Abstract
Observations of vibrationally excited hydroxyl (OH*) emissions are widely used to obtain information about the dynamics and composition of the atmosphere. We present some analytical approximations for the characteristics of the hydroxyl layer in the Martian atmosphere such as OH* concentration at the maximum and height of the maximum, as well as relations for estimating the influence of various factors on the OH* layer in night conditions. These characteristics depend on the temperature of the environment, concentration of atomic oxygen, and their vertical gradients. The relations are applied to the results of numerical modeling using the global atmospheric circulation model for prediction of seasonal behavior of the hydroxyl layer on Mars. Annual and intra-annual variations in the concentration of excited hydroxyl and layer height from the modeling data have both some similarities with those of the Earth and significant differences. The concentration and height maximum in the equatorial, northern and southern midlatitudes vary depending on the season; the maximum concentration and the minimum height fall on the first half of the year. Model calculations confirmed the presence of the peak OH* concentration at polar latitudes in winter at an altitude of approximately 50 km with the volume emission densities of 2.1, 1.4, and 0.6 × 104 photons cm–3 s–1 for vibrational level transitions 1–0, 2–1, and 2–0, respectively. The relations obtained may be used for the analysis of measurements and interpretation of their variations.
REFERENCES
Adler-Golden, S., Kinetic parameters for OH nightglow modeling consistent with recent laboratory measurements, J. Geophys. Res., 1997, vol. 102, pp. 19969–19976. https://doi.org/10.1029/97JA01622
Ammosov, P., Gavrilyeva, G., Ammosova, A., and Koltovskoi, I., Response of the mesopause temperatures to solar activity over Yakutia in 1999–2013, Adv. Space Res., 2014, vol. 54, pp. 2518–2524. https://doi.org/10.1016/j.asr.2014.06.007
Barbier, D., L’emission de la raie rouge du ciel nocturne en Afrique, Ann. Geophys., 1961, vol. 17, pp. 305–318.
Bertaux, J.L., Gondet, B., Lefevre, F., Bibring, J.P., and Montmessin, F., First detection of O2 1.27 μm nightglow emission at Mars with OMEGA/MEX and comparison with general circulation model predictions, J. Geophys. Res., 2012, vol. 117, p. J04. https://doi.org/10.1029/2011JE003890
Buriti, R.A., Takahashi, H., Lima, L.M., and Medeiros, A.F., Equatorial planetary waves in the mesosphere observed by airglow periodic oscillations, Adv. Space Res., 2005, vol. 35, pp. 2031–2036. https://doi.org/10.1016/j.asr.2005.07.012
Burkholder, J.B., Sander, S.P., Abbatt, J., Barker, J.R., Cappa, C., Crounse, J.D., Dibble, T.S., Huie, R.E., Kolb, C.E., Kurylo, M.J., et al., Chemical kinetics and photochemical data for use in atmospheric studies, Evaluation No. 19, JPL Publication 19-5, Pasadena, CA: Jet Propulsion Laboratory, 2020. http://jpldataeval.jpl.nasa.gov.
