Skip to main content
SpringerLink
Log in

Synthesis Gas Production by Partial Oxidation of Methane and Dry Reforming of Methane in the Presence of Novel Ni–Co/MFI Catalysts

  • Published:
Petroleum Chemistry Aims and scope Submit manuscript

Abstract

Catalysts based on Ni, Co, and NiCo supported on MFI zeolites for the partial oxidation of methane and dry reforming of methane to synthesis gas have been synthesized and studied. The total metal content in the catalysts is 2 wt %. A commercial zeolite with a binder (alumina) and a binder-free zeolite synthesized by an accelerated microwave-assisted hydrothermal method are used as supports. The synthesis gas yield is 97% in the presence of Ni and NiCo catalysts supported on the MFI zeolite synthesized by the microwaveassisted hydrothermal method. The simultaneous presence of Ni and Co in the catalyst makes the sample resistant to coking during dry reforming of methane, whereas the Ni catalyst is characterized by the formation of a significant amount of carbon fibers.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. A. Holmen, Catal. Today, 142, (2009).

  2. B. C. Enger, R. Lødeng, and A. Holmen, Appl. Catal., A 346, (2008).

  3. S. Zeng, X. Zhang, X. Fu, et al., Appl. Catal., B 136/137, 308 (2013).

    Article  Google Scholar 

  4. Methanol: The Basic Chemical and Energy Feedstock of the Future: Asinger’s Vision Today, Ed. by M. Bertau, H. Offermanns, L.Plass, (Springer, Heidelberg, 2014).

  5. L. M. T. S. Rodrigues, R. B. Silva, M. G. C. Rocha, et al., Catal. Today 197, 137 (2012).

    Article  CAS  Google Scholar 

  6. V. S. Arutyunov, Oxidative Conversion of Natural Gas (KRASAND, Moscow, 2011).

    Google Scholar 

  7. K. A. Chalupka, W. K. Jozwiak, J. Rynkowski, et al., Appl. Catal., B 146, 227 (2014).

    Article  CAS  Google Scholar 

  8. A. G. Dedov, A. S. Loktev, D. A. Komissarenko, et al., Fuel Process. Technol. 148, 128 (2016).

    Article  CAS  Google Scholar 

  9. A. G. Dedov, A. S. Loktev, D. A. V. K. Ivanov, et al., Dokl. Phys. Chem. 461 (2), 73 (2015).

    Article  CAS  Google Scholar 

  10. A. I. Osman, J. Meudal, F. Laffir, et al. Appl. Catal., B 212, 68 (2017).

    Article  CAS  Google Scholar 

  11. J.-S. Chang, S.-E. Park, and H. Chon, Appl. Catal., A 145, 111 (1996).

    Article  CAS  Google Scholar 

  12. J. Estephane, S. Aouad, S Hany., et al. Int. J. Hydrogen Energy 40, 9201 (2015).

    Article  CAS  Google Scholar 

  13. A. Luengnaruemitchai and A. Kaengsilalai, Chem. Eng. J. 144, 96 (2008).

    Article  CAS  Google Scholar 

  14. G. Moradi, F. Khezeli, and H. Hemmati, J. Nat. Gas Sci. Eng. 33, 657 (2016).

    Article  CAS  Google Scholar 

  15. A. N. Pinheiro, A. Valentini, J. M. Sasaki, and A. C. Oliveira, Appl. Catal., A 355, 156 (2009).

    Article  CAS  Google Scholar 

  16. P. Frontera, A. Aloise, A. Macario, et al., Top. Catal. 53, 265 (2010).

    Article  CAS  Google Scholar 

  17. J. Estephane, M. Ayoub, Kh. Safieh, et al., C. R. Chim. 18, 277 (2015).

    Article  CAS  Google Scholar 

  18. M. Abdollahifar, M. Haghighi, and M. Sharifi, Energy Conv. Manage. 103, 1101 (2015).

    Article  CAS  Google Scholar 

  19. C. Dai, S. Zhang, A. Zhang, et al., J. Mater. Chem. A 3, 16461 (2015).

    Article  CAS  Google Scholar 

  20. P. Frontera, A. Macario, A. Aloise, et al., Catal. Today 218/219, 18 (2013).

    Article  Google Scholar 

  21. S. Zhang, S. Muratsugu, N. Ishiguro, and M. Tada, ACS Catal. 3, 1855 (2013).

    Article  Google Scholar 

  22. N. Wang, K. Shen, L. Huang, et al., ACS Catal. 3, 1638 (2013).

    Article  CAS  Google Scholar 

  23. A. G. Dedov, A. S. Loktev, D. A. Levchenko, et al. Theor. Found. Chem. Eng. 49, 502 (2015).

    Article  CAS  Google Scholar 

  24. A. G. Dedov, A. S. Loktev, E. A. Isaeva, et al. Pet. Chem. 57, 678 (2017).

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Gubkin Russian State University of Oil and Gas (National Research University), Moscow, Russia

    A. G. Dedov, A. S. Loktev, I. E. Mukhin, A. A. Karavaev, S. I. Tyumenova & I. I. Moiseev

  2. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russia

    A. E. Baranchikov & V. K. Ivanov

  3. Moscow State University, Moscow, Russia

    K. I. Maslakov & M. A. Bykov

Authors
  1. A. G. Dedov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. A. S. Loktev
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. I. E. Mukhin
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. A. A. Karavaev
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. S. I. Tyumenova
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. A. E. Baranchikov
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. V. K. Ivanov
    View author publications

    You can also search for this author in PubMed Google Scholar

  8. K. I. Maslakov
    View author publications

    You can also search for this author in PubMed Google Scholar

  9. M. A. Bykov
    View author publications

    You can also search for this author in PubMed Google Scholar

  10. I. I. Moiseev
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to A. S. Loktev.

Additional information

Original Russian Text © A.G. Dedov, A.S. Loktev, I.E. Mukhin, A.A. Karavaev, S.I. Tyumenova, A.E. Baranchikov, V.K. Ivanov, K.I. Maslakov, M.A. Bykov, I.I. Moiseev, 2018, published in Neftekhimiya, 2018, Vol. 58, No. 2, pp. 154–164.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Dedov, A.G., Loktev, A.S., Mukhin, I.E. et al. Synthesis Gas Production by Partial Oxidation of Methane and Dry Reforming of Methane in the Presence of Novel Ni–Co/MFI Catalysts. Pet. Chem. 58, 203–213 (2018). https://doi.org/10.1134/S0965544118030052

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0965544118030052

Keywords

Search

Navigation