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Assessing the selectivity of composite ion-exchange membranes within the framework of the extended three-wire model of conduction

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Abstract

The possibility of assessing the selectivity of composite perfluorated membranes MF-4SK modified with polyaniline (PANI), based on the concentration dependence of their specific conductivity in terms of the extended three-wire model of conduction of ion-exchange materials is investigated. To check the reliability of results obtained, the transport numbers of ions are calculated based on the electrodiffusion coefficients of counter ions and coions determined from concentration dependences of conductivity and diffusion permeability of ion-exchange membranes. The transport numbers of hydrogen ions found by these two methods are shown to coincide with high accuracy throughout the whole range of concentrations of HCl solutions for the original MF-4SK membrane and membranes with the fixed thickness of the modified polyaniline layer on their one side. For the MF-4SK sample the with gradient distribution of polyaniline, which exhibits asymmetrical transport characteristics, the deviation between the transport numbers of ions calculated with the use of electrodiffusion coefficients of counter ions and coions and those determined in terms of the extended three-wire model of conduction is shown to increase with the increase in solution concentration but not exceed 4%.

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References

  1. Helfferich, F., Ionenaustauscher, Weinheim Verlag Chemie, 1959 (translated into Russian).

    Google Scholar 

  2. Zabolotskii, V.I. and Nikonenko, V.V., Perenos ionov v membranakh (Ion Transfer in Membranes), Moscow Nauka, 1996.

    Google Scholar 

  3. Lebedev, K.A., Nikonenko, V.V., and Zabolotskii, V.I., Elektrokhimiya, 1987, vol. 23, p. 601.

    CAS  Google Scholar 

  4. Hladik, J., Physics of Electrolytes, London Academic, 1972 (translated into Russian).

    Google Scholar 

  5. Gnusin, N.P., Zabolotskii, V.I., Nikonenko, V.V., and Meshechkov, A.I., Zh. Fiz. Khim., 1980, vol. 54, p. 1518.

    CAS  Google Scholar 

  6. Gnusin, N.P., Parshikov, S.B., and Demina, O.A., Russ. J. Electrochem., 1998, vol. 34, p. 1185.

    CAS  Google Scholar 

  7. Gnusin, N.P., Demina, O.A., Berezina, N.P., and Parshikov, S.B., in Teoriya i praktika sorbts. protsessov, (Theory and Practice of Sorption Processes), Voronezh: Voronezh gos. un-t, 1999, no. 25, p. 213.

    Google Scholar 

  8. Demina, O.A., Kononenko, N.A., and Falina, I.V., Petroleum Chem., 2014, vol. 54, p. 39.

    Article  Google Scholar 

  9. Grebenyuk, V.D., Pevnitskaya, M.V., and Gnusin, N.P., Zh. Prikl. Khim., 1969, vol. 42, p. 578.

    CAS  Google Scholar 

  10. Berezina, N.P., Shkirskaya, S.A., Kolechko, M.V., and Timofeev, S.V., RF Patent no. 2481885, 2012.

    Google Scholar 

  11. Kolechko, M.V., Filippov, A.N., Shkirskaya, S.A., Berezina, N.P., and Timofeev, S.V., Colloid J., 2013, vol. 75, no. 3.

  12. Berezina, N.P., Shkirskaya, S.A., Kolechko, M.V., Popova, O.V., Senchikhin, I.N., and Roldugin, V.I., Russ. J. Electrochem., 2011, vol. 47, p. 995.

    Article  CAS  Google Scholar 

  13. GOST (State Standard) 17552-72: Ion-exchange Membranes. Methods of Determination of the Total Equilibrium Exchange Capacity, 1972.

  14. GOST (State Standard) 17554-72: Ion-Exchange Membranes. Method of Determination of Moisture Content, 1972.

  15. Mazanko, A.F., Kamar’yan, G.M., and Romashin, O.P., Promyshlennyi membrannyi elektroliz (Industrial Membrane- Assisted Electrolysis), Moscow Khimiya, 1989.

    Google Scholar 

  16. Meshechkov, A.I., Demina, O.A., and Gnusin, N.P., Elektrokhimiya, 1987, vol. 23, p. 1452.

    CAS  Google Scholar 

  17. Gnusin, N.P., Demina, O.A., Meshechkov, A.I., and Tur’yan, I.Ya., Elektrokhimiya, 1985, vol. 21, p. 1525.

    CAS  Google Scholar 

  18. Berezina, N.P., Kononenko, N.A., Filippov, A.N., Shkirskaya, S.A., Falina, I.V., and Sytcheva, A.A.-R., Russ. J. Electrochem., 2010, vol. 46, p. 485.

    Article  CAS  Google Scholar 

  19. Gnusin, N.P., Demina, O.A., and Annikova, L.A., Russ. J. Electrochem., 2009, vol. 45, p. 490.

    Article  CAS  Google Scholar 

  20. Demina, O.A., Demin, A.V., Gnusin, N.P., and Zabolotskii, V.I., Polymer, Sci. A, 2010, vol. 52, p. 1270.

    Google Scholar 

  21. Berezina, N.P., Kononenko, N.A., Dyomina, O.A., and Gnusin, N.P., Adv. Colloid Interface Sci., 2008, vol. 139, p. 3.

    Article  CAS  Google Scholar 

  22. Spravochnik khimika (Chemist’s Handbook), Nikol’skii, B.P., Ed., Moscow: Khimiya, 1965, vol. 3.

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Authors and Affiliations

  1. Kuban State University, ul. Stavropol’skaya 149, Krasnodar, 350040, Russia

    O. A. Demina, S. A. Shkirskaya, N. A. Kononenko & E. V. Nazyrova

Authors
  1. O. A. Demina
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  2. S. A. Shkirskaya
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  3. N. A. Kononenko
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  4. E. V. Nazyrova
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Corresponding author

Correspondence to N. A. Kononenko.

Additional information

Original Russian Text © O.A. Demina, S.A. Shkirskaya, N.A. Kononenko, E.V. Nazyrova, 2016, published in Elektrokhimiya, 2016, Vol. 52, No. 4, pp. 339–346.

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Demina, O.A., Shkirskaya, S.A., Kononenko, N.A. et al. Assessing the selectivity of composite ion-exchange membranes within the framework of the extended three-wire model of conduction. Russ J Electrochem 52, 291–298 (2016). https://doi.org/10.1134/S1023193516040030

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  • DOI: https://doi.org/10.1134/S1023193516040030

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