Caridade, P.J.S.B., Horta, J.-Z.J., and Varandas, A.J.C., Implications of the O + OH reaction in hydroxyl nightglow modeling, Atmos. Chem. Phys., 2013, vol. 13, pp. 1–13. https://doi.org/10.5194/acp-13-1-2013
Chalamala, B.R. and Copeland, R.A., Collision dynamics of OH (X2Π, v = 9), J. Chem. Phys., 1993, vol. 99, pp. 5807–5811. https://doi.org/10.1063/1.465932
Clancy, R.T., Sandor, B.J., Garcia-Munoz, A., Lefevre, F., Smith, M.D., Wolff, M.J., Montmessin, F., Murchie, S.L., and Nair, H., First detection of Mars atmospheric hydroxyl: CRISM Near-IR measurement versus LMD GCM simulation of OH Meinel band emission in the Mars polar winter atmosphere, Icarus, 2013, vol. 226, pp. 272–281. https://doi.org/10.1016/j.icarus.2013.05.035
Dalin, P., Perminov, V., Pertsev, N., and Romejko, V., Updated long-term trends in mesopause temperature, airglow emissions, and noctilucent clouds, J. Geophys. Res., 2020, vol. 125, p. e2019JD030814. https://doi.org/10.1029/2019JD030814
Dodd, J.A., Lipson, S.J., and Blumberg, W.A.M., Formation and vibrational relaxation of oh(X2Πi, v) by O2 and CO2, J. Chem. Phys., 1991, vol. 95, pp. 5752–5762. https://doi.org/10.1063/1.461597
Forget, F., Hourdin, F., and Talagrand, O., CO2 snowfall on Mars: Simulation with a general circulation model, Icarus, 1998, vol. 131, pp. 302–316. https://doi.org/10.1006/icar.1997.5874
Forget, F., Hourdin, F., Fournier, R., Hourdin, C., Talagrand, O., Collins, M., Lewis, S.R., Read, P.L., and Huot, J.-P., Improved general circulation models of the Martian atmosphere from the surface to above 80 km, J. Geophys. Res., 1999, vol. 104, pp. 24155–24176. https://doi.org/10.1029/1999JE001025
Forget, F., Millour, E., Montabone, L., and Lefevre, F., Non condensable gas enrichment and depletion in the Martian polar regions, Mars Atmosphere: Modeling and Observations, 2008, vol. 1447, p. 9106.
Fukuyama, K., Airglow variations and dynamics in the lower thermosphere and upper mesosphere—II. Seasonal and long-term variations, J. Atmos. Terr. Phys., 1977, vol. 39, pp. 1–14.
Gao, H., Xu, J., and Wu, Q., Seasonal and QBO variations in the OH nightglow emission observed by TIMED/SABER, J. Geophys. Res., 2010, vol. 115, p. A06313. https://doi.org/10.1029/2009JA014641
García-Muñoz, A., McConnell, J.C., McDade, I.C., and Melo, S.M.L., Airglow on Mars: Some model expectations for the OH Meinel bands and the O2 IR atmospheric band, Icarus, 2005, vol. 176, pp. 75–95. https://doi.org/10.1016/j.icarus.2005.01.006
Gavrilov, N.M., Shiokawa, K., and Ogawa, T., Seasonal variations of medium-scale gravity wave parameters in the lower thermosphere obtained from SATI observations at Shigaraki, Japan, J. Geophys. Res., 2002, vol. 107, no. D24, p. 4755. https://doi.org/10.1029/2001JD001469
Gavrilyeva, G.A., Ammosov, P.P., and Koltovskoi, I.I., Semidiurnal thermal tide in the mesopause region over Yakutia, Geomagn. Aeron., 2009, vol. 49, no. 1, pp. 110–114. https://doi.org/10.1134/S0016793209010150
Gérard, J.-C., Soret, L., Saglam, A., Piccioni, G., and Drossart, P., The distributions of the OH Meinel and O2 (a1∆–X3Σ) nightglow emissions in the Venus mesosphere based on VIRTIS observations, Adv. Space Res., 2010, vol. 45, pp. 1268–1275. https://doi.org/10.1016/j.asr.2010.01.022
Gorinov, D.A., Khatuntsev, I.V., Zasova, L.V., Turin, A.V., and Piccioni, G., Circulation of Venusian atmosphere at 90–110 km based on apparent motions of the O2 1.27 μm nightglow from VIRTIS-M (Venus Express) data, Geophys. Res. Lett., 2018, vol. 45, pp. 2554–2562. https://doi.org/10.1002/2017GL076380
Grygalashvyly, M., Sonnemann, G.R., Lubken, F.-J., Hartogh, P., and Berger, U., Hydroxyl layer: Mean state and trends at midlatitudes, J. Geophys. Res., 2014, vol. 119, pp. 12391–12419. https://doi.org/10.1002/2014JD022094
Harrison, A.W., Evans, W.F.J., and Llewellyn, E.J., Study of the (4-1) and (5-2) hydroxyl bands in the night airglow, Can. J. Phys., 1971, vol. 49, pp. 2509–2517.
