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Crystal structure of palladium(II) complex with 2,2′-dipyridylamine and 4-toluenesulfonyl-L-serine

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Abstract

The [Pd(dpa)(tsser)] complex (1) is prepared from the reaction of PdCl2 and 2,2′-dipyridylamine (dpa) with 4-toluenesulfonyl-L-serine (tsserH2). This complex is characterized by spectral methods (IR, UV-Vis, 1H NMR, and luminescence), elemental analysis, thermal analysis (TG, DTA), and single crystal X-ray diffraction. X-ray structure determinations show that in this complex, PdII atoms are four-coordinated in a distorted square-planar configuration by two N atoms from a bidentate 2,2′-dipyridylamine ligand and one N atom and one O atom from a bidentate tsser2– ligand.

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Science, Lorestan University, Khoramabad, Iran

    E. Mehdipour & H. Bahrami

  2. Department of Chemistry, Faculty of Science, Khoramabad Branch, Islamic Azad University, Tehran, Iran

    S. Shamaei

  3. Young Researchers and Elite Club, Yadegar-e-Imam Khomeini (RAH) Branch, Islamic Azad University, Tehran, Iran

    V. Amani

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  1. E. Mehdipour
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  2. H. Bahrami
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  3. S. Shamaei
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  4. V. Amani
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Correspondence to E. Mehdipour.

Additional information

The text was submitted by the authors in English. Zhurnal Strukturnoi Khimii, Vol. 57, No. 3, pp. 564-571, March-April, 2016.

Original Russian Text © 2016 E. Mehdipour, H. Bahrami, S. Shamaei, V. Amani.

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Mehdipour, E., Bahrami, H., Shamaei, S. et al. Crystal structure of palladium(II) complex with 2,2′-dipyridylamine and 4-toluenesulfonyl-L-serine. J Struct Chem 57, 534–541 (2016). https://doi.org/10.1134/S0022476616030161

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  • DOI: https://doi.org/10.1134/S0022476616030161

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