Skip to main content
SpringerLink
Log in

Thermoinduced Structural Transformations of [Fe(hfac)2(THF)2]

  • Published:
Journal of Structural Chemistry Aims and scope Submit manuscript

Abstract

It is found that on cooling from 295 K to 100 K, [Fe(hfac)2(THF)2] crystals undergo reversible phase transitions during which their symmetry changes and one of the unit cell parameters doubles.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Problems of Chemistry and Application of Metal β-Dicetonates [in Russian] / Ed. V. Spitsyn. Nauka: M., 1985.

  2. G. G. Condorelli, G. Malandrino, and I. L. Fragala. Coord. Chem. Rev., 2007, 251, 1931.

    Article  CAS  Google Scholar 

  3. H. Zhang, B. Li, J. Sun, R. Clerac, and E. V. Dikarev. Inorg. Chem., 2008, 47 (21), 10046–10052.

    Article  CAS  Google Scholar 

  4. R. J. Wilson and F. A. Houle. Phys. Rev. Lett., 1985, 55, 2184.

    Article  CAS  Google Scholar 

  5. H. Itoh, T. Takeda, and S. Naka. J. Mater. Sci., 1986, 21, 3677.

    Article  CAS  Google Scholar 

  6. M. Tiitta and L. Niinisto. Chem. Vap. Deposition, 1997, 3, 167.

    Article  CAS  Google Scholar 

  7. B. D. Fahlman and A. R. Barron. Ad. Mater. Opt. Electron., 2000, 10, 223.

    Article  CAS  Google Scholar 

  8. A. Navulla, A. A. Tsirlin, A. M. Abakumov, R. V. Shpanchenko, H. Zhang, and E. V. Dikarev. J. Am. Chem. Soc., 2011, 133, 692.

    Article  CAS  Google Scholar 

  9. F. A. Cotton, G. Wilkinson, C. A. Murillo, and M. Bochmann. Advanced Inorganic Chemistry, 6th Edition. Wiley: Chichester, 1999, 1355.

    Google Scholar 

  10. V. V. Scopenko, A. Yu. Tsivadze, L. I. Savranskii, and A. D. Garnovskii. Koordinatsyonnaya Khimiya [in Russian]. Akademkniga: M., 2007.

  11. Cambridge Structural Database System, Version 5.40, 2018 (updates Feb. 2019).

  12. K. E. Preuss, J. Wu, and M. Jennings. Acta Crystallogr., E, 2005, 61, m430.

    Article  Google Scholar 

  13. G. M. Sheldrick. Acta Cryst., 2015, C71, 3.

    Google Scholar 

Download references

Funding

The study was supported by the Russian Science Foundation grant 17-13-01022.

Author information

Authors and Affiliations

  1. International Tomography Center, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

    G. V. Romanenko, S. V. Fokin, A. S. Bogomyakov & V. I. Ovcharenko

  2. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

    D. P. Pishchur

Authors
  1. G. V. Romanenko
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. S. V. Fokin
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. D. P. Pishchur
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. A. S. Bogomyakov
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. V. I. Ovcharenko
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to G. V. Romanenko.

Ethics declarations

The authors declare that they have no conflict of interests.

Additional information

Russian Text © The Author(s), 2019, published in Zhurnal Strukturnoi Khimii, 2019, Vol. 60, No. 10, pp. 1696–1700.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Romanenko, G.V., Fokin, S.V., Pishchur, D.P. et al. Thermoinduced Structural Transformations of [Fe(hfac)2(THF)2]. J Struct Chem 60, 1630–1634 (2019). https://doi.org/10.1134/S0022476619100081

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0022476619100081

Keywords

Search

Navigation