Skip to main content
SpringerLink
Log in

Specific features of the structure and electrical conductivity of the magnetically ordered oxide (La0.9Sr0.1)(Fe0.8Mg0.2)O3−y

  • Structure of Inorganic Compounds
  • Published:
Crystallography Reports Aims and scope Submit manuscript

Abstract

The structure of the (La0.9Sr0.1)(Fe0.8Mg0.2)O3− y oxide is investigated using neutron diffraction at temperatures of 10, 295, 500, 700, and 1000 K. The results of the structure refinement are in good agreement with the experimental data on the electrical conductivity and confirm the inference that the oxidation state of iron cations is higher than 3+ and that the structure of the compound is antiferromagnetically ordered at temperatures below 500 K.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. T. Ishihara, H. Matsuda, and Y. Takita, J. Am. Chem. Soc. 116(9), 3801 (1994).

    Article  Google Scholar 

  2. K. Huang, R. S. Tichy, and J. B. Goodenough, J. Am. Ceram. Soc. 81(10), 2565 (1998).

    Article  Google Scholar 

  3. P. Huang and A. Petric, J. Electrochem. Soc. 143 (1996).

  4. T. Ishihara, H. Furutani, M. Honda, et al., Chem. Mater. 11, 2081 (1999).

    Article  Google Scholar 

  5. T. Ishihara, T. Shibayama, H. Nishiguchi, and Y. Takita, J. Mater. Sci. 36, 1125 (2001).

    Article  Google Scholar 

  6. N. Trofimenko and H. Ullmann, Solid State Ionics 118, 215 (1999).

    Article  Google Scholar 

  7. E. D. Politova, S. Yu. Stefanovich, A. K. Avetisov, et al., in Proceedings of the NATO Advanced Research Workshop “Mixed Ionic Electronic Conducting Perovskites for Advanced Energy Systems,” Kiev, Ukraine, 2003 (Kiev, 2003), p. 213.

  8. T. Yu. Glavatskikh, N. U. Venskovskii, V. V. Aleksandrovskii, et al., Neorg. Mater. 39(7), 892 (2003) [Inorg. Mater. 39 (7), 759 (2003)].

    Google Scholar 

  9. E. D. Politova, S. Yu. Stefanovich, A. K. Avetisov, et al., J. Solid State Electrochem. 8(9), 655 (2004).

    Article  Google Scholar 

  10. E. D. Politova, V. V. Aleksandrovskii, S. V. Zaitsev, et al., Mater. Sci. Forum 514–516, 412 (2006).

    Article  Google Scholar 

  11. S. A. Ivanov, G. M. Kaleva, V. V. Aleksandrovskiĭ, et al., Kristallografiya 51(2), 241 (2006) [Crystallogr. Rep. 51 (2), 212 (2006)].

    Google Scholar 

  12. E. D. Politova, G. M. Kaleva, and V. S. Rusakov, in Proceedings of the Ninth International Symposium “Ordering in Metals and Alloys” (OMA-2006), Rostov-on-Don, Russia, 2006 (Rostov-on-Don, 2006), p. 89 [in Russian].

  13. S. A. Ivanov, S.-G. Eriksson, R. Tellgren, and H. Rundolf, Mater. Res. Bull. 39, 2317 (2004).

    Article  Google Scholar 

  14. V. V. Aleksandrovskiĭ, N. U. Venskovskiĭ, G. M. Kaleva, et al., Izv. Akad. Nauk, Ser. Fiz. 65(8), 1150 (2001).

    Google Scholar 

  15. E. D. Politova, S. Yu. Stefanovich, V. V. Aleksandrovskii, et al., Phys. Status Solidi C 2(1), 196 (2005).

    Article  ADS  Google Scholar 

  16. J. Rodríguez-Carvajal, Physica B (Amsterdam) 192, 55 (1993).

    ADS  Google Scholar 

  17. J. B. Goodenough and J.-S. Zhou, Transport Properties in Structure and Bonding (Springer-Verlag, Berlin, 2001), p. 18.

    Google Scholar 

  18. R. D. Shannon, Acta Crystallogr., Sect. A: Cryst. Phys., Diffr., Theor. Gen. Crystallogr. 32, 751 (1976).

    Article  ADS  Google Scholar 

  19. N. E. Brese and M. O’Keefe, Acta Crystallogr., Sect. B: Struct. Sci. 47, 192 (1991).

    Article  Google Scholar 

  20. F. M. Figueiredo, J. Waerenborgh, V. V. Kharton, et al., Solid State Ionics 156, 371 (2003).

    Article  Google Scholar 

  21. K. Kuzushita, Sh. Morimoto, and S. Nasu, Physica A (Amsterdam) 329–333, 736 (2003).

    Google Scholar 

  22. Y. R. Uhm, C. W. Lee, S. R. Yoon, et al., J. Magn. Magn. Mater. 254–255, 595 (2003).

    Article  Google Scholar 

  23. Sh. Marimoto, K. K. Kuzushita, and S. Nasu, J. Magn. Magn. Mater. 272–276, 127 (2004).

    Article  Google Scholar 

  24. T. Pedersen, S. Saadi, K. H. Nielsen, et al., Solid State Ionics 175, 1555 (2005).

    Article  Google Scholar 

  25. U. Russo, L. Nodari, M. Faticanti, et al., Solid State Ionics 176, 97 (2005).

    Article  Google Scholar 

  26. R. E. Mitchell, Perovskites Modern and Ancient (Almaz, Ontario, Canada, 2002), p. 318.

    Google Scholar 

  27. A. M. Glazer, Acta Crystallogr., Sect. B: Struct. Crystallogr. Cryst. Chem. 28, 3384 (1972).

    Article  Google Scholar 

  28. W. C. Koehler and E. O. Wollan, J. Phys. Chem. Solids 2, 100 (1957).

    Article  ADS  Google Scholar 

  29. J. A. Kilner and R. J. Brook, Solid State Ionics 6, 237 (1982).

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Karpov Research Institute of Physical Chemistry, ul. Vorontsovo pole 10, Moscow, 105064, Russia

    S. A. Ivanov, G. M. Kaleva, A. V. Mosunov & E. D. Politova

  2. Department of Chemistry, Göteborg University, Göteborg, SE-61182, Sweden

    S. -G. Eriksson

Authors
  1. S. A. Ivanov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. G. M. Kaleva
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. A. V. Mosunov
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. E. D. Politova
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. S. -G. Eriksson
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to S. A. Ivanov.

Additional information

Original Russian Text © S.A. Ivanov, G.M. Kaleva, A.V. Mosunov, E.D. Politova, S.-G. Eriksson, 2008, published in Kristallografiya, 2008, Vol. 53, No. 1, pp. 69–75.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Ivanov, S.A., Kaleva, G.M., Mosunov, A.V. et al. Specific features of the structure and electrical conductivity of the magnetically ordered oxide (La0.9Sr0.1)(Fe0.8Mg0.2)O3−y . Crystallogr. Rep. 53, 68–75 (2008). https://doi.org/10.1134/S1063774508010082

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1063774508010082

PACS numbers

Search

Navigation