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Cu(II) and Co(II) Complexes with (4Z)-4-[(2-Diethylaminoethylamino)methylene]-5-Methyl-2-Phenylpyrazol-3-one: Synthesis, Magnetic Properties, and Crystal Structures

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Abstract

(4Z)-4-[(2-Diethylaminoethylamino)methylene]-5-methyl-2-phenylpyrazol-3-one (НL, product of the condensation of 5-hydroxy-3-methyl-1-phenylpyrazole-4-carbaldehyde with N,N-diethylethylenediamine) and its complexes CuL2 (I) and Co(L)CH3COO · CH3OH · H2O (II) are synthesized. The structures and compositions of the synthesized compounds are determined by elemental analysis, 1Н NMR and IR spectroscopy, and X-ray diffraction analysis (CIF files CCDC nos. 1971770 (I) and 1971772 (II)). Bis(chelate) pentacoordinated complex I has a distorted tetragonal pyramidal structure, and a distorted octahedral structure with the monodentate acetate anion and methanol and water molecules is observed for monochelate complex II.

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ACKNOWLEDGMENTS

IR and 1Н NMR spectra were recorded using the equipment of the Center for Collective Use Molecular Spectroscopy.

Funding

This work was supported by the Ministry of Science and Higher Education of the Russian Federation in terms of the state task of the Southern Federal University. The XRD studies were supported by the program of the Peoples Friendship University 5-100.

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Authors and Affiliations

  1. Research Institute of Physical and Organic Chemistry, Southern Federal University, Rostov-on-Don, Russia

    A. S. Burlov, M. S. Milutka, Yu. V. Koshchienko & A. I. Uraev

  2. Research Institute of Physics, Southern Federal University, Rostov-on-Don, Russia

    V. G. Vlasenko

  3. Southern Federal University, Rostov-on-Don, Russia

    T. V. Lifintseva

  4. Southern Scientific Center, Russian Academy of Sciences, Rostov-on-Don, Russia

    D. A. Garnovskii

  5. The Smart Materials International Research Institute, Rostov-on-Don, Russia

    Yu. V. Rusalev

  6. Kurchatov Institute Russian Research Center, 123182, Moscow, Russia

    V. A. Lazarenko

  7. Peoples Friendship University, 117198, Moscow, Russia

    V. N. Khrustalev

  8. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 119991, Moscow, Russia

    V. N. Khrustalev

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  1. A. S. Burlov
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  2. V. G. Vlasenko
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  4. M. S. Milutka
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  8. Yu. V. Rusalev
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Correspondence to A. S. Burlov.

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Dedicated to I.L. Eremenko on the occasion of his 70th birthday

Translated by E. Yablonskaya

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Burlov, A.S., Vlasenko, V.G., Lifintseva, T.V. et al. Cu(II) and Co(II) Complexes with (4Z)-4-[(2-Diethylaminoethylamino)methylene]-5-Methyl-2-Phenylpyrazol-3-one: Synthesis, Magnetic Properties, and Crystal Structures. Russ J Coord Chem 46, 485–492 (2020). https://doi.org/10.1134/S1070328420070015

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