Exactly solvable model of reversible adsorption on a disordered substrate

J. Talbot, G. Tarjus, and P. Viot
Phys. Rev. E 76, 051106 – Published 9 November 2007

Abstract

We consider the reversible adsorption of particles (monomers with exclusion nearest-neighbor sites) on a one-dimensional lattice, where adsorption occurs on a finite fraction of sites selected randomly. By comparing this one-dimensional system to the pure system where all sites are available for adsorption, we show that when the activity goes to infinity, there exists a mapping between this model and the pure system at the same density. By examining the susceptibilities, we demonstrate that there is no mapping at finite activity. However, when the site density is small or moderate, the mapping exists up to second order in site density. We also propose and evaluate approximate approaches that may be applied to systems where no analytic result is known.

  • Figure
  • Figure
  • Figure
  • Figure
  • Figure
  • Received 13 August 2007

DOI:https://doi.org/10.1103/PhysRevE.76.051106

©2007 American Physical Society

Authors & Affiliations

J. Talbot1, G. Tarjus2, and P. Viot2

  • 1Department of Chemistry and Biochemistry, Duquesne University, Pittsburgh, Pennsylvania 15282-1530, USA
  • 2Laboratoire de Physique Théorique de la Matière Condensée, Université Pierre et Marie Curie, 4, place Jussieu,75252 Paris Cedex, 05 France

Article Text (Subscription Required)

Click to Expand

References (Subscription Required)

Click to Expand
Issue

Vol. 76, Iss. 5 — November 2007

Reuse & Permissions
Access Options
Author publication services for translation and copyediting assistance advertisement

Authorization Required


×
×

Images

×

Sign up to receive regular email alerts from Physical Review E

Log In

Cancel
×

Search


Article Lookup

Paste a citation or DOI

Enter a citation
×