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Synthesis, Crystal Structures, and Properties of Two Compounds Based on Carboxylate-Sulfonate Ligand

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Abstract

Two coordination compounds, Mn2(L)2(bipy)4(H2O)4·Mn(bipy)2(H2O)4 (1) and Cu(phen)2Cl·H2L (2) (H3L = 4-sulfophthalic acid; bipy = 4,4′-bipyridine; phen = 1,10-phenanthroline), have been synthesized by the hydrothermal method and characterized by elemental analyses, IR spectra and single crystal X-ray diffraction. Compound 1 is a discrete trinuclear complex, composed of L3–-bridging dinuclear and N-donor mononuclear units. Two units are extended into a two-dimensional supra-molecular structure via hydrogen bonds and π–π interactions between bipy molecules. Compound 2 features the N-donor mononuclear structure with uncoordinated H2L– anion. The H2L– anions are interconnected by H-bonding interactions generating one-dimensional double-chain structures. In the solid state, compounds 1 and 2 exhibit photoluminescence with emissions maximums at 463 and 415 nm, respectively. Magnetic susceptibility measurements indicate the antiferromagnetic coupling between Mn ions in compound 1.

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Funding

Scientific Research Fund Project of Liaoning Provincial Education Department (no. L2019010).

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Authors and Affiliations

  1. School of Petrochemical Engineering, Liaoning Petrochemical University, 113001, Fushun, China

    Xian Chen, Pengpeng Yin, Lei Guan, Ying Wang, Hongzhe Jin & Xuejia Xiong

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  1. Xian Chen
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  2. Pengpeng Yin
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  3. Lei Guan
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  4. Ying Wang
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  5. Hongzhe Jin
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Correspondence to Ying Wang.

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Chen, X., Yin, P., Guan, L. et al. Synthesis, Crystal Structures, and Properties of Two Compounds Based on Carboxylate-Sulfonate Ligand. Russ J Gen Chem 91, 1584–1591 (2021). https://doi.org/10.1134/S1070363221080223

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  • DOI: https://doi.org/10.1134/S1070363221080223

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