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Complexing and ion selective properties of some acid type phosphoryl podands. The crystal and molecular structures of 1,5-bis(2-dihydroxyphosphoryl-4-ethylphenoxy)-3-oxapentane dihydrate [(HO)2(O)P(C6H3CH2CH3)(OCH2CH2)2O (C6H3CH2CH3)P(O)(OH)2] · 2H2O

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Abstract

The synthesis of 1,5-bis(2-dihydroxyphosphoryl-4-ethylphenoxy)-3-oxapentane [(HO)2(O)P(C6H3CH2CH3)(OCH2CH2)2O(C6H3CH2CH3)P(O)(OH)2] (H4K2) and single crystal X-ray diffraction study of H4K2 · 2H2O (I) are described. The crystals are orthorhombic, a = 33.291(4) Å, b = 8.9374(10) Å, c = 8.1021(9) Å, V = 2410.6(5) Å3, Z = 4, space group Cmc21, R = 0.0484 for 2566 reflections with I > 2σ(I). In I, the molecules of H4K2 are hydrogen-bonded to two crystallographically independent H2O molecules to give neutral conglomerates H4K2 · 2H2O. The electroanalytical characteristics of poly(vinyl chloride) membranes based on H4K2 were tested. Cu2+ and Zn2+ complexes with H4K2 and Er3+, Nd3+, and complexes with H4K2, 1,5-bis[2-(dihydroxyphosphoryl-4-methoxy)phenoxy]-3-oxapentane, 1,5-bis[2-(dihydroxyphosphinyl)phenoxy]-3-oxapentane, and 1,8-bis[2-(dihydroxyphosphinyl)phenoxy]-3,6-dioxaoctane were prepared.

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Authors and Affiliations

  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 119991, Russia

    L. Kh. Minacheva, I. S. Ivanova, E. N. Pyatova, A. V. Churakov & V. S. Sergienko

  2. Institute of Physiologically Active Substances, Russian Academy of Sciences, Chernogolovka, Moscow oblast, 142432, Russia

    V. E. Baulin & I. P. Kalashnikova

  3. Frumkin Institute of Electrochemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 119991, Russia

    V. E. Baulin & A. Yu. Tsivadze

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  1. L. Kh. Minacheva
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  2. V. E. Baulin
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  3. I. S. Ivanova
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  4. E. N. Pyatova
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  5. I. P. Kalashnikova
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  6. A. V. Churakov
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  7. V. S. Sergienko
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  8. A. Yu. Tsivadze
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Original Russian Text © L.Kh. Minacheva, V.E. Baulin, I.S. Ivanova, E.N. Pyatova, I.P. Kalashnikova, A.V. Churakov, V.S. Sergienko, A.Yu. Tsivadze, 2013, published in Zhurnal Neorganicheskoi Khimii, 2013, Vol. 58, No. 8, pp. 1033–1042.

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Minacheva, L.K., Baulin, V.E., Ivanova, I.S. et al. Complexing and ion selective properties of some acid type phosphoryl podands. The crystal and molecular structures of 1,5-bis(2-dihydroxyphosphoryl-4-ethylphenoxy)-3-oxapentane dihydrate [(HO)2(O)P(C6H3CH2CH3)(OCH2CH2)2O (C6H3CH2CH3)P(O)(OH)2] · 2H2O. Russ. J. Inorg. Chem. 58, 919–927 (2013). https://doi.org/10.1134/S0036023613080159

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  • DOI: https://doi.org/10.1134/S0036023613080159

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