Dynamic Arrest in Charged Colloidal Systems Exhibiting Large-Scale Structural Heterogeneities

C. Haro-Pérez, L. F. Rojas-Ochoa, R. Castañeda-Priego, M. Quesada-Pérez, J. Callejas-Fernández, R. Hidalgo-Álvarez, and V. Trappe
Phys. Rev. Lett. 102, 018301 – Published 5 January 2009
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Abstract

Suspensions of charged liposomes are found to exhibit typical features of strongly repulsive fluid systems at short length scales, while exhibiting structural heterogeneities at larger length scales that are characteristic of attractive systems. We model the static structure factor of these systems using effective pair interaction potentials composed of a long-range attraction and a shorter range repulsion. Our modeling of the static structure yields conditions for dynamically arrested states at larger volume fractions, which we find to agree with the experimentally observed dynamics.

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  • Received 8 March 2008

DOI:https://doi.org/10.1103/PhysRevLett.102.018301

©2009 American Physical Society

Authors & Affiliations

C. Haro-Pérez1,*, L. F. Rojas-Ochoa2, R. Castañeda-Priego3, M. Quesada-Pérez4, J. Callejas-Fernández1, R. Hidalgo-Álvarez1, and V. Trappe5,†

  • 1Grupo de Física de Fluidos y Biocoloides, Departamento de Física Aplicada, Universidad de Granada, 18071 Granada, Spain
  • 2Departamento de Física, Cinvestav-IPN, 07360 México Distrito Federal, Mexico
  • 3Instituto de Física, Universidad de Guanajuato, 37150 León, Mexico
  • 4Departamento de Física, Escuela Politécnica Superior de Linares, Universidad de Jaén, 23700 Linares, Spain
  • 5Département de Physique, Université de Fribourg, 1700 Fribourg, Switzerland

  • *Present address: Instituto de Física “Manuel Sandoval Vallarta,” UASLP, 78000 San Luis Potosí, Mexico.
  • Veronique.Trappe@unifr.ch

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Issue

Vol. 102, Iss. 1 — 9 January 2009

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