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Crystal structure of the 2:1 complex of 2,6-dichloro-4-nitrophenol with 1,4-dioxane

  • Self-Organization in Molecular and Supramolecular Compounds
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Abstract

Crystal structure of a complex of 2,6-dichloro-4-nitrophenol (DCNP) with 1,4-dioxane is reported. Single crystals suitable for X-ray diffraction study was obtained by slow evaporation of a solution of DCNP in 1,4-dioxane. X-ray structure determination showed that the compound crystallizes in the monoclinic space group P21/n with cell parameters a = 11.9935(7) Å, b = 5.1491(3) Å, c = 16.8775(10) Å, β = 105.9360(10)°, V = 1002.23(10) Å3 and Z = 4. In the structure, the molecules lie about an inversion centre and asymmetric unit contains half of the structure. Two molecules of DCNP moiety are connected by an 1,4-dioxane molecule via strong hydrogen bonding.

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Authors and Affiliations

  1. Chemistry Department, K.Maras Sütcü Imam University, 46100, K.Maras, Turkey

    M. Köse, G. Ceyhan, S. Purtas & M. Tümer

  2. Chemistry Department, Loughborough University, LE11 3TU, Leics, UK

    V. McKee

Authors
  1. M. Köse
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  2. G. Ceyhan
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  3. S. Purtas
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  4. M. Tümer
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  5. V. McKee
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Corresponding author

Correspondence to M. Köse.

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Original Russian Text © 2014 M. Köse, G. Ceyhan, S. Purtas, M. Tümer, V. McKee.

The text was submitted by the authors in English.

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Köse, M., Ceyhan, G., Purtas, S. et al. Crystal structure of the 2:1 complex of 2,6-dichloro-4-nitrophenol with 1,4-dioxane. J Struct Chem 55, 1623–1626 (2014). https://doi.org/10.1134/S0022476614080320

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  • DOI: https://doi.org/10.1134/S0022476614080320

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