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Synthesis and characterization of Sibunit-supported Pd–Ga, Pd–Zn, and Pd–Ag catalysts for liquid-phase acetylene hydrogenation

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Abstract

Pd/Sibunit and Pd–M/Sibunit (M = Ga, Zn, or Ag) catalysts have been synthesized, and their catalytic properties in liquid-phase acetylene hydrogenation have been investigated. Doping of the palladium catalyst with a metal M leads to the formation of the Pd2Ga, PdZn, or Pd0.46Ag0.54 bimetallic compound. The bimetallic particles are much smaller (1.6–2.0 nm) than the monometallic palladium particles (4.0 nm). Doping with zinc raises the ethylene selectivity by 25% without affecting the activity of the catalyst. Specific features of the effect of each of the dopants on palladium are reported.

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Authors and Affiliations

  1. Institute of Hydrocarbons Processing, Siberian Branch, Russian Academy of Sciences, Omsk, 644040, Russia

    D. V. Glyzdova, N. S. Smirnova, D. A. Shlyapin & P. G. Tsyrul’nikov

  2. Omsk State University, Omsk, 644077, Russia

    D. V. Glyzdova, N. N. Leont’eva & V. I. Vershinin

  3. Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, Novosibirsk, 630090, Russia

    E. Yu. Gerasimov & I. P. Prosvirin

Authors
  1. D. V. Glyzdova
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  2. N. S. Smirnova
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  3. N. N. Leont’eva
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  4. E. Yu. Gerasimov
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  5. I. P. Prosvirin
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  6. V. I. Vershinin
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  7. D. A. Shlyapin
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  8. P. G. Tsyrul’nikov
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Correspondence to D. V. Glyzdova.

Additional information

Original Russian Text © D.V. Glyzdova, N.S. Smirnova, N.N. Leont’eva, E.Yu. Gerasimov, I.P. Prosvirin, V.I. Vershinin, D.A. Shlyapin, P.G. Tsyrul’nikov, 2017, published in Kinetika i Kataliz, 2017, Vol. 58, No. 2, pp. 152–158.

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Glyzdova, D.V., Smirnova, N.S., Leont’eva, N.N. et al. Synthesis and characterization of Sibunit-supported Pd–Ga, Pd–Zn, and Pd–Ag catalysts for liquid-phase acetylene hydrogenation. Kinet Catal 58, 140–146 (2017). https://doi.org/10.1134/S0023158417020057

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  • DOI: https://doi.org/10.1134/S0023158417020057

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