" /> " /> " /> " /> " /> " /> (3), 3α,4α-dichloromethano-3,5,5-trimethyldecahydro-1H-benzocycloheptene-9,1'-spiro(2',2'-dichlorocyclopropane), (3), 3α,4α-dichloromethano-3,5,5-trimethyldecahydro-1H-benzocycloheptene-9,1'-spiro(2',2'-dichlorocyclopropane), (3), 3α,4α-dichloromethano-3,5,5-trimethyldecahydro-1H-benzocycloheptene-9,1'-spiro(2',2'-dichlorocyclopropane), (3), 3α,4α-dichloromethano-3,5,5-trimethyldecahydro-1H-benzocycloheptene-9,1'-spiro(2',2'-dichlorocyclopropane), (3), 3α,4α-dichloromethano-3,5,5-trimethyldecahydro-1H-benzocycloheptene-9,1'-spiro(2',2'-dichlorocyclopropane), (3), 3α,4α-dichloromethano-3,5,5-trimethyldecahydro-1H-benzocycloheptene-9,1'-spiro(2',2'-dichlorocyclopropane), (4), and (4), and (4), and (4), and (4), and (4), and 3α,4α-dibromomethano-3,5,5-trimethyldecahydro-1H-benzocycloheptene-9,1'-spiro(2',2'-dibromocyclopropane), 3α,4α-dibromomethano-3,5,5-trimethyldecahydro-1H-benzocycloheptene-9,1'-spiro(2',2'-dibromocyclopropane), 3α,4α-dibromomethano-3,5,5-trimethyldecahydro-1H-benzocycloheptene-9,1'-spiro(2',2'-dibromocyclopropane), 3α,4α-dibromomethano-3,5,5-trimethyldecahydro-1H-benzocycloheptene-9,1'-spiro(2',2'-dibromocyclopropane), 3α,4α-dibromomethano-3,5,5-trimethyldecahydro-1H-benzocycloheptene-9,1'-spiro(2',2'-dibromocyclopropane), 3α,4α-dibromomethano-3,5,5-trimethyldecahydro-1H-benzocycloheptene-9,1'-spiro(2',2'-dibromocyclopropane), 9α,9aα-dichloromethano-3,5,5,9-tetramethyl-1,4a,5,6,7,8,9,9a-octahydro-2H-benzocycloheptene, 9α,9aα-dichloromethano-3,5,5,9-tetramethyl-1,4a,5,6,7,8,9,9a-octahydro-2H-benzocycloheptene, 9α,9aα-dichloromethano-3,5,5,9-tetramethyl-1,4a,5,6,7,8,9,9a-octahydro-2H-benzocycloheptene, 9α,9aα-dichloromethano-3,5,5,9-tetramethyl-1,4a,5,6,7,8,9,9a-octahydro-2H-benzocycloheptene, 9α,9aα-dichloromethano-3,5,5,9-tetramethyl-1,4a,5,6,7,8,9,9a-octahydro-2H-benzocycloheptene, 9α,9aα-dichloromethano-3,5,5,9-tetramethyl-1,4a,5,6,7,8,9,9a-octahydro-2H-benzocycloheptene, C16H24Cl2, (5), resulting from C16H24Cl2, (5), resulting from C16H24Cl2, (5), resulting from C16H24Cl2, (5), resulting from C16H24Cl2, (5), resulting from C16H24Cl2, (5), resulting from C17H24Br4, C17H24Br4, C17H24Br4, C17H24Br4, C17H24Br4, C17H24Br4, C17H24Cl4, C17H24Cl4, C17H24Cl4, C17H24Cl4, C17H24Cl4, C17H24Cl4, and β-himachalene, are reported. and β-himachalene, are reported. and β-himachalene, are reported. and β-himachalene, are reported. and β-himachalene, are reported. and β-himachalene, are reported. cyclopropanation reactions of the C=C double bonds of α-cis-himachalene cyclopropanation reactions of the C=C double bonds of α-cis-himachalene cyclopropanation reactions of the C=C double bonds of α-cis-himachalene cyclopropanation reactions of the C=C double bonds of α-cis-himachalene cyclopropanation reactions of the C=C double bonds of α-cis-himachalene cyclopropanation reactions of the C=C double bonds of α-cis-himachalene
Download citation
Download citation
link to html
The crystallographic structures of 3[alpha],4[alpha]-dibromomethano-3,5,5-trimethyldecahydro-1H-benzocycloheptene-9,1'-spiro(2',2'-dibromocyclopropane), C17H24Br4, (3), 3[alpha],4[alpha]-dichloromethano-3,5,5-trimethyldecahydro-1H-benzocycloheptene-9,1'-spiro(2',2'-dichlorocyclopropane), C17H24Cl4, (4), and 9[alpha],9a[alpha]-dichloromethano-3,5,5,9-tetramethyl-1,4a,5,6,7,8,9,9a-octahydro-2H-benzocycloheptene, C16H24Cl2, (5), resulting from cyclopropanation reactions of the C=C double bonds of [alpha]-cis-himachalene and [beta]-himachalene, are reported.

Supporting information

cif

Crystallographic Information File (CIF)
Contains datablocks block, 3, 4, 5

hkl

Structure factor file (CIF format)
Contains datablock 3

hkl

Structure factor file (CIF format)
Contains datablock 4

hkl

Structure factor file (CIF format)
Contains datablock 5

CCDC references: 131410; 131411; 131412

-1
Follow Acta Cryst. C
Sign up for e-alerts
Follow Acta Cryst. on Twitter
Follow us on facebook
Sign up for RSS feeds