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Crystallization and dielectric and optical properties of borate glasses (1 − x)Na2B4O7 + xNb2O5

  • Synthesis and Properties of Inorganic Compounds
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Abstract

The crystallization and dielectric and optical properties of glasses (1 − x)Na2B4O7 + xNb2O5, where x = 0.15–0.35, have been studied. The formation of structural entities based on NbO6 octahedra in the glass has been detected by Raman spectroscopy. In the thermally poled glass, a layer with nonlinear optical properties is formed under the anode surface. The nonlinear optical properties of the poled sample have been studied by the second harmonic generation method using laser radiation. The nonlinear optical coefficient d 33 for the poled glass with the maximal content of niobia is 0.1 pm/V.

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Authors and Affiliations

  1. Moscow State University, Vorob’evy gory, Moscow, 119991, Russia

    A. P. Malakho, S. Yu. Stefanovich, V. A. Morozov & B. I. Lazoryak

  2. Institut de Chimie de la Matière Condensée de Bordeaux, UPR 9048, CNRS, Université Bordeaux I, Chat. Brivazac, Av. du dr. Schweitzer, 33608, Pessac Cedex, France

    E. Fargin

  3. Laboratoire de Physico-Chimie Moléculaire, UMR 5803 CNRS, Université Bordeaux I, 351 cours de la Libération, 33405, Talence Cedex, France

    V. Rodriguez

Authors
  1. A. P. Malakho
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  2. S. Yu. Stefanovich
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  3. V. A. Morozov
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  4. B. I. Lazoryak
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  5. E. Fargin
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  6. V. Rodriguez
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Additional information

Original Russian Text © A.P. Malakho, S.Yu. Stefanovich, V.A. Morozov, B.I. Lazoryak, E. Fargin, V. Rodriguez, 2007, published in Zhurnal Neorganicheskoi Khimii, 2007, Vol. 52, No. 3, pp. 349–356.

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Malakho, A.P., Stefanovich, S.Y., Morozov, V.A. et al. Crystallization and dielectric and optical properties of borate glasses (1 − x)Na2B4O7 + xNb2O5 . Russ. J. Inorg. Chem. 52, 301–307 (2007). https://doi.org/10.1134/S0036023607030011

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  • DOI: https://doi.org/10.1134/S0036023607030011

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