Kaye, J.A., On the possible role of the reaction O + HO2 → OH + O2 in OH airglow, J. Geophys. Res., 1988, vol. 93, pp. 285–288.
Krasnopolsky, V.A., Photochemistry of the Martian atmosphere: Seasonal, latitudinal, and diurnal variations, Icarus, 2006, vol. 185, pp. 153–170. https://doi.org/10.1016/j.icarus.2006.06.003
Krasnopolsky, V.A., Solar activity variations of thermospheric temperatures on Mars and a problem of CO in the lower atmosphere, Icarus, 2010, vol. 207, pp. 638–647. https://doi.org/10.1016/j.icarus.2009.12.036
Krasnopolsky, V.A., Nighttime photochemical model and night airglow on Venus, Planet. Space Sci., 2013, vol. 85, pp. 78–88. https://doi.org/10.1016/j.pss.2013.05.022
Krasnopolsky, V.A. and Lefèvre, F., Chemistry of the atmospheres of Mars, Venus, and Titan, in Comparative Climatology of Terrestrial Planets, Mackwell, S.J., , Eds., Tucson: Univ. Arizona, 2013, pp. 231–275. https://doi.org/10.2458/azu_uapress_9780816530595-ch11
Krassovsky, V.I., Chemistry of the upper atmosphere, Space Res., 1963, vol. 3, pp. 96–116.
Lefèvre, F., Lebonnois, S., Montmessin, F., and Forget, F., Three-dimensional modeling of ozone on Mars, J. Geophys. Res., 2004, vol. 109, p. E07004. https://doi.org/10.1029/2004JE002268
Lefèvre, F., Bertaux, J.-L., Clancy, R.T., Encrenaz, T., Fast, K., Forget, F., Lebonnois, S., Montmessin, F., and Perrier, S., Heterogeneous chemistry in the atmosphere of Mars, Nature, 2008, vol. 454, pp. 971–975. https://doi.org/10.1038/nature07116
Lindner, B.L., Ozone on Mars: The effects of clouds and airborne dust, Planet. Space Sci., 1988, vol. 36, pp. 125–144. https://doi.org/10.1016/0032-0633(88)90049-9
Liu, G. and Shepherd, G.G., An empirical model for the altitude of the OH nightglow emission, Geophys. Res. Lett., 2006, vol. 33, p. L09805. https://doi.org/10.1029/2005GL025297
Liu, G., Shepherd, G.G., and Roble, R.G., Seasonal variations of the nighttime O(1S) and OH airglow emission rates at mid-to-high latitudes in the context of the large-scale circulation, J. Geophys. Res., 2008, vol. 113, p. A06302. https://doi.org/10.1029/2007JA012854
Llewellyn, E.J., Long, B.H., and Solheim, B.H., The quenching of OH* in the atmosphere, Planet. Space Sci., 1978, vol. 26, pp. 525–531. https://doi.org/10.1016/0032-0633(78)90043-0
Lopez-Gonzalez, M.J., Rodríguez, E., Shepherd, G.G., Sargoytchev, S., Shepherd, M.G., Aushev, V.M., Brown, S., García-Comas, M., and Wiens, R.H., Tidal variations of O2 atmospheric and OH(6-2) airglow and temperature at mid-latitudes from SATI observations, Ann. Geophys., 2005, vol. 23, pp. 3579–3590. https://doi.org/10.5194/angeo-23-3579-2005
Lopez-Gonzalez, M.J., Rodríguez, E., García-Comas, M., Costa, V., Shepherd, M.G., Shepherd, G.G., Aushev, V.M., and Sargoytchev, S., Climatology of planetary wave type oscillations with periods of 2–20 days derived from O2 atmospheric and OH(6-2) airglow observations at mid-latitude with SATI, Ann. Geophys., 2009, vol. 27, pp. 3645–3662. https://doi.org/10.5194/angeo-27-3645-2009
Makhlouf, U.B., Picard, R.H., and Winick, J.R., Photochemical-dynamical modeling of the measured response of airglow to gravity waves. 1. Basic model for OH airglow, J. Geophys. Res., 1995, vol. 100, pp. 11289—11311. https://doi.org/10.1029/94JD03327
