Abstract
The work is concerned with the study of a relatively new prospective composite material based on basalt fibers. In this work, an attempt has been made to investigate in more depth the structural changes that occur during irradiation of basalt composite samples by gamma ray streams and which affect the mechanical properties. The changes that have occurred during radiation modification have been evaluated by mechanical tests and infra-red spectrum investigations. The impact of the material structure on the elastic properties of the irradiated basalt composite is reasonably assumed. It is discovered that the modification of the material by gamma irradiation leads to an increase in the elastic properties of the basalt composite. At the same time the value of fracture strain decreases. Analysis of the IR spectrum in the high-frequency region showed that the radiation exposure results in continuing polymerization reactions and intermolecular cross-linking. However, when the radiation dose reaches 15 Mrad, there is a reduction in the number of bonds in the low-frequency region of the spectrum, which, according to the authors, corresponds to a breakdown of the aluminum-silicon-oxygen and organo-silicate frameworks.
Similar content being viewed by others
DATA AVAILABILITY STATEMENTS
The datasets generated and/or analyzed during the current study are available from the corresponding author on reasonable request.
REFERENCES
Osnos, M.S. and Osnos, S.P., Sostavn. Mir, 2019, no. 1, p. 58.
Osnos, S.P., Rozhkov, A.I., and Fedotov, A.A., Sostavn. Mir, 2022, no. 2, p. 18.
Dhand, V., Mittal, G., Rhee, K.Y., Park, S.J., and Hui, D., Compos., Part B: Eng., 2015, vol. 73, p. 166.
Szabo, P.J., Reti, T., and Czigany, T., Mater. Sci. Forum, 2008, vol. 589, p. 7.
Dorigato, A. and Pegoretti, A., J. Compos. Mater., 2012, vol. 46, no. 15, p. 1773.
Liu, H., Yu, Y., Liu, Y., Zhang, M., Li, L., Ma, L., Sun, Y., and Wang, W., Polymers, 2022, vol. 14, p. 2376.
Liu, Y., Zhang, M., Liu, H., Tian, L., Liu, J., Fu, C., and Fu, X., Polymers, 2022, vol. 14, p. 2443.
Yan, L., Chu, F., Tuo, W., Zhao, X., Wang, Y., Zhang, P., and Gao, Y., Polym. Polym. Compos., 2021, vol. 29, no. 9, p. 1612.
Fitzgerald, A., Pround, W., Kandemir, A., Murphy, R.J., Jesson, D.A., Trask, R.S., Hamerton, I., and Longana, M.L., Sustainability, 2021, vol. 13, no. 3, p. 1160.
Chuvashov, Yu., Yashchenko, O., Diduka, I., and Gulik, V., Zh. Nat. Voloknakh, 2020, vol. 19, no. 8.
Baptista, R., Marat-Mendes, R., Fortes, C., Gil, R., and Queiroga, B., 6° Congresso Nacional de Biomecânica (The 6th Portuguese Congress on Biomechanics), Ruben, R.B. et al., Eds., Monte Real, Leiria, 2015, p. 135.
Karavaeva, E.M., Rogozhnikov, G.I., Nyashin, Y.I., and Nikitin, V.N., Russ. J. Biomech., 2015, vol. 19, no. 1, p. 106.
Okhlopkova, A.A., Vasil’ev, S.V., and Gogoleva, O.V., Arktika 21 Vek., Tekh. Nauki, 2014, vol. 1, no 2, p. 11.
Starovoitova, I.A., Zykova, E.S., Suleimanov, A.M., et al., Izv. KGUAE, 2016, no. 3, p. 217.
Efanova, V.V., Ukr. Khim. Zh., 2000, vol. 66, no. 3, p. 59.
Arzamastsev, S.V., Artemenko, S.E., and Pavlov, V.V., Plastmassy, 2011, no. 5, p. 60.
Shcherbakov, A., Mostovoy, A., Bekeslev, A., Burmistrov, I., Arzamastsev, S., and Lopukhova, M., Polymers, 2022, vol. 14, no. 21, p. 4594.
Bekeslev, A., Mostovoy, A., Tastanova, L., Kadykova, Y., Kalganova, S., and Lopukhova, M., Polymers, 2020, vol. 12, no. 7, p. 1437.
El-Hadi, Z.A., J. Solid State Chem., 2002, vol. 163, no. 2, p. 351.
Artemenko, S.E. and Kadykov, Yu.A., Plastmassy, 2009, no. 1, p. 11.
Kudinov, V.V., Korneeva, N.V., Krylov, I.K., et al., Fiz. Khim. Obrab. Mater., 2008, no. 2, p. 32.
Makarevich, Yu.L., Oniskiv, V.D., and Stolbov, V.Yu., Lect. Notes Netw. Syst., 2022, vol. 315, p. 464.
Makarevich, Yu.L., Oniskiv, V.D., Stolbov, V.Yu., and Gitman, I., Mech. Compos. Mater., 2022, vol. 58, no. 1, p. 43.
Skroznikov, S.V., Zelentsova, N.S., Lyamkina, D.E., et al., Dostizh. Obl. Khim. Khim. Tekhnol., 2010, vol. 24, no. 3, p. 77.
Al-Harthi, M.A., Polym. Compos., 2014, vol. 35, no. 10, p. 2036.
Mussaeva, M.A. and Ibragimova, E.M., Tech. Phys. Lett., 2019, vol. 45, no. 2, p. 155.
Ibragimova, E.M., Salakhitdinov, A.N., Salakhitdinova, M.K., and Yusupov, A.A., J. Appl. Spectrosc., 2018, vol. 85, no. 2, p. 255.
Singha, K., Int. J. Text. Sci., 2012, vol. 1, no. 4, p. 19.
Mayo, D.W., Miller, F.A., and Hannah, R.W., Course Notes on the Interpretation of Infrared and Raman Spectra, Hoboken, NJ: Wiley–Interscience, 2003.
Nakamoto, K., Infrared and Raman Spectra of Inorganic and Coordination Compounds, New York: Wiley, 1986, 4th ed.
Askadskii, A.A. and Matveev, Yu.I., Khimicheskaya struktura i fizicheskie svoistva polimerov (Chemical Structure and Physical Properties of Polymers), Moscow: Khimiya, 1983.
Nurullaev, E.M., and Oniskiv, V.D., High Energy Chem., 2021, vol. 55, no. 2, p. 150.
Nurullaev, E.M., Oniskiv, V.D., Astaf’eva, S.A., and Lebedeva, E.A., High Energy Chem., 2022, vol. 56, no. 6, p. 423.
ACKNOWLEDGMENTS
The authors express gratitude to the Candidate of Chemical Sciences S.A. Astafieva (IHTT UrO RAS) for fruitful discussion of research results and participation in a number of experiments.
Funding
This research was carried out with the financial support of the Ministry of Science and Higher Education of the Russian Federation in the framework of the program of activities of the Perm Scientific and Educational Center “Rational Subsoil Use” and of the Government of the Perm Region in the framework grant no. С-26/581.
Author information
Authors and Affiliations
Contributions
The manuscript was written through the contribution of all authors. All authors discussed the results, reviewed, and approved the final version of the manuscript.
Corresponding author
Ethics declarations
The authors declared no potential conflicts of interest with respect to the research, authorship, and publication of the article.
Rights and permissions
About this article
Cite this article
Oniskiv, V.D., Stolbov, V.Y. & Makarevich, Y.L. Investigation of Mechanical Properties and Structure of Irradiated Basalt Composites Using IR Spectrometry. High Energy Chem 57, 410–417 (2023). https://doi.org/10.1134/S0018143923050090
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S0018143923050090