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Experimental and Theoretical Study of Influence of Nature of Counterion on Electroosmotic Water Transport in Sulfonated Cation-Exchange Membranes

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Abstract

The free solvent transport number in an MF-4SK perfluorinated membrane in solutions of alkaline metal chlorides and hydrochloric acid is for the first time calculated within the framework of a capillary model based on the data of standard contact porosimetry and membrane conductometry. The reasons for the change in the structural characteristics and specific conductivity upon varying the nature of the counterion are discussed. The portion of through mesopores in MF-4SK homogeneous and MK-40 heterogeneous sulfonated cation-exchange membranes is estimated using the experimental data on the water transport numbers in solutions of electrolytes of different natures.

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Funding

This research was financially supported by the Kuban Science Foundation within scientific project no. H-21.1/23/21.

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Authors and Affiliations

  1. Kuban State University, 350040, Krasnodar, Russia

    I. V. Falina, N. A. Kononenko, S. A. Shkirskaya, O. A. Demina & M. V. Gritsay

  2. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, 119071, Moscow, Russia

    Yu. M. Volfkovich & V. E. Sosenkin

Authors
  1. I. V. Falina
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  2. N. A. Kononenko
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  3. S. A. Shkirskaya
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  4. O. A. Demina
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  5. Yu. M. Volfkovich
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  6. V. E. Sosenkin
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  7. M. V. Gritsay
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Correspondence to I. V. Falina.

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Translated by E. Boltukhina

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Falina, I.V., Kononenko, N.A., Shkirskaya, S.A. et al. Experimental and Theoretical Study of Influence of Nature of Counterion on Electroosmotic Water Transport in Sulfonated Cation-Exchange Membranes. Membr. Membr. Technol. 4, 281–289 (2022). https://doi.org/10.1134/S2517751622050043

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  • DOI: https://doi.org/10.1134/S2517751622050043

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