, Y. Li, and H. Garcia, Chem. Soc. Rev. 49, 3638 (2020).
Y. Kuwahara, H. Kango, and H. Yamashita, ACS Sustain. Chem. Eng. 5, 1141 (2017).
A. H. Valekar, M. Lee, J. W. Yoon, et al., ACS Catal. 10, 3720 (2020).
Y. Wang, J. Huang, S. Lu, et al., New J. Chem. 44, 20308 (2020).
F. Li, S. Jiang, J. Huang, et al., New J. Chem. 44, 478 (2020).
R. Rezaee, M. Montazer, A. Mianehro, and M. Mahmoudirad, Starch-Starke 73, 2100120 (2021).
K. Yu, M. Zeng, Y. Yin, et al., Adv. Eng. Mater. 20, 1700543 (2018).
Y. Zhao, Z. Qiu, and J. Huang, Chin. J. Chem. Eng. 16, 1857 (2008).
R. C. C. Costa, F. C. C. Moura, J. D. Ardisson, et al., Appl. Catal. B 83, 131 (2008).
E. C. Spencer, N. L. Ross, R. E. Olsen, et al., J. Phys. Chem. C 119, 9609 (2015).
C. Chen, D. Chen, S. Xie, et al., ACS Appl. Mater. Interfaces 9, 41043 (2017).
M. J. Gilkey, P. Panagiotopoulou, A. V. Mironenko, et al., ACS Catal. 5, 3988 (2015).
S. Jiang, J. Huang, Y. Wang, et al., J. Chem. Technol. Biotechnol. 96, 639 (2021).
F. Li, W. Zhu, S. Jiang, et al., Int. J. Hydrogen Energy 45, 1981 (2020).
F. Li, L. J. France, Z. Cai, et al., Appl. Catal., B 214, 67 (2017).
J. C. Van der Waal, P. J. Kunkeler, K. Tan, and H. van Bekkum, J. Catal. 173, 74 (1998).
J. M. Rubio-Caballero, S. Saravanamurugan, P. Maireles-Torres, and A. Riisagerl, Catal. Today 234, 233 (2014).
R. Maderuelo-Solera, R. López-Asensio, J. A. Cecilia, et al., Appl. Clay Sci. 183, 105351 (2019).
Funding
The authors acknowledge the financial support from Scientific Research Foundation for Postdoctoral Settlement, Heilongjiang Province of China (grant no. 16190024).
Author information
Authors and Affiliations
Corresponding author
Ethics declarations
The authors declare that they have no conflicts of interest.
Rights and permissions
About this article
Cite this article
Lu, S., Fu, M., Wang, Y. et al. Catalytic Transfer Hydrogenation of Furfural to Furfuryl Alcohol over Magnetic Fe–Fe3O4/UiO-66. Russ. J. Phys. Chem. 96, 2387–2394 (2022). https://doi.org/10.1134/S0036024422110292
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S0036024422110292