Comment on “Algebraic perturbation theory for polar fluids: A model for the dielectric constant”

István Szalai, Kwong-Yu Chan, and Douglas Henderson
Phys. Rev. E 62, 8846 – Published 1 December 2000
PDFExport Citation

Abstract

Kalikmanov [Phys. Rev. E 59, 4085 (1999)] proposed a perturbation theory method to calculate the dielectric constant of dipolar hard sphere fluids using an infinitely long cylindrical container to avoid the depolarization. We demonstrate that while the method is very helpful, his theory appears to be incomplete because of the incorrect calculation of the corresponding three-body integrals. It is shown that with the correct consideration of these terms the theory is consistent with the results of earlier work in low-density limit, and at high densities the method yields the equation of Tani et al. [Mol. Phys. 48, 863 (1983)] for the dipolar hard sphere fluid dielectric constant.

  • Received 19 October 1999

DOI:https://doi.org/10.1103/PhysRevE.62.8846

©2000 American Physical Society

Authors & Affiliations

István Szalai*

  • Department of Chemistry, The University of Hong Kong, Pokfulam Road, Hong Kong, Republic of China

Kwong-Yu Chan

  • Department of Chemistry, The University of Hong Kong, Pokfulam Road, Hong Kong, Republic of China

Douglas Henderson

  • Department of Chemistry and Biochemistry, Brigham Young University, Provo, Utah 84602-5700

  • *Permanent address: Department of Physical Chemistry, University of Veszprém, H-8201 Veszprém, P.O. Box 158, Hungary. Electronic address: szalai@almos.vein.hu
  • Electronic address: hrsccky@hku.hk
  • Electronic address: doug@huey.byu.edu

Comments & Replies

Original Article

References (Subscription Required)

Click to Expand
Issue

Vol. 62, Iss. 6 — December 2000

Reuse & Permissions
Access Options
Author publication services for translation and copyediting assistance advertisement

Authorization Required


×
×

Images

×

Sign up to receive regular email alerts from Physical Review E

Log In

Cancel
×

Search


Article Lookup

Paste a citation or DOI

Enter a citation
×