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Uranyl complexes with methyl derivatives of alicyclic dioximes

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Abstract

A reaction of uranyl dioxalate complexes with methyl derivatives of alicyclic α-dioximes, 3-methyl-1,2-cyclohexanedione dioxime and 3-methyl-1,2-cyclopentanedione dioxime, was studied. The structure of (CN3H6)4[(UO2)2(C6H8N2O2)(CO3)(C2O4)2] · (C6H10N2O2) · 2H2O and NH4(CN3H6)3[(UO2)2(C7H10N2O2)(CO3)(C2O4)2] · 2H2O based on binuclear complex anions with carbonate-dioximate fragment was studied by X-ray diffraction.

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Authors and Affiliations

  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 119991, Russia

    A. G. Beirakhov, I. M. Orlova, E. G. Il’in, A. S. Kanishcheva, A. V. Churakov & Yu. N. Mikhailov

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  1. A. G. Beirakhov
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  2. I. M. Orlova
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  3. E. G. Il’in
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  4. A. S. Kanishcheva
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  5. A. V. Churakov
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  6. Yu. N. Mikhailov
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Additional information

Original Russian Text © A.G. Beirakhov, I.M. Orlova, E.G. Il’in, A.S. Kanishcheva, A.V. Churakov, Yu.N. Mikhailov, 2012, published in Zhurnal Neorganicheskoi Khimii, 2012, Vol. 57, No. 7, pp. 1019–1026.

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Beirakhov, A.G., Orlova, I.M., Il’in, E.G. et al. Uranyl complexes with methyl derivatives of alicyclic dioximes. Russ. J. Inorg. Chem. 57, 945–952 (2012). https://doi.org/10.1134/S0036023612070054

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  • DOI: https://doi.org/10.1134/S0036023612070054

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