Visualizing the collective motions responsible for the α and β relaxations in a model glass

Peter Harrowell
Phys. Rev. E 48, 4359 – Published 1 December 1993
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Abstract

Maps of the spatial distributions of the relaxation times are obtained from Monte Carlo simulations of the facilitated kinetic Ising model. The β relaxation, acting over short and intermediate time scales, is observed to occur in localized pockets. The slow α relaxation is governed by the fraction of these pockets which are free to move. This physical picture is able to account for the non-Arrhenius temperature dependence of the time scales of the α process, the scaling of the relaxation function in the β region, and the value of the relaxation function at the crossover time.

  • Received 6 July 1993

DOI:https://doi.org/10.1103/PhysRevE.48.4359

©1993 American Physical Society

Authors & Affiliations

Peter Harrowell

  • Van ’t Hoff Laboratory for Physical and Colloid Chemistry, University of Utrecht, Padualaan 8, 3584 CH Utrecht, The Netherlands
  • Department of Physical and Theoretical Chemistry, University of Sydney, Sydney, New South Wales 2006, Australia

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Vol. 48, Iss. 6 — December 1993

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