Skip to main content
SpringerLink
Log in

Reactions of molybdenum atoms with NO, O2, N2O, and CO2 molecules behind shock waves

  • Kinetics and Mechanism of Chemical Reactions. Catalysis
  • Published:
Russian Journal of Physical Chemistry B Aims and scope Submit manuscript

Abstract

Experimental results on the interaction of Mo atoms with various oxygen-containing molecules (NO, O2, N2O, and CO2) at high temperatures (>1200 K) are presented, which are in close agreement with measurements at moderate and low temperatures. It is demonstrated that the height of the activation barrier is additionally increased for spin-forbidden reactions and that an increase in the heat of reaction causes an increase in the rate constant for a given type of reaction. For the reactions of Mo atoms with O2 and N2O, interpolated temperature dependences of the rate constants, based on the high-temperature measurements conducted in the present work and the published low-temperature data, are proposed.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. J. M. C. Plane, Chem. Rev. 103, 4963 (2003).

    Article  CAS  Google Scholar 

  2. L. Deguillaume, M. Leriche, K. Desboeufs, et al., Chem. Rev. 105, 3388 (2005).

    Article  CAS  Google Scholar 

  3. G. T. Linteris, M. D. Rumminger, and V. I. Babushok, Prog. Energy Combust. Sci. 34, 288 (2008).

    Article  CAS  Google Scholar 

  4. W. P. Linak and J. O. L. Wendt, Prog. Energy Combust. Sci. 19, 145 (1993).

    Article  CAS  Google Scholar 

  5. U. S. Akhmadov, I. S. Zaslonko, and V. N. Smirnov, Kinet. Katal. 29, 291 (1988).

    CAS  Google Scholar 

  6. M. L. Campbell, J. Phys. Chem. A 107, 3048 (2003).

    Article  CAS  Google Scholar 

  7. A. Fontijn, Pure Appl. Chem. 70, 469 (1998).

    Article  CAS  Google Scholar 

  8. U. S. Akhmadov, I. S. Zaslonko, and V. N. Smirnov, Kinet. Katal. 29, 942 (1988).

    CAS  Google Scholar 

  9. R. E. McClean, M. L. Campbell, and R. H. Goodwin, J. Phys. Chem. 100, 7502 (1996).

    Article  CAS  Google Scholar 

  10. L. Lian, S. A. Mitchell, and D. M. Rayner, J. Phys. Chem. 98, 11637 (1994).

    Article  CAS  Google Scholar 

  11. M. L. Campbell, R. E. McClean, and J. S. S. Harter, Chem. Phys. Lett. 235, 497 (1995).

    Article  CAS  Google Scholar 

  12. K. E. Lewis, D. M. Golden, and G. P. Smith, J. Am. Chem. Soc. 106, 3905 (1984).

    Article  CAS  Google Scholar 

  13. B. V. L’vov, Atomic Absorption Spectral Analysis (Nauka, Moscow, 1966) [in Russian].

    Google Scholar 

  14. A. U. Acuna and D. Husain, J. Chem. Soc., Faraday Trans. 69, 585 (1973).

    Article  CAS  Google Scholar 

  15. Thermodynamic Properties of Individual Substances, The Handbook, Ed. by V. P. Glushko (Nauka, Moscow, 1978), vol. 1, pt. 2 [in Russian].

    Google Scholar 

  16. Thermodynamic Properties of Individual Substances, The Handbook, Ed. by V. P. Glushko (Nauka, Moscow, 1982), vol. 4, pt. 2 [in Russian].

    Google Scholar 

  17. I. Shim and K. A. Gingerich, J. Mol. Struct. (Theochem) 460, 123 (1999).

    Article  CAS  Google Scholar 

  18. J. M. Parnis, S. A. Mitchell, and P. A. Hackett, J. Phys. Chem. 94, 8152 (1990).

    Article  CAS  Google Scholar 

  19. S. A. Mitchell and P. A. Hackett, J. Chem. Phys. 93, 7822 (1990).

    Article  CAS  Google Scholar 

  20. D. Ritter and J. C. Weisshaar, J. Phys. Chem. 94, 4907 (1990).

    Article  CAS  Google Scholar 

  21. G. H. Jeung, P. Luc, R. Vetter, et al., Phys. Chem. Chem. Phys. 4, 596 (2002).

    Article  CAS  Google Scholar 

  22. R. E. McClean and L. Pasternack, J. Phys. Chem. 96,9828 (1992).

    Article  CAS  Google Scholar 

  23. D. Ritter and J. C. Weisshaar, J. Phys. Chem. 93, 1576 (1989).

    Article  CAS  Google Scholar 

  24. D. E. Clemmer, K. Honma, and I. Koyano, J. Phys. Chem. 97, 11480 (1993).

    Article  CAS  Google Scholar 

  25. M. L. Campbell and K. L. Hooper, J. Chem. Soc., Faraday Trans. 93, 2139 (1997).

    Article  CAS  Google Scholar 

  26. T. Wakabayashi, Y. Nakai, and Y. Ishikawa, Chem. Lett., 331 (1997).

  27. V. N. Kondrat’ev and E. E. Nikitin, Kinetics and Mechanism of Gas Phase Reactions (Nauka, Moscow, 1974) [in Russian].

    Google Scholar 

  28. V. N. Smirnov, Doctoral Dissertation in Mathematics and Physics (IKhF RAN, Moscow, 2009).

  29. U. V. Choudary, K. A. Gingerich, and J. E. Kingcade, J. Less. Common Met. 42, 111 (1975).

    Article  CAS  Google Scholar 

  30. J. B. Pedley and E. M. Marshall, J. Phys. Chem. Ref. Data 12, 967 (1983).

    Article  CAS  Google Scholar 

  31. H. P. Loock, B. Simard, S. Wallin, et al., Chem. Phys. 109, 8980 (1998).

    CAS  Google Scholar 

  32. M. R. Sievers, Y.-M. Chen, and P. B. Armentrout, Chem. Phys. 105, 6322 (1996).

    CAS  Google Scholar 

  33. J. Sugar and A. Musgrove, J. Phys. Chem. Ref. Data 17, 155 (1988).

    Article  CAS  Google Scholar 

  34. P. Song, W. Guan, C. Yao, et al., Theor. Chem. Acc. 117, 407 (2007).

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Semenov Institute of Chemical Physics, Russian Academy of Sciences, Moscow, Russia

    V. N. Smirnov

  2. Chechen State University, Grozny, Chechen Republic, Russia

    U. S. Akhmadov

Authors
  1. V. N. Smirnov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. U. S. Akhmadov
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to V. N. Smirnov.

Additional information

Original Russian Text © V.N. Smirnov, U.S. Akhmadov, 2010, published in Khimicheskaya Fizika, 2010, Vol. 29, No. 10, pp. 26–31.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Smirnov, V.N., Akhmadov, U.S. Reactions of molybdenum atoms with NO, O2, N2O, and CO2 molecules behind shock waves. Russ. J. Phys. Chem. B 4, 742–747 (2010). https://doi.org/10.1134/S1990793110050088

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1990793110050088

Keywords

Search

Navigation