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Physicochemical properties and electrochemical behavior of Ebonex/Pt-based materials

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Abstract

Physicochemical properties and electrochemical behavior of Ebonex®/Pt-based electrodes obtained with the use of a combined electrochemical method by electrodeposition of a thin platinum layer on substoichiometric titanium oxides (Ebonex®) followed by heat treatment are studied. Phase composition is found to depend substantially on the temperature of the electrode treatment. At temperatures above 230°C, a titanium-dioxide-hollandite phase is formed and facilitates thermal diffusion of platinum deep into the substrate. A previously unknown titanium-oxygen phase (310°C) that affects the electrochemical behavior of the electrodes is discovered. Ebonex®/Pt-based materials are found to be n-type semiconductors, the flat band potentials and the number of charge carriers of which are determined by the formation conditions.

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References

  1. Kim, J. and Choi, W., Appl. Catalysis B: Environ., 2011, vol. 106, nos. 1–2, p. 39.

    CAS  Google Scholar 

  2. Selvarani, G., Maheswari, S., Sridhar, P., et al., J. Electrochem. Soc., 2009, vol. 156, no. 11, p. B1354.

    Article  CAS  Google Scholar 

  3. Shanmugam, S. and Gedanken, A., J. Phys. Chem. C, 2009, vol. 113, no. 43, p. 18707.

    Article  CAS  Google Scholar 

  4. Kasian, O., Luk’yanenko, T., and Velichenko, A., Chem. Chem. Technol., 2012, vol. 6, no. 3, p. 241.

    Google Scholar 

  5. Selvaganesh, S.V., Selvarani, G., Sridhar, P., et al., J. Electrochem. Soc., 2010, vol. 157, no. 7, p. B1000.

    Article  CAS  Google Scholar 

  6. Kasian, O., Luk’yanenko, T., Amadelli, R., and Velichenko, A., Russ. J. Electrochem., 2013, vol. 49, no. 6, p. 557.

    Article  CAS  Google Scholar 

  7. Jang, G.-W. and Rajeshwar, K., J. Electrochem. Soc., 1987, vol. 134, no. 7, p. 1830.

    Article  CAS  Google Scholar 

  8. Tamura, T., Ishibashi, S., Terakura, K., et al., Phys. Rev. B, 2009, vol. 80, no. 19.

    Google Scholar 

  9. Wang, X.-Y., Jiang, Y.-S., Zhu, H., et al., Chem. Res. Chin. Univ., 2011, vol. 27, no. 3, p. 486.

    CAS  Google Scholar 

  10. Jeong, D.S., Schroeder, H., and Waser, R., Nanotecnology, 2009, vol. 20, no. 37.

    Google Scholar 

  11. Kim, S. and Lee, S.-K., J. Photochem. Photobiol. A: Chem., 2009, vol. 203, nos. 2–3, p. 145.

    Article  CAS  Google Scholar 

  12. Fan, J.-W., Liu, X.-H., and Zhang, J., Environ. Technol., 2011, vol. 32, no. 4, p. 427.

    Article  CAS  Google Scholar 

  13. Hirakawa, K., Inoue, M., and Abe, T., Electrochim. Acta, 2010, vol. 55, no. 20, p. 5874.

    Article  CAS  Google Scholar 

  14. Antolini, E. and Gonzalez, E.R., Solid State Ionics, 2009, vol. 180, p. 746.

    Article  CAS  Google Scholar 

  15. Tauster, S.J., Acc. Chem. Res., 1987, vol. 20, p. 389.

    Article  CAS  Google Scholar 

  16. Jaksic, J.M., Krstajic, N.V., Vracar, Lj.M., et al., Electrochim. Acta, 2007, vol. 53, p. 349.

    Article  CAS  Google Scholar 

  17. Hayfield, P.C.S., Development of a New Material — Monolithic Ti 407 Ebonex(R) Ceramic, Cambridge: Roy. Soc. Chem., 2002.

