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Synthesis and characterization of MF-4SK + SiO2 hybrid membranes modified with tungstophosphoric heteropolyacid

  • Synthesis and Properties of Inorganic Compounds
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Abstract

Composites based on MF-4K perfluorinated cation-exchange membranes doped with hydrous silica nanoparticles, which were precipitated under various conditions, and with tungstophosphoric heteropolyacid nanoparticles were synthesized. The proton conductivity of the composites was studied as a function of temperature and relative ambient humidity. As a result of modification, the water content and ion conductivity of the membranes in low humidities increase by 2.5 orders of magnitude compared to unmodified MF-4SK membranes and the material is rendered less water-dependent.

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References

  1. T. Xu, J. Membr. Sci. 263, 1 (2005).

    Article  CAS  Google Scholar 

  2. A. B. Yaroslavtsev, V. V. Nikonenko, and V. I. Zabolotskii, Usp. Khim. 72(5), 2935 (2003).

    Google Scholar 

  3. D. J. Jones and J. Roziere, Handbook of Fuel Cells: Fundamentals, Technology and Applications, Vol. 3: Fuel Cell Technology and Applications (Wiley, 2003), p. 447.

  4. V. V. Volkov, B. V. Mchedlishvili, V. I. Roldugin, et al., Ross. Nanotekhnol. 3(11–12), 67 (2008).

    Google Scholar 

  5. B. Bonnet, D. J. Jones, J. Roziere, et al., J. New Mater. Electrochem. Syst. 3, 87 (2000).

    CAS  Google Scholar 

  6. E. Yu. Voropaeva, I. A. Stenina, and A. B. Yaroslavtsev, Zh. Neorg. Khim. 53(11), 1797 (2008) [Russ. J. Inorg. Chem. 53 (11), 1677 (2008)].

    CAS  Google Scholar 

  7. E. Yu. Voropaeva, I. A. Stenina, and A. B. Yaroslavtsev, Zh. Neorg. Khim. 53(10), 1637 (2008) [Russ. J. Inorg. Chem. 53 (10), 1531 (2008)].

    CAS  Google Scholar 

  8. E. Yu. Voropaeva, E. A. Sanginov, V. I. Volkov, et al., Zh. Neorg. Khim. 53(10), 1643 (2008) [Russ. J. Inorg. Chem. 53 (10), 1536 (2008)].

    CAS  Google Scholar 

  9. I. A. Stenina, E. Yu. Voropaeva, A. G. Veresov, et al., Zh. Neorg. Khim. 53(3), 397 (2008) [Russ. J. Inorg. Chem. 53 (3), 343 (2008)].

    CAS  Google Scholar 

  10. I. A. Stenina, E. Yu. Voropaeva, T. R. Brueva, et al., Zh. Neorg. Khim. 53(6), 912 (2008) [Russ. J. Inorg. Chem. 53 (6), 842 (2008)].

    CAS  Google Scholar 

  11. E. Yu. Voropaeva, I. A. Stenina, and A. B. Yaroslavtsev, Zh. Neorg. Khim. 52(1), 5 (2007) [Russ. J. Inorg. Chem. 52 (1), 1 (2007)].

    CAS  Google Scholar 

  12. A. B. Yaroslavtsev, Usp. Khim. 66(7), 641 (1997).

    CAS  Google Scholar 

  13. P. Staiti, S. Freni, and S. Hocevar, J. Power Sources 79, 250 (1999).

    Article  CAS  Google Scholar 

  14. P. Staiti, A. S. Arico, V. Baglio, et al., Solid State Ionics 145, 101 (2001).

    Article  CAS  Google Scholar 

  15. A. B. Yaroslavtsev, E. M. Yaroslavtseva, and V. F. Chuvaev, Zh. Neorg. Khim. 39(6), 948 (1994).

    CAS  Google Scholar 

  16. N. P. Berezina, S. V. Timofeev, and N. A. Kononenko, J. Membr. Sci. 209, 509 (2002).

    Article  CAS  Google Scholar 

  17. N. P. Berezina, N. A. Kononenko, G. A. Dvorkina, and N. V. Shel’deshov, Physicochemical Properties of Ion-Exchange Resins (Izd-vo Krasnodarsk. Gos. Univ., Krasnodar, 1999) [in Russian].

    Google Scholar 

  18. W. Y. Hsu and T. D. Gierke, J. Membr. Sci. 13, 307 (1983).

    Article  CAS  Google Scholar 

  19. L. G. Karakchiev and N. Z. Lyakhov, Neorg. Mater. 34(5), 575 (1998).

    Google Scholar 

  20. Ph. Colomban, Proton Conductors: Solids, Membranes and Gels—Materials and Devices (Cambridge Univ. Press, Cambridge, 1992).

    Google Scholar 

  21. A. Cliarfield, Inorganic Ion Exchange Materials (CRC Press, Boca Ration, FL, 1982).

    Google Scholar 

  22. K. D. Kreuer, M. Hampele, L. Dolde, and A. Rabenau, Solid State Ionics 28–30, 589 (1988).

    Article  Google Scholar 

  23. B. S. Bokshtein and A. B. Yaroslavtsev, Diffusion of Atoms and Ions in Solids (Izd-vo MISIS, Moscow, 2005) [in Russian].

    Google Scholar 

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Authors and Affiliations

  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 119991, Russia

    E. Yu. Safronova, I. A. Stenina & A. B. Yaroslavtsev

  2. Higher Chemical College, Russian Academy of Sciences, Moscow, Russia

    E. Yu. Safronova

Authors
  1. E. Yu. Safronova
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  2. I. A. Stenina
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  3. A. B. Yaroslavtsev
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Additional information

Original Russian Text © E.Yu. Safronova, I.A. Stenina, A.B. Yaroslavtsev, 2010, published in Zhurnal Neorganicheskoi Khimii, 2010, Vol. 55, No. 1, pp. 16–20.

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Safronova, E.Y., Stenina, I.A. & Yaroslavtsev, A.B. Synthesis and characterization of MF-4SK + SiO2 hybrid membranes modified with tungstophosphoric heteropolyacid. Russ. J. Inorg. Chem. 55, 13–17 (2010). https://doi.org/10.1134/S0036023610010031

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  • DOI: https://doi.org/10.1134/S0036023610010031

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