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Physical-Chemical Properties of Binary Liquid Mixtures of Isoamyl Alcohol with Chloroethanes at 298–308 K

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Abstract

The density (ρ), viscosity (η), and speed of sound (u) were measured for binary mixtures of 3‑methyl-1-butanol(isoamylalcohol) with 1,2-dichloroethane (DCE), 1,1,2-trichloroethane (TCE), and 1,1,2,2-tetrachloroethane (TECE) over the entire range of mole fractions and at temperature 298.15, 303.15, and 308.15 K. From these measurements, the values of excess molar volume (VE), deviation in viscosity (∆η), deviation in isentropic compressibility (∆ks), excess Gibbs free energy of activation of viscous flow (G*E) and Grunberg−Nissan interaction parameter (d ') have been calculated. The excess parameter deviations have been fitted to Redlich−Kister type polynomial equation using multiparametric nonlinear regression analysis to estimate the binary coefficients and standard deviations. The results were discussed in terms of molecular interactions and dipole-dipole interactions. The effects of temperature and chlorine atoms number of investigated chloroethanes were also studied for the binary mixtures.

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ACKNOWLEDGMENTS

Authors are thankful to university grants commission (UGC), Government of India, for financial support in the form of UGC-JRF.

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Authors and Affiliations

  1. Department of Chemistry, Kakatiya University, 506009, Warangal, India

    T. Savitha Jyostna, B. Satheesh, D. Sreenu, G. Ramesh, G. Sowjanya & R. Suresh

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  1. T. Savitha Jyostna
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  2. B. Satheesh
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  3. D. Sreenu
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  4. G. Ramesh
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  5. G. Sowjanya
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Correspondence to T. Savitha Jyostna.

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Savitha Jyostna, T., Satheesh, B., Sreenu, D. et al. Physical-Chemical Properties of Binary Liquid Mixtures of Isoamyl Alcohol with Chloroethanes at 298–308 K. Russ. J. Phys. Chem. 93, 278–287 (2019). https://doi.org/10.1134/S0036024419020249

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