    Google Scholar 

  18. Ellis, K., Hill, A., Loyns, A., and Partington, T., J. Power Sources, 2004, vol. 136, p. 366.

    Article  CAS  Google Scholar 

  19. Grimm, J., Bessarabov, D., Maier, W., et al., Desalination, 1998, vol. 115, p. 295.

    Article  CAS  Google Scholar 

  20. Bejan, D., Malcolm, J.D., Morrison, L., and Bunce, N.J., Electrochim. Acta, 2009, vol. 54, p. 5548.

    Article  CAS  Google Scholar 

  21. Clarke, R.L., J. Appl. Electrochem., 1998, vol. 28, p. 1021.

    Article  Google Scholar 

  22. Chen, G., Betterton, E.A., and Arnold, R., J. Appl. Electrochem., 1999, vol. 29, p. 961.

    Article  CAS  Google Scholar 

  23. Kao, W.-H., Patel, P., and Haberichter, S.L., J. Electrochem. Soc., 1997, vol. 144, p. 1907.

    Article  CAS  Google Scholar 

  24. Bejan, D., Guinea, E., and Bunce, N.J., Electrochim. Acta, 2012, vol. 69, p. 275.

    Article  CAS  Google Scholar 

  25. Bejan, D., Malcolm, J.D., Morrison, L., and Bunce, N., Electrochim. Acta, 2009, vol. 54, p. 5548.

    Article  CAS  Google Scholar 

  26. El-Sherif, S., Bejan, D., and Bunce, N., Can. J. Chem., 2010, vol. 88, p. 928.

    Article  CAS  Google Scholar 

  27. Farndon, E. and Pletcher, D., Electrochim. Acta, 1977, vol. 42, p. 1281.

    Article  Google Scholar 

  28. Farndon, E. and Pletcher, D., Electrochim. Acta, 1977, vol. 42, p. 1269.

    Article  Google Scholar 

  29. Dieckmann, G. and Lagner, S., Electrochim. Acta, 1998, vol. 44, p. 437.

    Article  CAS  Google Scholar 

  30. Slavcheva, E., Nikolova, V., Petkova, T., et al., Electrochim. Acta, 2005, vol. 50, p. 5444.

    Article  CAS  Google Scholar 

  31. Jaksic, J., Krstajic, N., Vracar, L., et al., Electrochim. Acta, 2007, vol. 53, p. 349.

    Article  CAS  Google Scholar 

  32. Park, S.-Y., Mho, S.-I., Chi, E.O., et al., Thin Solid Films, 1995, vol. 258, p. 5.

    Article  CAS  Google Scholar 

  33. Vracar, Lj.M., Krstajic, N.V., Radmilovic, V.R., and Jaksic, M.M., J. Electroanal. Chem., 2006, vol. 587, p. 99.

    Article  CAS  Google Scholar 

  34. Stoyanova, A., Borisov, G., Lefterova, E., and Slavcheva, E., Int. J. Hydrogen Energy, 2012

    Google Scholar 

  35. Kasian, O., Luk’yanenko, T., Velichenko, A., and Amadelli, R., Int. J. Electrochem. Sci., 2012, vol. 7, p. 7915.

    CAS  Google Scholar 

  36. Korobov, V.I. and Ochkov, V.F., Chemical Kinetics with Mathcad and Maple, New York: Springer, 2011.

    Book  Google Scholar 

  37. Korobov, V.I. and Ochkov, V.F., Khimicheskaya kinetika: Vvedenie v Mathcad/Maple/MCS (Chemical Kinetics: Introduction to Mathcad/Maple/MCS), Moscow: Goryachaya liniya-Telekom, 2009.

    Google Scholar 

  38. Kraus, W. and Nolze, G., PowderCell for Windows, version 2.4, Berlin: Fed. Inst. Mater. Res. Test., 2000.

    Google Scholar 

  39. Stoe WinXPOW, version 3.03, Darmstadt: Stoe & Cie, 2010.

  40. Young, R.A., The Rietveld Method, IUCr Monographs of Crystallography, New York: Oxford Univ. Press, 1993, vol. 5.

    Google Scholar 

  41. Roisnel, T. and Rodriguez-Carvajal, J., Mater. Sci. Forum, 2001, vols. 378–381, p. 118.

    Article  Google Scholar 

  42. de Keijser, Th.H., Langford, J.I., Mittemeijer, E.J., and Vogels, A.B.P., J. Appl. Crystallogr., 1982, vol. 15, p. 308.

