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Crystal structure of [Pd(NH3)4][Rh(NH3)(NO2)5]

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Abstract

An XRD analysis is used to study the single crystal of [Pd(NH3)4][Rh(NH3)(NO2)5] double complex salt at T = 150(2) K. Crystallographic characteristics are as follows: a = 7.6458(5) Å, b = 9.8813(6) Å, c = 9.5788(7) Å, β = 109.469(2)°, V = 682.30(8) Å3, P21/m space group, Z = 2, d x = 2.553 g/cm3. The geometry of the complex [Rh(NH3)(NO2)5]2− anion is described for the first time: Rh-N(NO2) distances are 2.020(4)–2.060(3) Å, Rh-N(NH3) 2.074(4) Å, N(NO2)-Rh-N(NH3) trans-angle is 178.8(2)°.

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Authors and Affiliations

  1. A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk, Russia

    E. A. Shusharina, A. A. Rybinskaya, P. E. Plyusnin, Yu. V. Shubin, S. V. Korenev & S. A. Gromilov

  2. Novosibirsk State University, Novosibirsk, Russia

    P. E. Plyusnin, Yu. V. Shubin, S. V. Korenev & S. A. Gromilov

Authors
  1. E. A. Shusharina
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  2. A. A. Rybinskaya
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  3. P. E. Plyusnin
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  4. Yu. V. Shubin
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  5. S. V. Korenev
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  6. S. A. Gromilov
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Corresponding author

Correspondence to S. A. Gromilov.

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Original Russian Text Copyright © 2011 by E. A. Shusharina, A. A. Rybinskaya, P. E. Plyusnin, Yu. V. Shubin, S. V. Korenev, and S. A. Gromilov

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Translated from Zhurnal Strukturnoi Khimii, Vol. 52, No. 3, pp. 636–639, May–June, 2011.

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Shusharina, E.A., Rybinskaya, A.A., Plyusnin, P.E. et al. Crystal structure of [Pd(NH3)4][Rh(NH3)(NO2)5]. J Struct Chem 52, 621–624 (2011). https://doi.org/10.1134/S0022476611030255

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  • DOI: https://doi.org/10.1134/S0022476611030255

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