Evidence of Supercritical Behavior in Liquid Single Crystal Elastomers

A. Lebar, Z. Kutnjak, S. Žumer, H. Finkelmann, A. Sánchez-Ferrer, and B. Zalar
Phys. Rev. Lett. 94, 197801 – Published 16 May 2005

Abstract

Temperature profiles of the first and the second moment of the nematic order parameter distribution function, as determined from the deuteron nuclear magnetic resonance line shapes, as well as heat capacity response, provide support for the supercritical scenario of the nematic-paranematic phase transition in liquid single crystal elastomers. The relative strength of the locked-in internal mechanical field with respect to the critical field can be decreased by swelling the elastomer samples with low molecular mass nematogen. By increasing the concentration of the dopant, critical and below-critical behavior is promoted.

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  • Received 30 November 2004

DOI:https://doi.org/10.1103/PhysRevLett.94.197801

©2005 American Physical Society

Authors & Affiliations

A. Lebar1, Z. Kutnjak1, S. Žumer2,1, H. Finkelmann3, A. Sánchez-Ferrer3, and B. Zalar1

  • 1J. Stefan Institute, Jamova 39, SI-1000 Ljubljana, Slovenia
  • 2Department of Physics, University of Ljubljana, Jadranska 19, SI-1000 Ljubljana, Slovenia
  • 3Institut für Makromolekulare Chemie, Universität Freiburg, D-79104 Freiburg, Germany

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Issue

Vol. 94, Iss. 19 — 20 May 2005

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