Forces in nematic liquid crystals constrained to the nanometer scale under hybrid anchoring conditions

B. Zappone, Ph. Richetti, R. Barberi, R. Bartolino, and H. T. Nguyen
Phys. Rev. E 71, 041703 – Published 11 April 2005

Abstract

Using a surface forces apparatus we have studied two thermotropic nematic liquid crystals (5CB and ME10.5) subjected to hybrid (homeotropic/planar) anchoring conditions. A film of nematic material is constrained between two curved smooth surfaces separated by less than 2500Å. The intersurface force is nonmonotonic with the separation, being repulsive for thicknesses larger than 100Å and strongly adhesive at a shorter scale. While the repulsion can be qualitatively explained by an elastic model of director deformation, including anchoring deviation at the boundaries, the attraction cannot be explained either by elasticity or by dispersive forces. The expected confinement-induced anchoring transition has not been observed for a thickness as small as 200Å.

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  • Received 7 August 2004

DOI:https://doi.org/10.1103/PhysRevE.71.041703

©2005 American Physical Society

Authors & Affiliations

B. Zappone1,2,*, Ph. Richetti2, R. Barberi1, R. Bartolino1, and H. T. Nguyen2

  • 1Liquid Crystals Laboratory (Cemif. Cal.–Università della Calabria), Ponte P. Bucci, cubo 33b, 87036 Arcavacata di Rende (CS), Italy
  • 2Centre de Recherche Paul Pascal (CNRS–Université Bordeaux 1), Avenue Schweitzer, 33600 Pessac, France

  • *Electronic address: zappone@fis.unical.it

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Vol. 71, Iss. 4 — April 2005

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