Skip to main content
SpringerLink
Log in

Physical and chemical properties of zinc Cyanoferrates(II)

  • Synthesis and Properties of Inorganic Compounds
  • Published:
Russian Journal of Inorganic Chemistry Aims and scope Submit manuscript

Abstract

Neutral zinc cyanoferrate(II) Zn2Fe(CN)6 · 2.5H2O and its hydrogen form HZn1.5Fe(CN)6 · 4.5H2O were synthesized and studied. X-ray diffraction, vibrational spectroscopy, and 1H NMR showed that Zn2Fe(CN)6 · 2.5H2O in aqueous solutions undergoes reversible hydrolysis. The hydrogen form of zinc cyanoferrate(II) is stable up to ≈200°C. The conductivity of HZn1.5Fe(CN)6 · 4.5H2O in the temperature range 90–120°C is σ = 10−3.3 S/cm, which is about three orders of magnitude higher than the conductivity of the neutral salt.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. I. V. Tananaev, G. B. Seifer, Yu. Ya. Kharitonov, et al., The Chemistry of Ferrocyanides (Nauka, Moscow, 1971) [in Russian].

    Google Scholar 

  2. A. G. Sharpe, The Chemistry of Cyano Complexes of the Transition Metals (Academic Press, London, 1976).

    Google Scholar 

  3. I. M. Kolthoff and E. I. A. N. Verzijl, Recl. Trav. Chim. Pays-Bas 43, 389 (1924).

    CAS  Google Scholar 

  4. S. Saito, Bull. Inst. Phys. Chem. Res. Tokyo, 10,316, 703 (1931).

    Google Scholar 

  5. I. V. Tananaev and A. P. Korol’kov, Izv. Akad. Nauk SSSR, Neorg. Mater. 1(9), 1577 (1965).

    CAS  Google Scholar 

  6. G. B. Seifer, Zh. Neorg. Khim. 8(5), 1172 (1963).

    Google Scholar 

  7. V. G. Kuznetsov, Z. V. Popova, and G. B. Seifer, Zh. Neorg. Khim. 15(8), 2077 (1970).

    CAS  Google Scholar 

  8. M. Cola and T. G. Valentini, Inorg. Nucl. Chem. Lett. 8, 5 (1972).

    Article  CAS  Google Scholar 

  9. J. Hanawalt, H. Rinn, and L. Frevel, Anal. Chem. 10, 457 (1938); Card 1-433, Powder Diffraction File PDF2 (ICDD, USA, 2006).

    CAS  Google Scholar 

  10. Vibrational Spectra in Inorganic Chemistry, Ed. by Yu. A. Kharitonov (Nauka, Moscow, 1971) [in Russian].

    Google Scholar 

  11. V. V. Pavlishchuk, Teor. Eksp. Khim. 33(6), 341 (1997).

    Google Scholar 

  12. S. Ochs, E. Grabner, and E. Mohler, Ber. Bunsen-Ges. Phys. Chem. 100, 594 (1966).

    Google Scholar 

  13. V. V. Vol’khin, M. V. Zil’berman, S. A. Kolesova, and E. A. Shul’ga, Zh. Prikl. Khim. 48(1), 54 (1975).

    CAS  Google Scholar 

  14. V. V. Vol’khin, Izv. Akad. Nauk SSSR, Neorg. Mater. 15(6), 1086 (1979).

    CAS  Google Scholar 

  15. B. S. Bokshtein and A. B. Yaroslavtsev, Diffusion of Atoms and Ions in Solids (MISIS, Moscow, 2005) [in Russian].

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institute of Solid-State Chemistry, Ural Division, Russian Academy of Sciences, ul. Pervomaiskaya 91, Yekaterinburg, 620219, Russia

    T. A. Denisova, L. G. Maksimova, O. N. Leonidova & N. A. Zhuravlev

Authors
  1. T. A. Denisova
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. L. G. Maksimova
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. O. N. Leonidova
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. N. A. Zhuravlev
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to T. A. Denisova.

Additional information

Original Russian Text © T.A. Denisova, L.G. Maksimova, O.N. Leonidova, N.A. Zhuravlev, 2009, published in Zhurnal Neorganicheskoi Khimii, 2009, Vol. 54, No. 1, pp. 8–14.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Denisova, T.A., Maksimova, L.G., Leonidova, O.N. et al. Physical and chemical properties of zinc Cyanoferrates(II). Russ. J. Inorg. Chem. 54, 6–12 (2009). https://doi.org/10.1134/S0036023609010021

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0036023609010021

Keywords

Search

Navigation