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An Electron-Deficient Coordination Polymer Based on a Viologen Ligand Accompanying Photochromism, Vaporchromism, and Photoswitchable Luminescence Properties

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Abstract

A novel viologen ligand, 1,1'-bis-(4-carboxybenzyl)-4,4'-bipyridinium- dibromide (H2BpybcBr2), has been synthesized and successfully introduced into cadmium based coordination polymers (CPs) when it reacts with cadmium perchlorate and 5-phenyltetrazole (5-Ph-Ptz) at room temperature. CPs has been characterized with single-crystal X-ray diffraction, powder X-ray diffraction, and thermogravimetric analysis. CP 1 shows high sensitivity to ultraviolet-visible radiation and exhibits the electron-transfer (ET) photochromic properties. Interestingly, CP 1 exhibits photocontrolled luminescence properties during the coloration-decoloration process and can be used to detect ammonia and aniline in solid state.

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Funding

The authors thank the Natural Science Foundation of Heilongjiang Province (QC2014C009), the Fundamental Research Fund for the Heilongjiang Provincial Universities (1353ZD001, 1352MSYYB010), and the Mudanjiang Normal University Key Project (GP2018001).

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Authors and Affiliations

  1. College of Chemistry and Chemical Engineering Mu Danjiang Normal University, 157012, Mu Danjiang, P. R. China

    S. X. Cui, Q. Z. Yin, J. H. Yu & J. Jiang

  2. State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, 130000, Changchun, P. R. China

    Y. C. Zou

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  1. S. X. Cui
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  2. Q. Z. Yin
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Correspondence to S. X. Cui or Y. C. Zou.

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Cui, S.X., Yin, Q.Z., Yu, J.H. et al. An Electron-Deficient Coordination Polymer Based on a Viologen Ligand Accompanying Photochromism, Vaporchromism, and Photoswitchable Luminescence Properties. Russ. J. Inorg. Chem. 65, 874–879 (2020). https://doi.org/10.1134/S0036023620060042

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