    Article  Google Scholar 

  43. Scott, K. and Taama, W.M., Electrochim. Acta, 1999, vol. 44, p. 3421.

    Article  CAS  Google Scholar 

  44. Scialdone, O., Galia, A., and Filardo, G., Electrochim. Acta, 2008, vol. 53, p. 7220.

    Article  CAS  Google Scholar 

  45. Bejan, D., Malcolm, J.D., Morrison, L., et al., Electrochim. Acta, 2009, vol. 54, p. 5548.

    Article  CAS  Google Scholar 

  46. Siracusano, S., Baglio, V., D’Urso, C., et al., Electrochim. Acta, 2009, vol. 54, p. 6292.

    Article  CAS  Google Scholar 

  47. Walsh, F.C. and Wills, R.G.A., Electrochim. Acta, 2010, vol. 55, p. 6342.

    Article  CAS  Google Scholar 

  48. Paunovic, P., Popovski, O., Fidanccevska, E., et al., Int. J. Hydrogen Energy, 2010, vol. 35, p. 10073.

    Article  CAS  Google Scholar 

  49. Smit, J.R., Nahlea, A.H., and Walsh, F.C., J. Appl. Electrochem., 1997, vol. 27, p. 815.

    Article  Google Scholar 

  50. Smit, J.R., Walsh, F.C., and Clarke, R.L., J. Appl. Electrochem., 1998, vol. 28, p. 1021.

    Article  Google Scholar 

  51. Chen, G., Betterton, E.A., and Arnold, R.G., J. Appl. Electrochem., 1999, vol. 29, p. 961.

    Article  CAS  Google Scholar 

  52. Leinekugel-le-Cocq, A.Y., Deniard, P., Jobic, S., et al., J. Solid State Chem., 2006, vol. 179, no. 10, p. 3196.

    Article  CAS  Google Scholar 

  53. Noailles, L.D., Johnson, C.S., Vaughey, J.T., et al., J. Power Sources, 1999, vols. 81–82, p. 259.

    Article  Google Scholar 

  54. Latroche, M., Brohan, L., Marchand, R., et al., J. Solid State Chem., 1989, vol. 81, p. 78.

    Article  CAS  Google Scholar 

  55. Le Page, Y. and Strobel, P., J. Solid State Chem., 1982, vol. 44, p. 273.

    Article  Google Scholar 

  56. Marezio, M., Tranqui, D., Lakkis, S., et al., Phys. Rev. B, 1977, vol. 16, p. 2811.

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Ukrainian State University of Chemical Technology, ave. Gagarin 8, Dnipropetrovsk, 49600, Ukraine

    A. B. Velichenko, O. I. Kasian & T. V. Luk’yanenko

  2. ISOF-CNR and Dipartamento di Chimica, Universita di Ferrara, via Borsari 46, Ferrara, Italy

    R. Amadelli

  3. Ivan Franko National University of Lviv, Universitetskaya Str. 1, Lviv, 79000, Ukraine

    P. Yu. Demchenko & R. E. Gladyshevskii

Authors
  1. A. B. Velichenko
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  2. O. I. Kasian
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  3. T. V. Luk’yanenko
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  4. R. Amadelli
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  5. P. Yu. Demchenko
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  6. R. E. Gladyshevskii
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Correspondence to A. B. Velichenko.

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Original Russian Text © A.B. Velichenko, O.I. Kasian, T.V. Luk’yanenko, R. Amadelli, P.Yu. Demchenko, R.E. Gladyshevskii, 2013, published in Fizikokhimiya Poverkhnosti i Zashchita Materialov, 2013, Vol. 49, No. 6, pp. 641–648.

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Velichenko, A.B., Kasian, O.I., Luk’yanenko, T.V. et al. Physicochemical properties and electrochemical behavior of Ebonex/Pt-based materials. Prot Met Phys Chem Surf 49, 705–711 (2013). https://doi.org/10.1134/S2070205113060178

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  • DOI: https://doi.org/10.1134/S2070205113060178

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