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Application of geological benchmarks for determining groundwater residence time in the aquifer based on uranium isotope data: Evidence from the Severnaya Dvina Basin

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Abstract

Using the Severnaya Dvina Basin as an example, it is shown that information on the distribution of natural U isotopes in aquifers can be applied for practical estimation of the duration of interaction between groundwater and host rocks (age of groundwater). The proposed calculation method includes preliminary determination of the generalized calculated parameter (probability of the transfer of 234U excess to water) based on geological benchmarks, hydrodynamic calculations, and paleohydrogeological reconstructions. It is assumed that this probability is constant for aquifers composed of homogeneous rocks with certain lithological composition and oxidizing conditions for U. The obtained correlations are valid for a model, where water entering the aquifer lacks U. If it contains such U, the “transport” time, which is equivalent to the timing of respective concentrations and isotopic ratios in the aquifer unit, is determined and estimates of the “water-rock” interaction in the aquifer unit are corrected.

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References

  • Andrews, J.N. and Kay, R.L.F., The evolution of enhanced 234U/238U activity ratios for dissolved uranium and groundwater dating, Short Pap. Fourth Int. Conf. “Geochron., Cosmochron., Isotope Geol.,” U.S. Geol. Surv. Openfile Rep., 1978, pp. 11–13.

    Google Scholar 

  • Andrews, J.N., Giles, I.S., and Kay, R.L.F., et al., Radioelements, radiogenic helium and age relationships of groundwaters from the granites at Stripa, Sweden, Geochim. Cosmochim. Acta, 1982, vol. 46, no. 9, pp. 1533–1543.

    Article  Google Scholar 

  • Barr, G.E., Lambert, S.J., and Carter, J.A., Uranium isotope disequilibrium in groundwaters of southeastern New Mexico and implications regarding age-dating of water, in Proc. Int. Symp. Isotope Hydrology, STI/PUB/493, Vienna: I.A.E.A, 1979, vol. 2, pp. 645–660.

    Google Scholar 

  • Bolikhovskaya, N.S. and Molod’kov, A.N., Scheme of periodization, correlation, and age of Pleistocene climatic events, in Fundamental problems of the Quaternary: Results of study and major lines of further studies. Materials of VI All-Russia Conf. on Study of the Quaternary Period, Novosibirsk: INGGSO RAN, IGM SO RAN, 2009, pp. 75–78.

    Google Scholar 

  • Chalov, P.I., Mechanism of the formation of nonequilibrium relationships between natural radioactive isotopes in the U- and Th-bearing natural compounds, Atomn. Energ., 1969, vol. 27, no. 1, pp. 26–32.

    Google Scholar 

  • Cherdyntsev, V.V., Isotopic composition of radioelements in natural bodies in relation to issues of geochronology, in Trudy tret’ei sessii Komissii po opredeleniyu absolyutnogo vozrasta geologicheskikh formatsii (Trans. 3rd Session Commission for Determination of the Absolute Age of Geological Formations), Moscow: AN SSSR, 1955, pp. 175–233.

    Google Scholar 

  • Clark, I.D. and Fritz, P., Environmental Isotopes in Hydrogeology, Boca Raton, FL: CRC Press, 1997.

    Google Scholar 

  • Ferronskii, V.I. and Polyakov, V.A., Izotopiya gidrosfery Zemli (Isotopy of the Earth’s hydrosphere), Moscow: Nauchn. Mir, 2009.

    Google Scholar 

  • Fröhlich, K. and Gellermann, R., On the potential use of uranium isotopes for groundwater dating, Chem. Geol., 1987, vol. 65, no. 1, pp. 67–77.

    Article  Google Scholar 

  • Fröhlich, K., Ivanovich, M., Hendry, M.J., et al., Application of isotopic methods to dating of very old groundwaters: Milk River aquifer, Alberta, Canada, Appl. Geochem., 1991, vol. 6, no. 4, pp. 465–472.

    Article  Google Scholar 

  • Garrels, R. and Christ, C., Solutions, minerals, and equilibria, New York: Harper and Row, 1965.

    Google Scholar 

  • Geyh, M., Amore, F.D., Darling, G., et al., Groundwater saturated and unsaturated zone, in Environmental isotopes in the hydrological cycle—principals and application, Mook, W.G., Ed., Vienna, 2001, vol. 4.

