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Hydrogen peroxide oxidative desulfurization of model diesel mixtures using azacrown ethers

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Abstract

Hydrogen peroxide oxidative desulfurization of model diesel fuel mixtures in the presence of azacrown ethers and their complexes with niobium pentachloride at 40–80°C has been studied. It has been found that the use of complexes of azacrown ethers with NbCl5 leads to a decrease in the total sulfur content in the model mixtures to 13% of the initial amount. The structure of the azacrown ether used has little effect on the extent of desulfurization of the model mixture.

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Authors and Affiliations

  1. Faculty of Chemistry, Moscow State University, Moscow, Russia

    E. V. Rakhmanov, S. V. Baranova, Zixiao Wang, A. V. Tarakanova, S. V. Kardashev, A. V. Akopyan, E. R. Naranov, M. S. Oshchepkov & A. V. Anisimov

Authors
  1. E. V. Rakhmanov
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  2. S. V. Baranova
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  3. Zixiao Wang
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  4. A. V. Tarakanova
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  5. S. V. Kardashev
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  6. A. V. Akopyan
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  7. E. R. Naranov
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  8. M. S. Oshchepkov
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  9. A. V. Anisimov
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Corresponding author

Correspondence to E. V. Rakhmanov.

Additional information

Original Russian Text © E.V. Rakhmanov, S.V. Baranova, Wang Zixiao, A.V. Tarakanova, S.V. Kardashev, A.V. Akopyan, E.R. Naranov, M.S. Oshchepkov, A.V. Anisimov, 2014, published in Neftekhimiya, 2014, Vol. 54, No. 4, pp. 318–324.

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Rakhmanov, E.V., Baranova, S.V., Wang, Z. et al. Hydrogen peroxide oxidative desulfurization of model diesel mixtures using azacrown ethers. Pet. Chem. 54, 316–322 (2014). https://doi.org/10.1134/S0965544114030098

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  • DOI: https://doi.org/10.1134/S0965544114030098

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