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Structure Breaking/Making Property of Acefylline Piperazine in Aqueous, Aqueous Methanol, and Aqueous Ethylene Glycol Systems

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Abstract

Densities of acefylline piperazine (AP) in aqueous, aqueous methanol, and aqueous ethylene glycol (10% v/v) systems are determined in the concentration range 0.04-0.14±0.001 mol/dm3 at different temperatures (298.15-318.15 K) with the interval of 5 K. The apparent molar volume (φv), the partial molar volume \((\phi_v^0)\), and the ion-ion interaction parameter (Sv) are calculated using the Masson equation. Partial molar expansibilities \((\phi_E^0)\), which indicate the presence or absence of the caging or packing effect, are also evaluated and discussed. The results are interpreted in terms of solute-solvent and solute-solute interactions of AP in aqueous, aqueous methanol, and aqueous ethylene glycol systems. The structure-breaking and structure-making properties of AP are inferred by the sign of Hepler′s criterion \((\partial^2\phi_v^0/\partial{T}^2)_p\), i.e. the second derivative of the partial molar volume with respect to the temperature at the constant pressure.

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References

  1. W. M. Mullett and E. P. Lai. Anal. Chem., 1998, 70, 3636–3641.

    Article  CAS  PubMed  Google Scholar 

  2. A. Zlatkov, P. Peikov, N. Danchev, et al. Arch. Pharm., 1998, 331, 313–318.

    Article  CAS  Google Scholar 

  3. B. Tsvetkova, J. Tencheva, and P. Peikov. J. Foo. Drug Anal., 2003, 11, 191–194.

    CAS  Google Scholar 

  4. S. Sved, I. McGilveray, and N. Beaudoin. Biopharm. Drug Dispos., 1981, 2, 177–184.

    Article  CAS  PubMed  Google Scholar 

  5. B. Tsvetkova, J. Tencheva, and P. Peikov. Acta Pharm., 2006, 56, 251–257.

    CAS  PubMed  Google Scholar 

  6. P. Peikov, A. Zlatkov, and N. Belcheva. Dokladi Bulgarskata Akademia Naukite, 1995, 48, 29–32.

    CAS  Google Scholar 

  7. S. S. Dhondge, S. P. Zodape, and D. V. Parwate. J. Chem. Therm., 2012, 48, 207–212.

    Article  CAS  Google Scholar 

  8. S. S. Dhondge, R. L. Paliwal, N. S. Bhave, et al. J. Chem. Therm., 2012, 45, 114–121.

    Article  CAS  Google Scholar 

  9. V. Syal, A. Chauhan, and S. Chauhan. J. Pur. Appl. Ultrason., 2005, 27, 61–69.

    CAS  Google Scholar 

  10. S. Masood, R. Saeed, and S. R. Khan. J. Mater. Phys. Chem., 2013, 1, 69–75.

    Google Scholar 

  11. M. Shaikh, M. Shafiq, and M. Farooqui. J. Adv. Sci. Res., 2011, 2, 21–26.

    CAS  Google Scholar 

  12. V. Syal, S. Chauhan, and P. Sharma. J. India. Chem. Soc., 2005, 82, 602–607.

    CAS  Google Scholar 

  13. S. K. Thakur and S. Chauhan. J. Chem. Pharm. Res., 2011, 3, 657–664.

    CAS  Google Scholar 

  14. B. Meshram, P. Agrawal, H. Chandak, et al. Int. J. Emerg. Tech. Compu. App. Sci., 2013, 5, 369–373.

    Google Scholar 

  15. A. Q. Munir and M. Ali. Asian J. Biomed. Pharm. Sci., 2014, 4, 22–29.

    Article  CAS  Google Scholar 

  16. D. Takaiwa, E. Yamamoto, and K. Yasuoka. Nanoscale, 2015, 7, 12659–12665.

    Article  PubMed  Google Scholar 

  17. A. Kaiser, O. Ismailova, A. Koskela, et al. J. Mol. Liq., 2014, 189, 20–29.

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  18. A. B. Dikko, E. S. Eyube, and E. Eke. IOSR J. App. Phy., 2015, 7, 63–66.

    Google Scholar 

  19. A. Ali, P. Bidhuri, and S. Uzair. J. Saudi Chem. Soc., 2017, 21, S136–S142.

    Google Scholar 

  20. K. Rajagopal and S. Jayabalakrishnan. J. Chem. Therm., 2010, 42, 984–993.

    Article  CAS  Google Scholar 

  21. K. Mahmood, M. Shakeel, and M. Siddiq. Asian J. Chem., 2016, 28, 761–764.

    Article  CAS  Google Scholar 

  22. M. Iqbal and R. Verrall, Can. J. Chem., 1989, 67, 727–735.

    Article  CAS  Google Scholar 

  23. Y. Marcus and G. Hefter. Chem. Rev., 2004, 104, 3405–3452.

    Article  CAS  PubMed  Google Scholar 

  24. A. Ali, S. Hyder, S. Sabir, et al. J. Chem. Therm., 2006, 38, 136–143.

    Article  CAS  Google Scholar 

  25. R. Saeed, S. Masood, M. Ashfaq, et al. J. Chem. Eng. Data, 2009, 54, 3125–3129.

    Article  CAS  Google Scholar 

  26. D. O. Masson. XXVIII. Th. London, Edinburgh, Dublin Philosophical Magazine J. Sci., 1929, 8, 218–235.

    Article  CAS  Google Scholar 

  27. V. K. Dakua, B. Sinha, and M. N. Roy. Phys. Chem. Liq., 2007, 45, 549–560.

    Article  CAS  Google Scholar 

  28. F. J. Millero. J. Phys. Chem., 1969, 73, 2417–2420.

    Article  CAS  Google Scholar 

  29. H. S. Frank and W.–Y. Wen. Discuss. Faraday Soc., 1957, 24, 133–140.

    Article  Google Scholar 

  30. H. S. Frank. J. Chem. Phys., 1945, 13, 493–507.

    Article  CAS  Google Scholar 

  31. H. L. Freidman and C. V. Krishnan. (F. Franks Ed.) Water: A comprehensive Treatise. Plenum Press, New York, 1973.

    Google Scholar 

  32. Y. Li, Y.–H. Li, F.–A. Wang, et al. J. Chem. Therm., 2013, 66, 14–21.

    Article  CAS  Google Scholar 

  33. J. Zhang, P. Zhang, K. Ma, et al. Sci. China, Ser. B: Chem., 2008, 51, 420–426.

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Department of Chemistry, University of Karachi, Karachi, Pakistan

    S. Masood, W. Rehman, Z. Khan, S. Begum & A. Perveen

  2. Department of Food Science and Technology, University of Karachi, Karachi, Pakistan

    H. Arshad

Authors
  1. S. Masood
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  2. W. Rehman
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  3. Z. Khan
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  4. H. Arshad
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  5. S. Begum
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  6. A. Perveen
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Correspondence to S. Masood.

Additional information

Original Russian Text © 2018 S. Masood, W. Rehman, Z. Khan, H. Arshad, S. Begum, A. Perveen.

The text was submitted by the authors in English. Zhurnal Strukturnoi Khimii, Vol. 59, No. 5, pp. 1188–1197, June-July, 2018.

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Masood, S., Rehman, W., Khan, Z. et al. Structure Breaking/Making Property of Acefylline Piperazine in Aqueous, Aqueous Methanol, and Aqueous Ethylene Glycol Systems. J Struct Chem 59, 1148–1157 (2018). https://doi.org/10.1134/S0022476618050189

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  • DOI: https://doi.org/10.1134/S0022476618050189

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