Appearance of a Liquid Crystalline Nematic-Isotropic Critical Point in a Mixture System of Rod- and Bent-Shaped Molecules

K. Takekoshi, K. Ema, H. Yao, Y. Takanishi, J. Watanabe, and H. Takezoe
Phys. Rev. Lett. 97, 197801 – Published 8 November 2006

Abstract

Heat capacity measurements have been made on a liquid-crystal mixture system formed from bent-shaped molecule 1,3-phenylene bis[4-(4-8-alkoxyphenyliminomethyl)benzoates] (P-8-O-PIMB) and rod-shaped molecule n-pentyl-cyanobiphenyl (5CB). The obtained results can be understood assuming that the addition of P-8-O-PIMB molecules to the 5CB system affects as a field conjugate to the nematic order parameter. The BXB4 transition can be viewed as the nematic-isotropic transition of 5CB, which is embedded in a framework of the B4 structure of P-8-O-PIMB molecules. The present mixture system offers a rare example of the nematic-isotropic critical point, whose critical behavior has not been studied yet in detail.

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  • Received 27 April 2006

DOI:https://doi.org/10.1103/PhysRevLett.97.197801

©2006 American Physical Society

Authors & Affiliations

K. Takekoshi, K. Ema*, and H. Yao

  • Department of Physics, Graduate School of Science and Engineering, Tokyo Institute of Technology, 2-12-1 Oh-okayama, Meguro, Tokyo 152-8550, Japan

Y. Takanishi, J. Watanabe, and H. Takezoe

  • Department of Organic and Polymeric Materials, Graduate School of Science and Engineering, Tokyo Institute of Technology, 2-12-1 Oh-okayama, Meguro, Tokyo 152-8550, Japan

  • *Corresponding author. Electronic address: kema@phys.titech.ac.jp

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Issue

Vol. 97, Iss. 19 — 10 November 2006

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