Marsh, D.R., Smith, A.K., Mlynczak, M.G., and Russell, J.M. III, Saber observations of the OH Meinel airglow variability near the mesopause, J. Geophys. Res., 2006, vol. 111, p. A10S05. https://doi.org/10.1029/2005JA011451
McDade, I.C. and Llewellyn, E.J., Kinetic parameters related to sources and sinks of vibrationally excited OH in the nightglow, J. Geophys. Res., 1987, vol. 92, pp. 7643–7650. https://doi.org/10.1029/JA092iA07p07643
Medvedeva, I.V. and Ratovsky, K.G., Manifestation of wave activity in the upper atmosphere during winter sudden stratospheric warmings, Sovrem. Probl. Distantsionnogo Zondirovaniya Zemli Kosmosa, 2020, vol. 17, no. 6, pp. 159–166. https://doi.org/10.21046/2070-7401-2020-17-6-159-166
Medvedeva, I.V., Semenov, A.I., Pogoreltsev, A.I., and Tatarnikova, A.V., Influence of sudden stratospheric warming on the mesosphere/lower thermosphere from the hydroxyl emission observations and numerical simulations, J. Atmos. Sol.-Terr. Phys., 2019, vol. 187, pp. 22–32. https://doi.org/10.1016/j.jastp.2019.02.005
Meriwether, J.W., Jr., A review of the photochemistry of selected nightglow emissions from the mesopause, J. Geophys. Res., 1989, vol. 94, pp. 14629–14646. https://doi.org/10.1029/JD094iD12p14629
Millour, E., Forget, F., Spiga, A., Vals, M., Zakharov, V., Montabone, L., Lefevre, F., Montmessin, F., and Chaufray, J.-Y., López-Valverde M.A., et al., The Mars climate database (version 5.3), Scientific Workshop: “From Mars Express to ExoMars,” 2018. https://ui.adsabs.harvard.edu/link_gateway/2018fmee.confE.68M/PUB_PDF.
Mlynczak, M.G., Hunt, L.A., Mast, J.C., Marshall, B.T., Russell, IIIJ.M., Smith, A.K., Siskind, D.E., Yee, J.-H., Mertens, C.J., Martin-Torres, F.J., et al., Atomic oxygen in the mesosphere and lower thermosphere derived from SABER: Algorithm theoretical basis and measurement uncertainty, J. Geophys. Res., 2013, vol. 118, pp. 5724–5735. https://doi.org/10.1002/jgrd.50401
Mlynczak, M.G., Hunt, L.A., Marshall, B.T., Mertens, C.J., Marsh, D.R., Smith, A.K., Russell, J.M., Siskind, D.E., and Gordley, L.L., Atomic hydrogen in the mesopause region derived from SABER: Algorithm theoretical basis, measurement uncertainty, and results, J. Geophys. Res., 2014, vol. 119, pp. 3516–3526. https://doi.org/10.1002/2013JD021263
Mulligan, F.G., Dyrland, M.E., Sigernes, F., and Deehr, C.S., Inferring hydroxyl layer peak heights from ground-based measurements of OH (6–2) band integrated emission rate at longyearbyen (78° N, 16° E), Ann. Geophys., 2009, vol. 27, pp. 4197–4205. https://doi.org/10.5194/angeo-27-4197-2009
Nagy, A.F., Lui, S.C., and Baker, D.J., Vibrationally-excited hydroxyl molecules in the lower atmosphere, Geophys. Res. Lett., 1976, vol. 3, pp. 731–734. https://doi.org/10.1029/GL003i012p00731
Nair, H., Allen, M., Anbar, A.D., Yung, Y.L., and Clancy, R.T., A photochemical model of the Martian atmosphere, Icarus, 1994, vol. 111, pp. 124–150. https://doi.org/10.1006/icar.1994.1137
Navarro, T., Madeleine, J.-B., Forget, F., Spiga, A., Millour, E., Montmessin, F., and Määttänen, A., Global climate modeling of the Martian water cycle with improved microphysics and radiatively active water ice clouds, J. Geophys. Res., 2014, vol. 119, pp. 1479–1495. https://doi.org/10.1002/2013JE004550
