Abstract
With the use of mono- and disubstituted C14-C16 alkylarenes as an example, it was found that, in many cases, the simplest additive relations for the estimation of gas-chromatographic retention indices make it possible to unambiguously identify the isomeric products of organic reactions even without the application of mass-spectrometric data. The simplest increments of different structural transformations of molecules, for example, CH3 → C6H5 and H → C6H5, remain of importance in algorithms of this type; however, the use of procedures with no increments for the assembly of target structures is more convenient.
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Original Russian Text © I.G. Zenkevich, A.I. Ukolov, A.S. Kushakova, L.K. Gustyleva, 2011, published in Zhurnal Analiticheskoi Khimii, 2011, Vol. 66, No. 12, pp. 1282–1289.
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Zenkevich, I.G., Ukolov, A.I., Kushakova, A.S. et al. Identification of isomeric alkylarenes with the use of additive relations for the evaluation of gas-chromatographic retention indices. J Anal Chem 66, 1165–1172 (2011). https://doi.org/10.1134/S1061934811120136
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DOI: https://doi.org/10.1134/S1061934811120136