    Google Scholar 

  • Kazemi, G.A., Lehr, J.H., and Perrochet, P., The age of groundwaters, Hoboken, N.J.: Wiley Interscience, 2006.

    Book  Google Scholar 

  • Kigoshi, K., Alpha-recoil 234Th: dissolution into water and the 234U/238U disequilibrium in nature, Science, 1971, vol. 173, pp. 47–48.

    Article  Google Scholar 

  • Kronfeld, J., Gradsztajn, E., Müller, H.W., et al., Excess 234U: an aging effect in confined waters, Earth Planet. Sci. Lett., 1975, vol. 27, no. 2, pp. 342–345.

    Article  Google Scholar 

  • Larsen, E., Lys., Demidov, I., et al., Age extent of the Scandinavian ice sheet in Northwest Russia, Boreas, 1999, vol. 28, no. 1, pp. 115–132.

    Article  Google Scholar 

  • Lisitsin, A.K., Hydrogeochemical model of the infiltrational ore-forming system, Geochem. Int., 1997, no. 3, pp. 271–280.

    Google Scholar 

  • Malov, A.I., Podzemnye vody Yugo-Vostochnogo Belomor’ya: formirovanie, rol’ v geologicheskikh protsessakh (Groundwaters in the southeastern White Sea region: formation and role in geological processes), Yekaterinburg: UrO RAN, 2003.

    Google Scholar 

  • Malov, A.I., The water-rock interaction in Vendian sandyclayey rocks of the Mezen syneclise, Lithol. Miner. Resour., 2004, no. 4, pp. 397–408.

    Google Scholar 

  • Malov, A.I., Kiselev, G.P., and Rudik, G.P., Uranium in groundwaters of the Mezen syneclise, Dokl. Earth. Sci., 2008, vol. 421, no. 5, pp. 653–656.

    Google Scholar 

  • Malov, A.I., Kiselev, G.P., Rudik, G.P., and Zykov, S.B., Uranium isotopes in Vendian groundwaters of the Mezen Syneclise, Water Resour., 2009, vol. 36, no. 6, pp. 703–712.

    Article  Google Scholar 

  • Malov, A.I., Titenko, A.P., and Georgiev, A.G., Geological factors of the formation of industrial iodine waters in the marine interglacial sediments, in Materialy 8 Ural’skogo litologicheskogo soveshchaniya “Aktual’nye voprosy litologii” (Materials of the 8th Uralian Lithol. Conf. “Actual issues of lithology”), Yekaterinburg: IGG UrO RAN, 2010, pp. 223–224.

    Google Scholar 

  • Malov, A.I., Kiselev, G.P., and Zykov, S.B., Specific features of uranium isotope partitioning in Vendian groundwaters of the Mezen syneclise, in Materialy Vserossiiskoi nauchnoi konferentsii “Problemy gidrogeologii, inzhenernoi geologii i gidrogeoekologii” (Materials of All-Russia Sci. Conf. “Problems of hydrogeology, engineering geology, and hydrogeoecology”), Tomsk: NTL, 2011, pp. 147–153.

    Google Scholar 

  • Rosholt, J.N., Shields, W.R., and Garner, E.L., Isotopic fractionation of uranium in sandstone, Science, 1963, vol. 139, no. 3551, pp. 224–226.

    Article  Google Scholar 

  • Sistema Belogo morya (The White Sea system), Lisitsyn, A.P, Ed., Moscow: Nauchn. Mir, 2010.

    Google Scholar 

  • Solomon, D.K., Poreda, R.J., Cook, P.G., and Hunt, A., Site characterization using 3H/3He groundwater ages, Cape Cod, MA, Ground Water, 1995, vol. 33, no. 6, pp. 988–996.

    Article  Google Scholar 

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Correspondence to A. I. Malov.

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Original Russian Text © A.I. Malov, 2013, published in Litologiya i Poleznye Iskopaemye, 2013, No. 3, pp. 274–285.

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Malov, A.I. Application of geological benchmarks for determining groundwater residence time in the aquifer based on uranium isotope data: Evidence from the Severnaya Dvina Basin. Lithol Miner Resour 48, 254–265 (2013). https://doi.org/10.1134/S002449021303005X

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  • DOI: https://doi.org/10.1134/S002449021303005X

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