Abstract
Cystine forms metal complexes of general formula [MII(C6H10N2O4S2)]; where MII = Mn(II), Co(II), Ni(II), Cu(II), Zn(II), Cd(II), Hg(II), and Pb(II) in the aqueous medium. Before reacting with metal salts the ligand solution was neutralized by NaHCO3 solution. The complexes were formulated by comparing the C, H, N, S and metal analysis data. The prepared complexes were characterized by different physicochemical methods. The UV-vis, FTIR spectral analysis, magnetic susceptibility of these complexes are discussed. Cyclic voltammetric studies of some of the complexes are also reported.
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J. M. Berg, J. L. Tymoczko, and L. Stryer, Biochemistry, 5th ed. (Freeman New York, 2001), p. 41.
F. P. Dwyer and D. P. Mellor, Chelating agents and Metal Chelates (Academic Press, New York, 1964), pp. 343, 387.
S. J. Lippard, Acc. Chem. Res. 6, 282 (1973).
M. Q. Ehsan, M. Jebin, and M. A. Quyser, Ind. J. Chem. A, 38, 826 (1999).
M. Q. Ehsan, S. Z. Haider, K. M. A. Malik, et al., Dhaka Univ. Stud. 35(2), 153 (1988).
M. Q. Ehsan, A. Rudaba, and M. A. Quyser, J. Bangladesh Chem. Soc. 10(2), 195 (1997).
M. Q. Ehsan, J. M. A. Rahman, and M. A. Quyser, J. Bangladesh Chem. Soc. 12(1), 75 (1999).
M. Q. Ehsan, M. Jebin, M. A. Quyser, et al., J. Bangladesh Chem. Soc. 10(1), 31 (1997).
S. Z. Haider, K. M. A. Malik, M. Q. Ehsan, et al., J Bangladesh Acad. Sci. 10(1), 82 (1986).
M. S. Rahman, H. M Nasim Akter, P. K. Bakshi, and M. Q. Ehsan, J. Saudi Chem. Soc. 11(2), 277 (2007).
M. Q. Ehsan, K. M. A. Malik, and S. Z. Haider, J. Bangladesh Acad. Sci. 20(2), 175 (1996).
M. Q. Ehsan, J. M. Arifur Rahman and M. A. Quyser, J. Bangladesh Chem. Soc. 10(2), 187 (1997).
D. L. Pavia, D. L. G.M. Lampman, and G. S. Kriz, Introduction to Spectroscopy (Saunder College Publisher, USA, 1979).
M. R. Silverstein, C. G. Bassler, and C. T. Moril, Spectroscopic Identification of Organic Compounds, 4th Ed. (Wiley, New York, 1971), p. 135.
K. Nakamoto, Infrared and Raman Spectra of Inorganic and Coordination Compounds, 3rd Ed. (Wiley, New York, 1978), p. 211.
L. Lang, Absorption Spectra in the Ultraviolet and Visible Region (Academic Press, New York, 1961).
A. E. Gillam and E. S. Strem, An Introduction to Electronic Absorption Spectroscopy in Organic Chemistry (Arnold, London, 1957).
H. H. Jatte and M. Orchin, Theory and Applications of Ultraviolet Spectroscopy (Wiley, New York, 1962).
A. Earnshaw, Introduction of Magnetochemistry (Academic Press, London, 1968).
G. Foex and C. J. Gorter, Constantes Selectionnees, 7: Diamagnetisme et Paramagnetisme (A Collection of Diamagnetic and Paramagnetic Susceptibilities) (Masson, Paris, 1957).
P. W. Selwood, Magnetochemistry, 2nd Ed. (Interscience, New York, 1956).
K. David and Jr. Gosser, Cyclic Voltammetry, Simulation and Analysis of Reaction Mechanisms (Wiley-VCH, New York, 1993).
A. J. Bard and L. R. Faulkner, Electrochemical Methods, Fundamentals and Applications, (Wiley, New York, 1980).
J. Zhang, Electroanal. Chem. 331, 945 (1972).
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Mamun, M.A., Ahmed, O., Bakshi, P.K. et al. Synthesis and characterization of some metal complexes of cystine: [Mn(C6H10N2O4S2)]; where MII = Mn(II), Co(II), Ni(II), Cu(II), Zn(II), Cd(II), Hg(II) and Pb(II). Russ. J. Inorg. Chem. 56, 1972–1980 (2011). https://doi.org/10.1134/S0036023611120394
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DOI: https://doi.org/10.1134/S0036023611120394