Perminov, V.I., Semenov, A.I., Medvedeva, I.N., and Pertsev, N.N., Temperature variability in the mesopause region according to hydroxyl-emission observations at midlatitudes, Geomagn. Aeron., 2014, vol. 54, no. 2, pp. 230–239. https://doi.org/10.1134/S0016793214020157
Perminov, V.I., Pertsev, N.N., Dalin, P.A., Zheleznov, Yu.A., Sukhodoev, V.A., and Orekhov, M.D., Seasonal and long-term changes in the intensity of O2(b1Σ) and OH(X2Π) airglow in the mesopause region, Geomagn. Aeron., 2021, vol. 61, pp. 589–599. https://doi.org/10.1134/S0016793221040113
Pertsev, N. and Perminov, V., Response of the mesopause airglow to solar activity inferred from measurements at Zvenigorod, Russia, Ann. Geophys., 2008, vol. 26, pp. 1049–1056. https://doi.org/10.5194/angeo-26-1049-2008
Pertsev, N.N., Andreyev, A.B., Merzlyakov, E.G., and Perminov, V.I., Mesosphere-thermosphere manifestations of stratospheric warmings: Joint use of satellite and ground-based measurements, Current Problems in Remote Sensing of the Earth from Space, 2013, vol. 10. no. 1, pp. 93–100. http://jr.rse.cosmos.ru/article.aspx?id=1154&lang=eng.
Piccioni, G., Drossart, P., Zasova, L., Migliorini, A., Gérard, J.-C., Mills, F.P., Shakun, A., García Muñoz, A., Ignatiev, N., Grassi, D., et al., The VIRTIS-Venus Express technical team. First detection of hydroxyl in the atmosphere of Venus, Astron. Astrophys., 2008, vol. 483, pp. L29–L33. https://doi.org/10.1051/0004-6361:200809761
Popov, A.A., Gavrilov, N.M., Andreev, A.B., and Pogoreltsev, A.I., Interannual dynamics in intensity of mesoscale hydroxyl nightglow variations over Almaty, Solar-Terr. Phys., 2018, vol. 4, no. 2, pp. 63–68. https://doi.org/10.12737/stp-42201810
Popov, A.A., Gavrilov, N.M., Perminov, V.I., Pertsev, N.N., and Medvedeva, I.V., Multi-year observations of mesoscale variances of hydroxyl nightglow near the mesopause at Tory and Zvenigorod, J. Atmos. Sol.-Terr. Phys., 2020, vol. 205, pp. 1–8. https://doi.org/10.1016/j.jastp.2020.105311
Reisin, E., Scheer, J., Dyrland, M.E., Sigernes, F., Deehr, C.S., Schmidt, C., Hoppner, K., Bittner, M., Ammosov, P.P., Gavrilyeva, G.A., et al., Traveling planetary wave activity from mesopause region airglow temperatures determined by the Network for the Detection of Mesospheric Change (NDMC), J. Atmos. Sol.-Terr. Phys., 2014, vol. 119, pp. 71–82. https://doi.org/10.1016/j.jastp.2014.07.002
Russell, J.P., Ward, W.E., Lowe, R.P., Roble, R.G., Shepherd, G.G., and Solheim, B., Atomic oxygen profiles (80 to 115 km) derived from Wind Imaging Interferometer/Upper Atmospheric Research Satellite measurements of the hydroxyl and greenline airglow: Local time-latitude dependence, J. Geophys. Res., 2005, vol. 110, p. D15305. https://doi.org/10.1029/2004JD005570
Shaposhnikov, D.S., Medvedev, A.S., Rodin, A.V., and Hartog, P., Seasonal water “pump” in theatmosphere of Mars: Vertical transport to the thermosphere, Geophys. Res. Lett., 2019, vol. 46, pp. 4161–4169. https://doi.org/10.1029/2019GL082839
Shefov, N.N., Hydroxyl emission of the upper atmosphere. I, Planet. Space Sci., 1969, vol. 17, pp. 797–813. https://doi.org/10.1016/0032-0633(69)90089-0
Shepherd, M.G., Meek, C.E., Hocking, W.K., Hall, C.M., Partamies, N., Sigernes, F., Manson, A.H., and Ward, W.E., Multi-instrument study of the mesosphere-lower thermosphere dynamics at 80° N during the major SSW in January 2019, J. Atmos. Sol.-Terr. Phys., 2020, vol. 210, p. 105427. https://doi.org/10.1016/j.jastp.2020.105427
Sonnemann, G.R., Hartogh, P., Berger, U., and Grygalashvyly, M., Hydroxyl layer: Trend of number density and intra-annual variability, Ann. Geophys., 2015, vol. 33, pp. 749–767. https://doi.org/10.5194/angeo-33-749-2015
Soret, L., Gérard, J.-C., Piccioni, G., and Drossart, P., Venus OH nightglow distribution based on VIRTIS limb observations from Venus Express, Geophys. Res. Lett., 2010, vol. 37, p. L06805. https://doi.org/10.1029/2010GL042377
Soret, L., Gérard, J.-C., Piccioni, G., and Drossart, P., The OH Venus nightglow spectrum: Intensity and vibrational composition from VIRTIS Venus Express observations, Planet. Space Sci., 2012, vol. 73, pp. 387–396. https://doi.org/10.1016/j.pss.2012.07.027
Swenson, G.R. and Gardner, C.S., Analytical models for the responses of the mesospheric OH* and Na layers to atmospheric gravity waves, J. Geophys. Res., 1998, vol. 103, pp. 6271–6294. https://doi.org/10.1029/97JD02985
Takahashi, H. and Batista, P.P., Simultaneous measurements of OH (9.4), (8.3), (7.2), 6.2), and (5.1) bands in the airglow, J. Geophys. Res., 1981, vol. 86, pp. 5632–5642. https://doi.org/10.1029/JA086iA07p05632
Turnbull, D.N. and Lowe, R.P., Vibrational population distribution in the hydroxyl night airglow, Can. J. Phys., 1983, vol. 61, pp. 244–250. https://doi.org/10.1139/p83-033
Wiens, R.H. and Weill, G.M., Diurnal, annual and solar cycle variations of hydroxyl and sodium nightglow intensities in the Europe–Africa sector, Planet. Space Sci., 1973, vol. 21, pp. 1011–1027.
Xu, J., Smith, A.K., Jiang, G., Gao, H., Wei, Y., Mlynczak, M.G., and Russell, J.M. III, Strong longitudinal variations in the OH nightglow, Geophys. Res. Lett., 2010, vol. 37, p. L21801. https://doi.org/10.1029/2010GL043972
Xu, J., Gao, H., Smith, A.K., and Zhu, Y., Using TIMED/SABER nightglow observations to investigate hydroxyl emission mechanisms in the mesopause region, J. Geophys. Res., 2012, vol. 117, p. D02301. https://doi.org/10.1029/2011JD016342
ACKNOWLEDGMENTS
The authors are grateful to the referees for very helpful and constructive comments on improving this paper.
The MCD data are available at http://www-mars.lmd.jussieu.fr/. The calculation results are published and available at https://doi.org/10.5281/zenodo.5941499.
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This study was partially supported by the Russian Science Foundation grant no. 20-72-00110.
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Shaposhnikov, D.S., Grigalashvili, M., Medvedev, A.S. et al. Analytical Approximations of the Characteristics of Nighttime Hydroxyl on Mars and Intra-Annual Variations. Sol Syst Res 57, 1–13 (2023). https://doi.org/10.1134/S0038094623010057
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DOI: https://doi.org/10.1134/S0038094623010057